Flow neutralisation of sulfur-containing chemical warfare agents with Oxone: packed bed vs. aqueous solution

Delaune, A; Mansour, S; Picard, B; Carrasqueira, P; Chataigner, I; Jean, L; Renard, P.-Y.; Monbaliu, Jean-Christophe; Legros, Julien

doi:10.1039/D1GC00449B

Request a copy

Article (Scientific journals)

Flow neutralisation of sulfur-containing chemical warfare agents with Oxone: packed bed vs. aqueous solution

Delaune, A; Mansour, S; Picard, B et al.

2021 • In RSC Green Chemistry, 23, p. 2925-2930

Peer reviewed

Permalink
https://hdl.handle.net/2268/261112

DOI
10.1039/D1GC00449B

Files (1)Send to Details Statistics Bibliography Similar publications

Files

Full Text

21GC2925.pdf

Publisher postprint (950.15 kB)

Request a copy

All documents in ORBi are protected by a user license.

Send to

RIS BibTex APA Chicago Permalink X Linkedin

Details

Keywords :

Oxidative neutralization; Chemical warfare agents; Continuous flow process

Abstract :

[en] The oxidative neutralisation of sulfur-containing CWAs (yperite and VX simulants) with Oxone has been developed in flow systems. In order to reach full selectivity towards harmless decomposition products, Oxone has to be used either in solid form (blister agent detoxification) or aqueous form (nerve agent detoxification).

Disciplines :

Chemistry

Author, co-author :

Delaune, A; Normandie Université

Mansour, S; Normandie Université

Picard, B; Normandie Université

Carrasqueira, P; Normandie Université

Chataigner, I; Normandie Université

Jean, L; Normandie Université

Renard, P.-Y.; Normandie Université

Monbaliu, Jean-Christophe ; Université de Liège - ULiège > Département de chimie (sciences) > CITOS

Legros, Julien; Normandie Université

Language :

English

Title :

Flow neutralisation of sulfur-containing chemical warfare agents with Oxone: packed bed vs. aqueous solution

Publication date :

2021

Journal title :

RSC Green Chemistry

ISSN :

1757-7039

eISSN :

1757-7047

Publisher :

Royal Society of Chemistry, London, United Kingdom

Volume :

Pages :

2925-2930

Peer reviewed :

Peer reviewed

Additional URL :

https://doi.org/10.1039/D1GC00449B

Available on ORBi :

since 17 June 2021

Statistics

Number of views

84 (4 by ULiège)

Number of downloads

4 (3 by ULiège)

More statistics

Scopus citations^®

Scopus citations^®
without self-citations

OpenCitations

OpenAlex citations

Bibliography

D. Hafemeister, Nuclear Proliferation and Terrorism in the Post-9/11 World, Springer International Publishing, Cham, 2016, 337-351
M. Peplow, Chem. Eng. News, 2018, 96, 3
H. John, M. J. van der Schans, M. Koller, H. E. T. Spruit, F. Worek, H. Thiermann, D. Noort, Forensic Toxicol. 2018, 36, 61, 71
G. Mercey, T. Verdelet, J. Renou, M. Kliachyna, R. Baati, F. Nachon, L. Jean, P.-Y. Renard, Acc. Chem. Res. 2012, 45, 756, 766
X. Li, J. Dong, H. Liu, X. Sun, Y. Chi, C. Hu, J. Hazard. Mater. 2018, 344, 994, 999
I. A. Fallis, P. C. Griffiths, T. Cosgrove, C. A. Dreiss, N. Govan, R. K. Heenan, I. Holden, R. L. Jenkins, S. J. Mitchell, S. Notman, J. A. Platts, J. Riches, T. Tatchell, J. Am. Chem. Soc. 2009, 131, 9746, 9755
G. W. Wagner, L. R. Procell, Y.-C. Yang, C. A. Bunton, Langmuir, 2001, 17, 4809, 4811
F. Gonzaga, E. Perez, I. Rico-Lattes, A. Lattes, New J. Chem. 2001, 25, 151, 155
Y.-C. Yang, Acc. Chem. Res. 1999, 32, 109, 115
Y. C. Yang, L. L. Szafraniec, W. T. Beaudry, D. K. Rohrbaugh, J. Am. Chem. Soc. 1990, 112, 6621, 6627
B. Smolkin, N. Levi, N. Karton-Lifshin, L. Yehezkel, Y. Zafrani, I. Columbus, J. Org. Chem. 2018, 83, 13949, 13955
N. Karton-Lifshin, S. Katalan, I. Columbus, R. Chen, L. Yehezkel, M. Madmon, S. Dagan, S. Elias, G. Fridkin, Y. Zafrani, Chem. Commun. 2019, 55, 12471, 12474
B. Picard, K. Pérez, T. Lebleu, D. Vuluga, F. Burel, D. C. Harrowven, I. Chataigner, J. Maddaluno, J. Legros, J. Flow Chem. 2020, 10, 139, 143
K. Pérez, B. Picard, D. Vuluga, F. Burel, R. Hreiz, L. Falk, J.-M. Commenge, A. Nagaki, J. Yoshida, I. Chataigner, J. Maddaluno, J. Legros, Org. Process Res. Dev. 2020, 24, 787, 791
T. Lebleu, J. Maddaluno, J. Legros, Org. Chem. Front. 2015, 2, 324, 327
A. Nagaki, H. Kim, J. Yoshida, Angew. Chem. Int. Ed. 2009, 48, 8063, 8065
A. Nagaki, D. Ichinari, J. Yoshida, Chem. Commun. 2013, 49, 3242
J. Yoshida, A. Nagaki, T. Iwasaki, S. Suga, Chem. Eng. Technol. 2005, 28, 259, 266
H. Kim, A. Nagaki, J. Yoshida, Nat. Commun. 2011, 2, 264
H. Kim, K.-I. Min, K. Inoue, D. J. Im, D.-P. Kim, J. Yoshida, Science, 2016, 352, 691, 694
M. Movsisyan, E. I. P. Delbeke, J. K. E. T. Berton, C. Battilocchio, S. V. Ley, C. V. Stevens, Chem. Soc. Rev. 2016, 45, 4892, 4928
D. Dallinger, B. Gutmann, C. O. Kappe, Acc. Chem. Res. 2020, 53, 1330, 1341
B. Picard, B. Gouilleux, T. Lebleu, J. Maddaluno, I. Chataigner, M. Penhoat, F.-X. Felpin, P. Giraudeau, J. Legros, Angew. Chem. Int. Ed. 2017, 56, 7568, 7572
N. Emmanuel, P. Bianchi, J. Legros, J.-C. M. Monbaliu, Green Chem. 2020, 22, 4105, 4115
Y. J. Jang, K. Kim, O. G. Tsay, D. A. Atwood, D. G. Churchill, Chem. Rev. 2015, 115, PR1, PR76
T. Islamoglu, Z. Chen, M. C. Wasson, C. T. Buru, K. O. Kirlikovali, U. Afrin, M. R. Mian, O. K. Farha, Chem. Rev. 2020, 120, 8130, 8160
M. M. Y. Motamedhashemi, F. Egolfopoulos, T. Tsotsis, J. Membr. Sci. 2011, 376, 119, 131
A. A. Wang, W. Chen, A. Mulchandani, Biotechnol. Bioeng. 2005, 91, 379, 386
P.-Y. Renard, H. Schwebel, P. Vayron, L. Josien, A. Valleix, C. Mioskowski, Chem. - Eur. J. 2002, 8, 2910, 2916
H. Hussain, I. R. Green, I. Ahmed, Chem. Rev. 2013, 113, 3329, 3371
S. Popiel, Z. Witkiewicz, A. Szewczuk, J. Hazard. Mater. 2005, 123, 94, 111
B. Yu, A.-H. Liu, L.-N. He, B. Li, Z.-F. Diao, Y.-N. Li, Green Chem. 2012, 14, 957, 962
J. Yoshida, A. Nagaki, T. Iwasaki, S. Suga, Chem. Eng. Technol. 2005, 28, 259, 266
K. Midorikawa, S. Suga, J. Yoshida, Chem. Commun. 2006, 3794, 3796
H. Usutani, Y. Tomida, A. Nagaki, H. Okamoto, T. Nokami, J. Yoshida, J. Am. Chem. Soc. 2007, 129, 3046, 3047
A. Nagaki, C. Matsuo, S. Kim, K. Saito, A. Miyazaki, J. Yoshida, Angew. Chem. Int. Ed. 2012, 51, 3245, 3248
H. S. N. Lee, M. T. Sng, C. Basheer, H. K. Lee, J. Chromatogr. A, 2008, 1196-1197, 125, 132
M. Krivec, A. Pohar, B. Likozar, G. Dražić, AIChE J. 2015, 61, 572, 581
L. Suhadolnik, A. Pohar, B. Likozar, M. Čeh, Chem. Eng. J. 2016, 303, 292, 301
L. Suhadolnik, D. Lašič Jurković, B. Likozar, M. Bele, S. Drev, M. Čeh, Appl. Catal. B, 2019, 257, 117894
F. Silva, A. Baker, J. Stansall, W. Michalska, M. S. Yusubov, M. Graz, R. Saunders, G. J. S. Evans, T. Wirth, Eur. J. Org. Chem. 2018, 2134, 2137
B. Picard, I. Chataigner, J. Maddaluno, J. Legros, Org. Biomol. Chem. 2019, 17, 6528, 6537
V. Vallet, C. Cruz, J. Licausi, A. Bazire, G. Lallement, I. Boudry, Toxicology, 2008, 246, 73, 82
Y. J. Rosenberg, J. Walker, X. Jiang, S. Donahue, J. Robosky, M. Sack, J. Lees, L. Urban, Sci. Rep. 2015, 5, 13247
World Intellectual Property Organization, WO2007143127A1, 2007
J. Yoshida, H. Kim, A. Nagaki, ChemSusChem, 2011, 4, 331, 340