[en] The catalytic behavior of La0.4Sr0.6MnO3 (PM3), La0.8Sr0.2MnO3 (PM2), and LaMnO3 (PM1) has been studied in the oxidation of natural terpenes (α-pinene, β-pinene, limonene, and valencene) in water. To find the best catalytic performance, several parameters were investigated such as the catalyst amount, the nature of the oxidant agent, the oxidant ratio, the temperature, the reaction time, and the nature of the solvent with the α-pinene as the model substrate. PM3 catalyst exhibited the best activity in the oxidation reaction using hydrogen peroxide as an oxidant agent giving a good yield towards verbenone with 50%. The recyclability of the catalyst performances showed remarkable stability after four cycles. Moreover, the photocatalytic mechanism of α-pinene using La1−xSrxMnO3 catalyst was performed through the density functional theory method, and the possible attack site for the photocatalytic reaction between α-pinene and the hydroperoxyl radical (⋅OOH) was predicted using the condensed Fukui function and obtained findings are in good agreement with the experimental results.
Disciplines :
Chemistry
Author, co-author :
Hasnaoui, Ali; Molecular Chemistry Laboratory, Unity of Coordination and Catalysis Chemistry, Faculty of Sciences Semlalia (UCA-FSSM), Cadi Ayyad University, Marrakech, Morocco
Nayad, Abdallah; Molecular Chemistry Laboratory, Unity of Coordination and Catalysis Chemistry, Faculty of Sciences Semlalia (UCA-FSSM), Cadi Ayyad University, Marrakech, Morocco
Fkhar, Lahcen ; Université de Liège - ULiège > Complex and Entangled Systems from Atoms to Materials (CESAM) ; Molecular Chemistry Laboratory, Unity of Coordination and Catalysis Chemistry, Faculty of Sciences Semlalia (UCA-FSSM), Cadi Ayyad University, Marrakech, Morocco
Louroubi, Abdelhadi; Molecular Chemistry Laboratory, Unity of Coordination and Catalysis Chemistry, Faculty of Sciences Semlalia (UCA-FSSM), Cadi Ayyad University, Marrakech, Morocco
Mahmoud, Abdelfattah ; Université de Liège - ULiège > Département de chimie (sciences) > Chimie inorganique structurale et Chimie des matériaux inorganiques (LCIS-GreenMAT)
Boschini, Frédéric ; Université de Liège - ULiège > Département de chimie (sciences) > Plateforme APTIS (Advanced Powder Technology and Innovative Solutions)
Mounkachi, Omar; Laboratory of Condensed Matter and Interdisciplinary Sciences (LaMCScI), Faculty of Science, Mohammed V University, Rabat, Morocco
bahsis, Lahoucine; Laboratory of Analytical and Molecular Chemistry, Polydisciplinary Faculty, Cadi Ayyad University, Safi, Morocco
El firdoussi, Larbi; Molecular Chemistry Laboratory, Unity of Coordination and Catalysis Chemistry, Faculty of Sciences Semlalia (UCA-FSSM), Cadi Ayyad University, Marrakech, Morocco
Ait Ali, Mustapha; Molecular Chemistry Laboratory, Unity of Coordination and Catalysis Chemistry, Faculty of Sciences Semlalia (UCA-FSSM), Cadi Ayyad University, Marrakech, Morocco
Language :
English
Title :
Oxyfunctionalization of natural terpenes catalyzed by La1−xSrxMnO3 in water as solvent: an experimental and theoretical study
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