[en] This study presents an investigation of the structural, magnetic and magnetocaloric properties of the 0.95(La0.45Nd0.25)Sr0.3MnO3/0.05CuO polycrystalline composite. The investigated composite materials are elaborated by combining both solid-state reaction and spray-drying method at the pilot-scale aiming to obtain a homogeneous composite material with controlled morphology and regular particles size. The structure, microstructure, magnetism and magnetocaloric features of the synthesized materials are investigated by using several techniques such as X-ray diffraction (XRD), scanning electron microscopy (SEM) and Magnetic measurements. The XRD and SEM data confirm the co-existence of perovskite and copper oxide phases. The magnetization data unveil that the studied composite exhibits a ferromagnetic to paramagnetic transition close to room-temperature (TC = 295 K). More importantly, its magnetocaloric effect in terms of the entropy change remains similar to that of (La0.45Nd0.25)Sr0.3MnO3/0.05CuO only synthesized by the conventional solid-state reaction technique. This points out the possibility of upscaling the production of magnetocaloric oxides to industrial levels using the spray-drying technique.
Disciplines :
Chemical engineering
Author, co-author :
Fkhar, L.
Mahmoud, Abdelfattah ; Université de Liège - ULiège > Département de chimie (sciences) > LCIS - GreenMAT
Tassou, S.A., Lewis, J.S., Ge, Y.T., Hadawey, A., Chaer, I., A review of emerging technologies for food refrigeration applications. Appl. Therm. Eng. 30:4 (2010), 263–276.
Pecharsky, V.K., Gschneidner, K.A. Jr., Magnetocaloric effect and magnetic refrigeration. J. Magn. Magn. Mater. 200:April (1999), 44–56.
Bingham, N.S., Phan, M.H., Srikanth, H., Torija, M.A., Leighton, C., Magnetocaloric effect and refrigerant capacity in charge-ordered manganites. J. Appl. Phys. 23909 (2009), 1–6.
Sande, P., Hueso, L.E., Rivas, J., Large magnetocaloric effect in manganites with charge order. Appl. Phys. Lett. 2040 (2001), 11–14.
Guzik, A., Talik, E., Zajdel, P., Magnetocaloric effect of the Gd3-xTbxCo system. Intermetallics, 118, 2020, 106686.
Zhang, Y., Review of the structural, magnetic and magnetocaloric properties in ternary rare earth RE2T2X type intermetallic compounds. J. Alloys Compd. 787 (2019), 1173–1186.
Tadout, M., Lambert, C., Salah, M., Hadri, E., Benyoussef, A., Hamedoun, M., Benaissa, M., Mounkachi, O., Mangin, S., Magnetic properties and magnetocaloric effect in Gd 100–x Cox thin films. Cryst. Artic., 2019.
Zhang, Y., Guo, D., Wu, B., Wang, H., Guan, R., Li, X., Ren, Z., Magnetic properties and magneto-caloric performances in RECo2B2C (RE = Gd, Tb and Dy) compounds. J. Alloys Compd., 817, 2020.
Li, L., Yan, M., Recent progresses in exploring the rare earth based intermetallic compounds for cryogenic magnetic refrigeration. J. Alloys Compd., 823, 2020, 153810.
Li, L., Yuan, Y., Qi, Y., Wang, Q., Zhou, S., Achievement of a table-like magnetocaloric effect in the dual-phase ErZn2/ErZn composite. Mater. Res. Lett. 6:1 (2018), 67–71.
Fkhar, L., Lamouri, R., Mahmoud, A., Boschini, F., Hamedoun, M., Ez-Zahraouy, H., Benyoussef, A., Hlil, E.K., Ait Ali, M., Mounkachi, O., Enhanced magnetic and magnetocaloric properties of La0.45Nd0.25Sr0.3MnO3/CuO composite. J. Supercond. Nov. Magn., 2020.
Aoki, F.Y., Hayden, F.G., Structural, magnetic and magnetocaloric properties of EuMnO3 perovskite manganite: a comprehensive MCE study. Mater. Res. Express, 5(2), 2018, 26107.
Rostamnejadi, A., Venkatesan, M., Kameli, P., Salamati, H., Coey, J.M.D., Magnetocaloric effect in La0.67Sr0.33MnO3 manganite above room temperature. J. Magn. Magn. Mater. Room Temp. 323:16 (2011), 2214–2218.
Fan, J., Pi, L., Zhang, L., Tong, W., Ling, L., Hong, B., Shi, Y., Zhang, W., Lu, D., Zhang, Y., Magnetic and magnetocaloric properties of perovskite manganite Pr 0.55Sr0.45MnO3. Physica B 406:11 (2011), 2289–2292.
Salem, A.F., Mohamed, E.A., Study on the influence of magnetic phase transitions on the magnetocaloric effect in Sm0.7Sr0.3Mn0.95Fe0.05O3 manganite. J. Alloys Compd. 608 (2014), 180–184.
Hueso, L.E., Sande, P., Miguéns, D.R., Rivas, J., Rivadulla, F., Tuning of the magnetocaloric effect in La0.67Ca0.33MnO3−δ nanoparticles synthesized by sol–gel techniques. J. Appl. Phys. 9943 (2002), 1–6.
Ca, L., Mno, S., Li, J.Q.Ã., Sun, W.A., Ao, W.Q., Tang, J.N., Hydrothermal synthesis and Magnetocaloric effect of La0.5Ca0.3Sr0.2MnO3. J. Magn. Magn. Mater. 302 (2006), 463–466.
El Maalam, K., Balli, M., Habouti, S., Dietze, M., Hamedoun, M., Hlil, E.-K., Es-Souni, M., El Kenz, A., Benyoussef, A., Mounkachi, O., Composite (La0.45Nd0.25)Sr0.3MnO3/5CuO materials for magnetic refrigeration applications. J. Magn. Magn. Mater. 449 (2017), 25–32.
Phan, M.H., Yu, S.C., Review of the magnetocaloric effect in manganite materials. J. Magn. Magn. Mater. 308:2 (2007), 325–340.
Skini, R., Omri, A., Khlifi, M., Dhahri, E., Hlil, E.K., Large magnetocaloric effect in lanthanum-deficiency manganites La 0.8-x□xCa0.2MnO3 (0.00≤x≤0.20) with a first-order magnetic phase transition. J. Magn. Magn. Mater. 364 (2014), 5–10.
Anwar, M.S., Ahmed, F., Danish, R., Heun, B., Impact of Co3O4 phase on the magnetocaloric effect and magnetoresistance. Ceram. Int. 3 (2014), 1–7.
Pekała, M., Pekała, K., Drozd, V., Staszkiewicz, K., Fagnard, J.F., Vanderbemden, P., Magnetocaloric and transport study of poly- and nanocrystalline composite manganites La0.7Ca0.3MnO3/La0.8Sr0.2MnO3. J. Appl. Phys., 112(2), 2012.
Fkhar, L., Mounkachi, O., El Maalam, K., Hamedoun, M., Boschini, F., El Kenz, A., Ait Ali, M., Hlil, E.K., Xiao, Y., Benyoussef, A., Large magnetic entropy change in Pr2/3Sr1/3MnO3-CuO composite at room temperature. J. Supercond. Nov. Magn. 32 (2019), 3579–3585.
Nasri, M., Khelifi, J., Triki, M., Dhahri, E., Hlil, E.K., Impact of CuO phase on magnetocaloric and magnetotransport properties of La0.6Ca0.4MnO3 ceramic composites. J. Alloys Compd. 678 (2016), 427–433.
Gharsallaoui, A., Roudaut, G., Chambin, O., Voilley, A., Saurel, R., Applications of spray-drying in microencapsulation of food ingredients: An overview. Food Res. Int. 40:9 (2007), 1107–1121.
Ting, J.M., Porter, W.W., Mecca, J.M., Bates, F.S., Reineke, T.M., Advances in polymer design for enhancing oral drug solubility and delivery. Bioconjug. Chem. 29:4 (2018), 939–952.
Mahmoud, A., Caes, S., Brisbois, M., Hermann, R.P., Berardo, L., Schrijnemakers, A., Malherbe, C., Eppe, G., Cloots, R., Vertruyen, B., Boschini, F., Spray-drying as a tool to disperse conductive carbon inside Na2FePO4F particles by addition of carbon black or carbon nanotubes to the precursor solution. J. Solid State Electrochem. 22:1 (2018), 103–112.
Brisbois, M., Caes, S., Sougrati, M.T., Vertruyen, B., Schrijnemakers, A., Cloots, R., Eshraghi, N., Hermann, R.P., Mahmoud, A., Boschini, F., Na2FePO4F/multi-walled carbon nanotubes for lithium-ion batteries: Operando Mössbauer study of spray-dried composites. Sol. Energy Mater. Sol. Cells 148 (2016), 67–72.
Brisbois, M., Krins, N., Hermann, R.P., Schrijnemakers, A., Cloots, R., Vertruyen, B., Boschini, F., Spray-drying synthesis of Na2FePO4F/carbon powders for lithium-ion batteries. Mater. Lett. 130 (2014), 263–266.
Mabrouki, W., Krichene, A., Chniba Boudjada, N., Boujelben, W., Sintering temperature effect on the magnetic properties of Pr0.67Sr0.33MnO3 manganite. Appl. Phys. A Mater. Sci. Process. 126:3 (2020), 1–12.
Park, J., Vescovo, E., Kim, H., Kwon, C., Ramesh, R., Venkatesan, T., Magnetic properties at surface boundary of a half-metallic ferromagnet La0.7Sr0.3MnO3. Phys. Rev. Lett. 81:9 (1998), 1953–1956.
Banerjee, S.K., On a generalized approach to first and second order magnetic transitions. Phys. Lett. 12 (1964), 16–17.
Chen, W., Nie, L.Y., Zhong, W., Shi, Y.J., Hu, J.J., Li, A.J., Du, Y.W., Magnetocaloric effect in Nd doped perovskite La0.7-xNd xBa0.3MnO3 polycrystalline near room temperature. J. Alloys Compd. 395:1–2 (2005), 23–25.
Dhahri, J., Mnefgui, S., Ben Hassine, A., Tahri, T., Oumezzine, M., Hlil, E.K., Behavior of the magnetocaloric effect in La0.7Ba0.2Ca0.1Mn1-xSnxO3 manganite oxides as promising candidates for magnetic refrigeration. Phys. B Phys. Condens. Matter, 2018.
El Maalam, K., Fkhar, L., Hamedoun, M., Mahmoud, A., Boschini, F., Hlil, E.K., Benyoussef, A., Mounkachi, O., Magnetocaloric properties of zinc-nickel ferrites around room temperature. J. Supercond. Nov. Magn. 30 (2017), 1943–1947.
Oumezzine, E., Hcini, S., Baazaoui, M., Hlil, E.K., Oumezzine, M., Structural, magnetic and magnetocaloric properties of Zn0.6-xNixCu0.4Fe2O4 ferrite nanoparticles prepared by Pechini sol-gel method. Powder Technol. 278 (2015), 189–195.
Anwar, M.S., Ahmed, F., Koo, B.H., