Laser control in a bifurcating region

[en] We present a complete analysis of the laser control of a model molecular system using both optimal control theory and adiabatic techniques. This molecule has a particular potential energy surface with a bifurcating region connecting three potential wells which allows a variety of processes such as isomerization, tunneling, or implementation of quantum gates on one or two qubits. The parameters of the model have been chosen so as to reproduce the main features of H3CO which is a molecule benchmark for such dynamics. We show the feasibility of different processes and we investigate their robustness against variations of laser field. We discuss the conditions under which each method of control gives the best results. We also point out the relation between optimal control theory and local control.

Disciplines :

Chemistry
Physics
Electrical & electronics engineering

Author, co-author :

Sugny, Dominique

Kontz, Cyrill

Ndong, Mamadou

Justum, Yves

Dive, Georges ; Université de Liège - ULiège > Centre d'ingénierie des protéines

Desouter, Michèle ; Université de Liège - ULiège > Département de chimie (sciences) > Département de chimie (sciences)

Language :

English

Title :

Laser control in a bifurcating region

Publication date :

October 2006

Journal title :

Physical Review. A, Atomic, molecular, and optical physics

ISSN :

1050-2947

eISSN :

1094-1622

Publisher :

American Physical Soc, College Pk, United States - Maryland

Volume :

Issue :

Pages :

043419 1-14

Peer reviewed :

Peer Reviewed verified by ORBi

Available on ORBi :

since 28 November 2009

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