[en] NaCu0.2Fe0.8-xMnxO2 compounds were prepared by the solid state method. The structural analyses confirmed that the samples crystallize in hexagonal system with R-3 m space group. Fourier transform infrared spectroscopy shows vibrational modes of the compounds NaCu0.2Fe0.8-xMnxO2 and proves the presence of the octahedral environment MO6 (M = Cu, Fe, Mn) which is in good agreement with the structural study. The investigation by UV–visible spectroscopy revealed a strong absorption of the prepared samples in the UV–visible range and allowed extracting the band gap (2.8 eV < Eg < 3 eV) which shows a small increase with manganese content and exhibits the samples semiconductor behavior. Additionally, the study of the real part of the dielectric permittivity using impedance spectroscopy demonstrated a high dielectric constant at low frequency and suggested the existence of space charge polarization and dipolar polarization. However, the study of the imaginary part of the dielectric permittivity proved that the dipolar polarization may be masked due to the high ionic DC conductivity. Finally, modulus formalism indicated two relaxations attributed to the grain boundary and grain relaxations.
Disciplines :
Chemistry
Author, co-author :
Ben Slima, Ichrak; Laboratory LaSCOM, University of Sfax, Sfax, Tunisia
Karoui, Karim; Laboratory LaSCOM, University of Sfax, Sfax, Tunisia ; GREMAN, UMR 7347-CNRS, CEA, INSACVL, University of Tours, Blois, France
Khirouni, Kamel; Laboratory of Physics of Materials and Nanomaterials applied to Environement, Faculty of Sciences of Gabès, University of Gabès, Tunisia
Mahmoud, Abdelfattah ; Université de Liège - ULiège > Département de chimie (sciences) > GREEnMat
Boschini, Frédéric ; Université de Liège - ULiège > Département de chimie (sciences) > GREEnMat
Ben Rhaiem, Abdallah; Laboratory LaSCOM, University of Sfax, Sfax, Tunisia
Language :
English
Title :
Investigation of the optical and dielectric properties of NaCu0.2Fe0.8-xMnxO2 (x = 0.4; 0.5; 0.6; 0.7) layered oxide materials
Kanwade, A., Gupta, S., Kankane, A., Tiwari, M.K., Srivastava, A., Satrughna, J.A.K., Shirage, P.M., Transition metal oxides as a cathode for indispensable Na-ion batteries. RSC Adv. 12:36 (2022), 23284–23310, 10.1039/D2RA03601K.
Kubota, K., Kumakura, S., Yoda, Y., Kuroki, K., Komaba, S., Electrochemistry and solid-state chemistry of NaMeO2 (Me= 3d transition metals). Adv. Energy Mater., 8(17), 2018, 1703415, 10.1002/aenm.201703415.
Singh, A.N., Islam, M., Meena, A., Faizan, M., Han, D., Bathula, C., Nam, K.W., Unleashing the Potential of Sodium-Ion Batteries: Current State and Future Directions for Sustainable Energy Storage. Adv. Funct. Mater., 2304617, 2023, 10.1002/adfm.202304617.
Choudhury, D., Rivero, P., Meyers, D., Liu, X., Cao, Y., Middey, S., Chakhalian, J., Anomalous charge and negative-charge-transfer insulating state in cuprate chain compound KCuO2. Phys. Rev. B, 92(20), 2015, 201108, 10.1103/PhysRevB.92.201108.
Singh, S., Tangra, A.K., Lotey, G.S., Optical and luminescence properties of β-NaFeO2 nanoparticles. Electron. Mater. Lett. 14:5 (2018), 594–598, 10.1007/s13391-018-0067-5.
Rosaiah, P., Hussain, M., O., Synthesis, electrical and dielectrical properties of lithium iron oxide. Adv. Mater. Lett. 4:4 (2013), 288–295, 10.5185/amlett.2012.8416.
Murali, N., Margarette, S.J., Veeraiah, V., Synthesis, dielectric, conductivity and magnetic studies of LiNi1/3Co1/3Mn(1/3)−xAlxO2 (x= 0.0, 0.02, 0.04 and 0.06) for cathode materials of lithium-ion batteries. Results Phys. 7 (2017), 1379–1388, 10.1016/j.rinp.2017.02.037.
Elamathi, R., Ramesh, R., Aravinthraj, M., Manivannan, M., Khan, F.L.A., Mphale, K., Maaza, M., Investigation of structural and electrical properties of lithium cobalt oxide nanoparticles for optoelectronic applications. Surf. Interfaces, 20, 2020, 100582, 10.1016/j.surfin.2020.100582.
