[en] Free tropospheric HCN columns have been derived from infrared solar spectra recorded with the National Solar Observatory Fourier transform spectrometer on Kitt Peak, Arizona (31.9ºN latitude, 111.6ºW longitude, 2.09 km altitude) between May 1978 and May 2000. The time series show up to a factor of 2.4 enhancement during the strong El Ninos of 1982-1983 and 1997-1998, the most intense since 1970. The observations provide confirmation that HCN is a sensitive tracer of biomass burning emissions transported to the free troposphere. No statistically significant long-term trend in the HCN-free tropospheric column has been detected over the 22-year measurement period. The results illustrate the importance of long-term spectroscopic measurements for quantifying climate and atmospheric chemistry-related atmospheric changes.
Disciplines :
Earth sciences & physical geography
Author, co-author :
Rinsland, Curtis P.
Goldman, Aaron
Zander, Rodolphe ; Université de Liège - ULiège > Services généraux (Faculté des sciences) > Relations académiques et scientifiques (Sciences)
Mahieu, Emmanuel ; Université de Liège - ULiège > Département d'astrophys., géophysique et océanographie (AGO) > Groupe infra-rouge de phys. atmosph. et solaire (GIRPAS)
Language :
English
Title :
Enhanced tropospheric HCN columns above Kitt Peak during the 1982-1983 and 1997-1998 El Nino warm phases
Publication date :
2001
Journal title :
Journal of Quantitative Spectroscopy and Radiative Transfer
ISSN :
0022-4073
Publisher :
Pergamon Press - An Imprint of Elsevier Science, Oxford, United Kingdom
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Bibliography
Malingreau J.P., Stephens G., Fellows L. (1985) Remote sensing of forest fires: Kalimantan and north Borneo. Ambio 14:314-320.
Matsueda H., Inoue H.Y., Ishii M., Tsutsumi Y. (1999) Large injection of carbon monoxide into the upper troposphere due to intense biomass burning in 1997. J Geophys Res 104(26):867-879.
Rinsland C.P., Goldman A., Murcray F.J., Stephen T.M., Pougatchev N.S., Fishman J., David S.J., Blatherwick R.D., Novelli P.C., Jones N.B., Connor B.J. (1999) Infrared solar spectroscopic measurements of free tropospheric CO, C2H6, and HCN above Mauna Loa, Hawaii: Seasonal variations and evidence for enhanced emissions from the southeast Asian tropical fires of 1997-1998. J Geophys Res 104(18):667-680.
Rinsland C.P., Gunson M.R., Wang P.H., Arduini R.F., Baum B.A., Minnis P., Goldman A., Abrams M.C., Baum B.A., Minnis P., Zander R., Mahieu E., Salawitch R.J., Michelsen H.A., Irion F.W., Newchurch M.J. (1998) ATMOS/ATLAS 3 infrared profile measurements of trace gases in the November 1994 tropical and subtropical upper troposphere. JQSRT 60:891-901.
Notholt J., Toon G.C., Rinsland C.P., Pougatchev N.S., Jones N.B., Connor B.J., Weller R., Gautrois M., Schrems O. (2000) Latitudinal variations of trace gas concentrations in the free troposphere measured by solar absorption spectroscopy during a ship cruise. J Geophys Res 105:1337-1349.
Rinsland C.P., Mahieu E., Zander R., Demoulin P., Forrer J., Buchmann B. (2000) Free tropospheric CO, C2 H6, and HCN above central Europe: Recent measurements from the Jungfraujoch station including the detection of enhanced columns during 1998. J Geophys Res 105(24):235-249.
Zhao Y., Kondo Y., Murcray F.J., Liu X., Koike M., Irie H., Strong K., Suzuki K., Sera M., Ikegami Y. (2000) Seasonal variations of HCN over northern Japan measured by ground-based infrared solar spectroscopy. Geophys Res Lett 27:2085-2088.
Lobert J.M., Scharffe D.H., Hao W.M., Kuhlbusch A., Seuwen W., Crutzen P.J. (1991) Experimental evaluation of biomass burning emissions: Nitrogen and carbon containing compounds. Global Biomass Burning: Atmospheric, Climatic and Biospheric Implications, Section IV, Biomass Burning: Laboratory Studies , Levine, JS, editor. Cambridge, MA: MIT Press; 289-304.
Lobert J., Scharffe, Hao W.M., Crutzen P.J. (1990) Importance of biomass burning in the atmospheric budgets of nitrogen-containing gases. Nature 346:552-554.
Yokelsen R.L., Susott R., Ward D.E., Reardon J., Griffith D.W.T. (1997) Emissions from smoldering combustion of biomass measured by open-path Fourier transform infrared spectroscopy. J Geophys Res 102(18):865-877.
Li Q., Jacob D.J., Bey I., Yantosca R.M., Zhao Y., Kondo Y., Notholt J. (2000) Atmospheric hydrogen cyanide (HCN): Biomass burning source, ocean sink?. Geophys Res Lett 27:357-360.
Pougatchev N.S., Connor B.J., Rinsland C.P. (1985) Infrared measurements of the ozone vertical distribution above Kitt Peak. J Geophys Res 100(16):689-697.
Rinsland C.P., Jones N.B., Connor B.J., Logan J.A., Pougatchev N.S., Goldman A., Murcray F.J., Stephen T.M., Pine A.S., Zander R., Mahieu E., Demoulin P. (1998) Northern and southern hemisphere ground-based infrared spectroscopic measurements of tropospheric carbon monoxide and ethane. J Geophys Res 103(28):197-217.
Rothman L.S., Rinsland C.P., Goldman A., Massie S.T., Edwards D.P., Flaud J.M., Perrin A., Camy-Peyret C., Dana V., Mandin J.Y., Schroeder J., McCann A., Gamache R.R., Wattson R.B., Yoshino K., Chance K.V., Jucks K.W., Brown L.R., Nemtchinov V., Varanasi P. (1998) The HITRAN molecular spectroscopic database and HAWKS (HITRAN Atmospheric Workstation): 1996 edition. JQSRT 60:655-710.
Rothman L.S., Goldman A., Gillis J.R., Gamache R.R., Pickett H.M., Poynter R.L., Husson N., Chedin A. (1983) AFGL trace gas compilation: 1982 edition. Appl Opt 22:1616-1624.
Rothman L.S., Gamache R.R., Goldman A., Brown L.R., Toth R.A., Pickett H.M., Poynter R.L., Flaud J.M., Camy-Peyret C., Barbe A., Husson N., Rinsland C.P., Smith M.A.H. (1987) The HITRAN database: 1986 edition. Appl Opt 26:4058-4097.
Smith M.A.H., Harvey G.A., Pellett G.L., Goldman A., Richardson D.J. (1984) Measurements of the HCN v3 band broadened by N2. J Mol Spectrosc 105:105-112.
Mahieu E., Rinsland C.P., Zander R., Demoulin P., Delbouille L., Roland G. (1995) Vertical column abundances of HCN deduced from ground-based infrared solar spectra: Long-term trend and variability. J Atmos Chem 20:299-310.
Rinsland C.P., Smith M.A.H., Rinsland P.L., Goldman A., Brault J.W., Stokes G.M. (1982) Ground-based infrared spectroscopic measurements of atmospheric hydrogen cyanide. J Geophys Res 87(11):119-125.
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