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Synthesis of functionalized polyesters by the "click" copper-catalyzed alkyne-azide cycloaddition
Lecomte, Philippe; Riva, Raphaël; Jérôme, Christine
2009In Khosravi, Ezat; Yagci, Yusuf; Savelyev, Yuri (Eds.) New smart materials via metal mediated macromolecular engineering
 

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The authors acknowledge Springer for allowing them to archive this paper. The original publication is available at http://www.springerlink.com/content/u54679040gkq2qp3/?p=2be6ce1d5e204f42b17375d594a3d716&pi=4


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Keywords :
ring-opening polymerization (ROP); lactone; click chemistry; copper-mediated Huisgen's cycloaddition; polymer functionalization
Abstract :
[en] The functionalization of aliphatic polyesters by the copper-mediated azide–alkyne Huisgen’s cycloaddition is very efficient under mild conditions, which prevents degradation from occurring. The implementation of this reaction requires the synthesis of aliphatic polyesters bearing pendant alkynes and azides, which can be carried out either by polycondensation or by ring-opening polymerization.
Research center :
Center for Education and Research on Macromolecules (CERM)
Disciplines :
Chemistry
Materials science & engineering
Author, co-author :
Lecomte, Philippe  ;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Riva, Raphaël ;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Jérôme, Christine  ;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Language :
English
Title :
Synthesis of functionalized polyesters by the "click" copper-catalyzed alkyne-azide cycloaddition
Publication date :
30 September 2009
Main work title :
New smart materials via metal mediated macromolecular engineering
Editor :
Khosravi, Ezat
Yagci, Yusuf
Savelyev, Yuri
Publisher :
Springer
ISBN/EAN :
978-90-481-3276-8
Collection name :
NATO Science for Peace and Security Series A: Chemistry and Biology
Pages :
77-91
Funders :
BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique
FRIA - Fonds pour la Formation à la Recherche dans l'Industrie et dans l'Agriculture [BE]
F.R.S.-FNRS - Fonds de la Recherche Scientifique [BE]
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since 05 October 2009

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