Liang, J.C., Yang, C.L., Wang, M.S., Ma, X.G., Yi, Y.G., High mobility and photocatalytic properties of NaXO2 (X= Co, Rh, Ir). Vacuum, 168, 2019, 108824, 10.1016/j.vacuum.2019.108824.
Triana, Y., Irkham, & Einaga, Y., Electrochemical oxidation behavior of nitrogen dioxide for gas detection using boron doped diamond electrodes. Electroanalysis, 34(4), 2022, 752, 10.1002/elan.202100122.
Singh, S., Kaur, J., Tovstolytkin, A., Singh, G., Superparamagnetic β-NaFeO2: a novel, efficient and biocompatible nanoparticles for treatment of cancer by nanohyperthermia. Mater. Res. Express, 6(8), 2019, 0850a6, 10.1088/2053-1591/ab243e.
Slima, I.B., Karoui, K., Mahmoud, A., Boschini, F., Rhaiem, A.B., Structural, optical, electric and dielectric characterization of a NaCu0.2Fe0.3Mn0.5O2 compound. RSC Adv. 12:3 (2022), 1563–1570, 10.1039/D1RA08263A.
I.B. Slima, K. Karoui, A. Mahmoud, F. Boschini, A.B. Rhaiem, Effects of Mn doping on structural properties and conduction mechanism of NaCu0.2Fe0.8−xMnxO2 (x= 0.4; 0.5; 0.6; 0.7) materials. J. Alloys Compd., 920 (2022) 166002. 10.1016/j.jallcom.2022.166002.
Julien, C.M., Massot, M., Poinsignon, C., Lattice vibrations of manganese oxides: Part I. Periodic structures. Spectrochim. Acta A Mol. Biomol. Spectrosc. 60:3 (2004), 689–700, 10.1016/S1386-1425(03)00279-8.
Missaoui, F., Trablsi, K., Moufida, K., Ates, A., Mahmoud, A., Boschini, F., Rhaiem, A.B., Structural, dielectric and transport properties of NaxFe1/2Mn1/2O2 (x= 1 and 2/3). RSC Adv., 13(26), 2023, 17923, 10.1039/d3ra02570e.
Saroha, R., Gupta, A., Panwar, A.K., Electrochemical performances of Li-rich layered-layered Li2MnO3-LiMnO2 solid solutions as cathode material for lithium-ion batteries. J. Alloy. Compd. 696 (2017), 580–589, 10.1016/j.jallcom.2016.11.199.
Siddiqui, H., Parra, M.R., Qureshi, M.S., Malik, M.M., Haque, F.Z., Studies of structural, optical, and electrical properties associated with defects in sodium-doped copper oxide (CuO/Na) nanostructures. J. Mater. Sci. 53:12 (2018), 8826–8843, 10.1007/s10853-018-2179-6.
Kumar, N., Parui, S.S., Limbu, S., Mahato, D.K., Tiwari, N., Chauhan, R.N., Structural and optical properties of sol–gel derived CuO and Cu2O nanoparticles. Mater. Today:. Proc. 41 (2021), 237–241, 10.1016/j.matpr.2020.08.800.
Durai, L., Badhulika, S., Facile synthesis of large area pebble-like β-NaFeO2 perovskite for simultaneous sensing of dopamine, uric acid, xanthine and hypoxanthine in human blood. Mater. Sci. Eng. C, 109, 2020, 110631, 10.1016/j.msec.2020.110631.
Mathiyalagan, K., Karuppiah, K., Ponnaiah, A., Rengapillai, S., Marimuthu, S., Significant role of magnesium substitution in improved performance of layered O3-Na-Mn-Ni-Mg-O cathode material for developing sodium-ion batteries. Int. J. Energy Res., 2022, 10.1002/er.7864.
Wen, H., Tanner, P.A., Optical properties of 3d transition metal ion-doped sodium borosilicate glass. J. Alloy. Compd. 625 (2015), 328–335, 10.1016/j.jallcom.2014.11.094.
Vaidhyanathan, B., Kumar, C.P., Rao, J.L., Rao, K.J., Spectroscopic investigations of manganese ions in microwave-prepared NaPO3 PbO glasses. J. Phys. Chem. Solid 59:1 (1998), 121–128, 10.1016/S0022-3697(97)00178-9.
