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Ruthenium benzylidene and benzylidyne complexes: Alkene metathesis catalysis
Nechmad, Noy B.; Lemcoff, N. Gabriel; Delaude, Lionel
2022In Parkin, Gerard; Meyer, Karsten; O'Hare, Dermot (Eds.) Comprehensive Organometallic Chemistry IV
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Keywords :
Alkylidene; Alkylidyne; Benzylidene; Benzylidyne; Grubbs Catalyst; N-Heterocyclic Carbene; Nitrogen Chelate; Olefin Metathesis; Oxygen Chelate; Phosphine Ligand; Propenylidene; Pyridine Ligand; Selenium Chelate; Sulfur Chelate
Abstract :
[en] This chapter surveys the various types of ruthenium benzylidene complexes that were described in the literature within the years 1995–2021. The emphasis is placed on their synthesis, characterization, and chemical reactivity rather than their catalytic activity. Some remarkable structure/activity relationships that helped tailoring the coordination sphere of the metal center through ligand design in order to achieve the highest possible activities and selectivities toward various kinds of olefin metathesis reactions are nonetheless highlighted. A brief overview of the few ruthenium benzylidyne complexes that have been reported thus far is also included.
Disciplines :
Chemistry
Author, co-author :
Nechmad, Noy B.
Lemcoff, N. Gabriel
Delaude, Lionel  ;  Université de Liège - ULiège > Molecular Systems (MolSys)
Language :
English
Title :
Ruthenium benzylidene and benzylidyne complexes: Alkene metathesis catalysis
Publication date :
2022
Main work title :
Comprehensive Organometallic Chemistry IV
Author, co-author :
Parkin, Gerard
Meyer, Karsten
O'Hare, Dermot
Publisher :
Elsevier, Amsterdam, Netherlands
ISBN/EAN :
9780128202067
Pages :
528-563
Peer reviewed :
Editorial reviewed
Available on ORBi :
since 14 June 2022

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