Hybrid Microcapsules for Encapsulation and Controlled Release of Rosemary Essential Oil

Berraaouan, Doha; Essifi, Kamal; Addi, Mohamed; Hano, Christophe; Fauconnier, Marie-Laure; Tahani, Abdesselam

doi:10.3390/polym15040823

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Hybrid Microcapsules for Encapsulation and Controlled Release of Rosemary Essential Oil

Berraaouan, Doha; Essifi, Kamal; Addi, Mohamed et al.

2023 • In Polymers, 15, p. 823

Peer Reviewed verified by ORBi

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https://hdl.handle.net/2268/299829

DOI
10.3390/polym15040823

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Keywords :

hybrids; clay; sodium alginate; rosemary essential oil; controlled release; encapsulation

Abstract :

[en] Abstract: The foremost objective of this work is to assess the microcapsules composition (polymerbased and polymer/clay-based) effect, on the release of rosemary essential oil into w/o medium and evaluate their antioxidant activity. Calcium alginate (CA) and calcium alginate/montmorillonite hybrid (CA-MTN) microcapsules were developed following an ionotropic crosslinking gelation and were used as host materials for the encapsulation of rosemary essential oil. The unloaded/loaded CA and hybrid CA-MTN microcapsules were characterized by Fourier transform infra-red (FT-ATR) spectroscopy, thermal analysis (TGA), scanning electron microscopy (SEM) and DPPH assay. The evaluation of the microcapsule’s physicochemical properties has shown that the clay filling with montmorillonite improved the microcapsule’s properties. The encapsulation efficiency improved significantly in hybrid CA-MTN microcapsules and exhibited higher values ranging from 81 for CA to 83% for hybrid CA-MTN and a loading capacity of 71 for CA and 73% for hybrid CA-MTN, owing to the large adsorption capacity of the sodic clay. Moreover, the hybrid CA-MTN microcapsules showed a time-extended release of rosemary essential oil compared to CA microcapsules. Finally, the DPPH assay displayed a higher reduction of free radicals in hybrid CA-MNT-REO (12.8%) than CA-REO (10%) loaded microcapsules. These results proved that the clay–alginate combination provides microcapsules with enhanced properties compared to the polymer-based microcapsules.

Research Center/Unit :

CNRST

Disciplines :

Agriculture & agronomy
Chemistry

Author, co-author :

Berraaouan, Doha; Physical Chemistry of Natural Substances and Process Research Team, Laboratory of Applied Chemistry and Environment (LCAE-CPSUNAP), Faculty of Sciences, Université Mohamed Premier, BV Mohammed VI, Oujda, Morocco

Essifi, Kamal; Physical Chemistry of Natural Substances and Process Research Team, Laboratory of Applied Chemistry and Environment (LCAE-CPSUNAP), Faculty of Sciences, Université Mohamed Premier, BV Mohammed VI, Oujda, Morocco

Addi, Mohamed; Laboratoire d'Amélioration des Productions Agricoles, Biotechnologie et Environnement (LAPABE), Faculty of Sciences, Université Mohamed Premier, BV Mohammed VI, Oujda, Morocco

Hano, Christophe; Laboratoire de Biologie des Ligneux et des Grandes Cultures, INRAE USC1328, Campus Eure et Loir, Orleans University, Chartres, France

Fauconnier, Marie-Laure ; Université de Liège - ULiège > TERRA Research Centre > Chimie des agro-biosystèmes

Tahani, Abdesselam; Physical Chemistry of Natural Substances and Process Research Team, Laboratory of Applied Chemistry and Environment (LCAE-CPSUNAP), Faculty of Sciences, Université Mohamed Premier, BV Mohammed VI, Oujda, Morocco

Language :

English

Title :

Hybrid Microcapsules for Encapsulation and Controlled Release of Rosemary Essential Oil

Publication date :

07 February 2023

Journal title :

Polymers

ISSN :

2073-4360

Publisher :

MDPI Open Access Publishing, Switzerland

Volume :

Pages :

823

Peer reviewed :

Peer Reviewed verified by ORBi

Additional URL :

https://www.mdpi.com/2073-4360/15/4/823

Name of the research project :

ANPMA/CNRST/UMP- 247/20

Funders :

Morocco and Mohamed Premier University

Funding number :

PPR15-

Available on ORBi :

since 08 February 2023

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