Moustafa, F.A., Fayad, A.M., Ezz-Eldin, F.M., El-Kashif, I., Effect of gamma radiation on ultraviolet, visible and infrared studies of NiO, Cr2O3 and Fe2O3-doped alkali borate glasses. Journal of Non-CrystallineSolids, 376, 2013, 18, 10.1016/j.jnoncrysol.2013.04.052.
Chakradhar, R.S., Murali, A., Rao, J.L., Electron paramagnetic resonance and optical absorption studies of Cu2+ ions in alkali barium borate glasses. J. Alloys Compd. 265:1–2 (1998), 29–37, 10.1016/S0925-8388(97)00437-4.
Ravikumar, R.V.S.S.N., Komatsu, R., Ikeda, K., Chandrasekhar, A.V., Reddy, B.J., Reddy, Y.P., Rao, P.S., EPR and optical studies on transition metal doped LiRbB4O7 glasses. J. Phys. Chem. Solid 64:2 (2003), 261–264, 10.1016/S0022-3697(02)00289-5.
Harrabi, D., Hcini, S., Dhahri, J., Wederni, M.A., Alshehri, A.H., Mallah, A., Bouazizi, M.L., Study of Structural and Optical Properties of Cu–Cr Substituted Mg–Co Spinel Ferrites for Optoelectronic Applications. J. Inorg. Organomet. Polym Mater., 1–14, 2022, 10.1007/s10904-022-02484-w.
Wang, J., Zhang, C., Liu, H., McLaughlin, R., Zhai, Y., Vardeny, S.R., Vardeny, Z.V., Spin-optoelectronic devices based on hybrid organic-inorganic trihalide perovskites. Nat. Commun. 10:1 (2019), 1–6, 10.1038/s41467-018-07952-x.
Trabelsi, K., Karoui, K., Jomni, F., Rhaiem, A.B., Optical and AC conductivity behavior of sodium orthosilicate Na2CoSiO4. J. Alloy. Compd., 867, 2021, 159099, 10.1016/j.jallcom.2021.159099.
Singh, B., Singh, P., Siddiqui, S., Singh, D., Gupta, M., Wastewater treatment using Fe-doped perovskite manganites by photocatalytic degradation of methyl orange, crystal violet and indigo carmine dyes in tungsten bulb/sunlight. J. Rare Earths, 2022, 10.1016/j.jre.2022.09.010.
N. Geetha, V.S. Kumar, D. Prakash, Synthesis and characterization of LaMn1-xFexO3 (x= 0, 0.1, 0.2) by coprecipitation route. J. Phys. Chem. Biophys, 8 (2018) 1–6. https://doi.org/10.4172/2161-0398.1000273.
Tangra, A.K., Lotey, G.S., Synthesis and investigation of structural, optical, magnetic, and biocompatibility properties of nanoferrites AFeO2. Curr. Appl. Phys. 27 (2021), 103–116, 10.1016/j.cap.2021.04.011.
Slima, I.B., Karoui, K., Rhaiem, A.B., Ionic conduction, structural and optical properties of LiCoO2 compound. Ionics, 2023, 10.1007/s11581-023-04960-w.
Kalthoum, R., Bechir, M.B., Rhaiem, A.B., CH3NH3CdCl3: A promising new lead-free hybrid organic–inorganic perovskite for photovoltaic applications. Physica E, 124, 2020, 114235, 10.1016/j.physe.2020.114235.
Palik, E.D., (eds.) Handbook of optical constants of solids, Vol. 3, 1998, Academic press.
Kalthoum, R., Bechir, M.B., Rhaiem, A.B., Dhaou, M.H., Optical properties of new organic-inorganic hybrid perovskites (CH3)2NH2CdCl3 andCH3NH3CdCl3 for solar cell applications. Opt. Mater., 125, 2022, 112084, 10.1016/j.optmat.2022.112084.
Mahfoudh, N., Karoui, K., BenRhaiem, A., Optical studies and dielectric response of [DMA]2MCl4 (M= Zn and Co) and [DMA]2ZnBr 4. RSC Adv. 11:40 (2021), 24526–24535, 10.1039/D1RA03652A.
Singh, R.K., Kumar, R., Jain, N., Dash, S.R., Singh, J., Srivastava, A., Investigation of optical and dielectric properties of CsPbI3 inorganic lead iodide perovskite thin film. J. Taiwan Inst. Chem. Eng. 96 (2019), 538–542, 10.1016/j.jtice.2018.11.001.
