[en] Hydrogen sulfide is a toxic, highly corrosive and pollutant gas, but also a key-biomarker in disease diagnosis trough breath analysis. Its detection at very low level is therefore relevant and can be achieved with chemiresistors. The present works proposes a solution consisting in a facile synthesis of CuOloaded SnO2 hollow nanospheres deposited on interdigitated electrodes (IDEs). Synthesis, chemical and electrical characterization,
deposit process of the sensing layer and gas sensing capabilities of the sensing platform are presented. CuO loaded SnO2 sensing platforms achieved a successful sub-ppm detection at an operating temperature of 100 degrees Celsius.
de Leuze, Oriane; IMCN, Université Catholique de Louvain,Louvain-La-Neuve,Belgium
Danlee, Yann; ICTEAM, Université Catholique de Louvain,Louvain-La-Neuve,Belgium
Tang, Xiaohui; ICTEAM, Université Catholique de Louvain,Louvain-La-Neuve,Belgium
Mahy, Julien ; Université de Liège - ULiège > Department of Chemical Engineering > Nanomaterials, Catalysis, Electrochemistry ; Université, de Lié,ge,Department of Chemical Engineering,Lié,ge,Belgium
Walewyns, Thomas; ICTEAM, Université Catholique de Louvain,Louvain-La-Neuve,Belgium
Raskin, Jean-Pierre; ICTEAM, Université Catholique de Louvain,Louvain-La-Neuve,Belgium
Hermans, Sophie; IMCN, Université Catholique de Louvain,Louvain-La-Neuve,Belgium
Francis, Laurent A.; ICTEAM, Université Catholique de Louvain,Louvain-La-Neuve,Belgium
Language :
English
Title :
Sub-ppm detection of H2S with CuO-loaded SnO2 hollow nanospheres deposited on interdigitated electrodes
Publication date :
10 June 2022
Event name :
2022 IEEE International Symposium on Olfaction and Electronic Nose (ISOEN)
Event place :
Aveiro, Portugal
Event date :
Du 29 mai au 1 juin 2022
Audience :
International
Main work title :
2022 IEEE International Symposium on Olfaction and Electronic Nose (ISOEN)
T. L. Guidotti, "Hydrogen Sulfide: Advances in Understanding Human Toxicity, " International Journal of Toxicology, vol 29, no 6, bll 569-581, 2010.
A. Mirzaei, S. S. Kim, en H. W. Kim, "Resistance-based H2S gas sensors using metal oxide nanostructures: A review of recent advances, " Journal of Hazardous Materials, vol 357, bll 314-331, 2018.
J.-W. Yoon en J.-H. Lee, "Toward breath analysis on a chip for disease diagnosis using semiconductor-based chemiresistors: Recent progress and future perspectives, " Lab Chip, vol 17, 09 2017.
G. Dutta Banik et al., "Hydrogen sulphide in exhaled breath: A potential biomarker for small intestinal bacterial overgrowth in IBS, " Journal of breath research, vol 10, bl 026010, 05 2016.
N. Alizadeh, H. Jamalabadi, en F. Tavoli, "Breath Acetone Sensors as Non-Invasive Health Monitoring Systems: A Review, " IEEE Sensors Journal, vol PP, bll 1-1, 09 2019.
M. Nakhleh, M. Quatredeniers, en H. Haick, "Detection of Halitosis in Breath: Between the Past, Present and Future, " Oral diseases, vol 24, 06 2017.
X. Liu, S. Cheng, H. Liu, S. Hu, D. Zhang, en H. Ning, "A Survey on Gas Sensing Technology, " Sensors (Basel, Switzerland), vol 12, bll 9635-9665, 12 2012.
A. Rydosz, "Sensors for Enhanced Detection of Acetone as a Potential Tool for Noninvasive Diabetes Monitoring, " Sensors, vol 18, no 7, 2018.
K.-I. Choi, H.-J. Kim, Y. C. Kang, en J.-H. Lee, "Ultraselective and ultrasensitive detection of H2S in highly humid atmosphere using CuO-loaded SnO2 hollow spheres for real-time diagnosis of halitosis, " Sensors and Actuators B: Chemical, vol 194, bll 371-376, 2014.
Z. Boroun, M. Ghorbani, R. Mohammadpour, en A. Moosavi, "Importance of N-P-N Junction in H2S Sensing Process of SnO2-CuO Heterostructures: A Theoretical Macroscopic Approach, " IEEE Sensors Journal, vol 21, no 6, bll 7123-7129, 2021.
L. Patil en D. Patil, "Heterocontact Type CuO-Modified SnO2 Sensor for the Detection of a ppm Level H2S Gas at Room Temperature, " Sensors and Actuators B-chemical-SENSOR ACTUATOR B-CHEM, vol 120, bll 316-323, 12 2006.
G. Sarala Devi, S. Manorama, en V. J. Rao, "High sensitivity and selectivity of an SnO2 sensor to H2S at around 100C, " Sensors and Actuators B: Chemical, vol 28, no 1, bll 31-37, 1995.
Q. Zhao, Y. Gao, X. Bai, C. Wu, en Y. Xie, "Facile Synthesis of SnO2 Hollow Nanospheres and Applications in Gas Sensors and Electrocatalysts, " European Journal of Inorganic Chemistry, vol 2006, bll 1643-1648, 04 2006.
K. Persson, "Materials Data on SnO2 (SG: 136) by Materials Project". 07 2014.
P. Jacobs, A. R. Varlan, en W. M. C. Sansen, "Design optimisation of planar electrolytic conductivity sensors, " Medical and Biological Engineering and Computing, 1995.
P. Leangtanom et al., "Highly sensitive and selective sensing of H2S gas using precipitation and impregnation-made CuO/SnO2 thick films, " Nanoscale Research Letters, 01 2021.