Orientation of Thiophenol Adsorbed on Silver Determined by Nonlinear Vibrational Spectroscopy of the Carbon Skeleton

[en] The orientation of thiophenol adsorbed on silver is determined by comparing ab initio calculated and experimental sum-frequency generation (SFG) spectra measured between 9 and 20 µm using a tandem KTP/CdSe optical parametric oscillator. The molecule S-C bond is tilted ~37° from the surface normal with the aromatic ring plane perpendicular to the surface.

Disciplines :

Physics

Author, co-author :

Mani, A. A.

Schultz, Z. D.

Caudano, Y.

Champagne, B.

Humbert, C.

Dreesen, Laurent ; Université de Liège - ULiège > Département de physique > Biophotonique

Gewirth, A. A.

White, J. O.

Thiry, P. A.

Peremans, A.

Language :

English

Title :

Orientation of Thiophenol Adsorbed on Silver Determined by Nonlinear Vibrational Spectroscopy of the Carbon Skeleton

Publication date :

2004

Journal title :

Journal of Physical Chemistry B

ISSN :

1520-6106

eISSN :

1520-5207

Publisher :

American Chemical Society, Washington, United States - District of Columbia

Volume :

108

Pages :

16135-16138

Peer reviewed :

Peer Reviewed verified by ORBi

Available on ORBi :

since 26 October 2009

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