Yan, X., Poxson, D.J., Cho, J., Welser, R.E., Sood, A.K., Kim, J.K., Schubert, E.F., Enhanced omnidirectional photovoltaic performance of solar cells using multiple-discrete-layer tailored-and low-refractive index anti-reflection coatings. Adv. Funct. Mater. 23:5 (2013), 583–590, 10.1002/adfm.201201032.
Abouhaswa, A.S., Rammah, Y.S., Ibrahim, S.E., El-Hamalawy, A.A., Structural, optical, and electrical characterization of borate glasses doped with SnO2. J. Non Cryst. Solids 494 (2018), 59–65, 10.1016/j.jnoncrysol.2018.04.051.
Mguedla, R., Kharrat, A.B.J., Taktak, O., Souissi, H., Kammoun, S., Khirouni, K., Boujelben, W., Experimental and theoretical investigations on optical properties of multiferroic PrCrO3 ortho-chromite compound. Opt. Mater., 101, 2020, 109742, 10.1016/j.optmat.2020.109742.
Ajmi, A., Karoui, K., Khirouni, K., Rhaiem, A.B., Optical and dielectric properties of NaCoPO4 in the three phases α, β and γ. RSC Adv. 9:26 (2019), 14772–14781, 10.1039/c9ra01558b.
Nageswara Rao, B., Venkateswarlu, M., Satyanarayana, N., Electrical and dielectric properties of rare earth oxides coated LiCoO2 particles. Ionics 20:2 (2014), 175–181, 10.1007/s11581-013-0973-3.
Arya, A., Sharma, A.L., Dielectric relaxations and transport properties parameter analysis of novel blended solid polymer electrolyte for sodium-ion rechargeable batteries. J. Mater. Sci. 54:9 (2019), 7131–7155, 10.1007/s10853-019-03381-3.
Benali, E.M., Benali, A., Bejar, M., Dhahri, E., Graca, M.P.F., Valente, M.A., Costa, B.F.O., Effect of annealing temperature on structural, morphological and dielectric properties of La0.8Ba0.1Ce0.1FeO3 perovskite. J. Mater. Sci. Mater. Electron. 31:19 (2020), 16220–16234, 10.1007/s10854-020-04140-w.
Kalthoum, R., Ben Bechir, M., Ben Rhaiem, A., Gargouri, M., MCdCl3 (M= CH3NH3,(CH3)2NH2): New Hybrid Perovskites with Large Dielectric Constants for Field-Effect Transistors. Physica Status Solidi (a), 218(24), 2021, 2100485, 10.1002/pssa.202100485.
Hastuti, E., Subhan, A., Amonpattaratkit, P., Zainuri, M., Suasmoro, S., The effects of Fe-doping on MnO2: phase transitions, defect structures and its influence on electrical properties. RSC Adv. 11:14 (2021), 7808–7823, 10.1039/D0RA10376D.
Mahani, R.M., Marzouk, S.Y., AC conductivity and dielectric properties of SiO2–Na2O–B2O3–Gd2O3 glasses. J. Alloy. Compd. 579 (2013), 394–400, 10.1016/j.jallcom.2013.05.173.
Murali, N., Margarette, S.J., Rao, V.K., Veeraiah, V., Structural, impedance, dielectric and modulus analysis of LiNi1-xy-0.02Mg0. 02CoxZnyO2 cathode materials for lithium-ion batteries. J. Sci.: Adv. Mater. Devices 2:2 (2017), 233–244, 10.1016/j.jsamd.2017.04.004.
Saha, B.C., Bera, A.K., Yusuf, S.M., Mechanism of Na-Ion Conduction in the Highly Efficient Layered Battery Material Na2Mn3O7. ACS Appl. Energy Mater. 4:6 (2021), 6040–6054, 10.1021/acsaem.1c00825.
L.C. Costa, S.S. Teixeira, M. Graça, Structural, morphologic and dielectric properties of sodium ferrites, in: AIP Conference Proceedings (2019, December) (Vol. 2196, No. 1, p. 020008). AIP Publishing LLC. 10.1063/1.5140281.
Yi, T.F., Sari, H.M.K., Li, X., Wang, F., Zhu, Y.R., Hu, J., Li, X., A review of niobium oxides based nanocomposites for lithium-ion batteries, sodium-ion batteries and supercapacitors. Nano Energy, 85, 2021, 105955, 10.1016/j.nanoen.2021.105955.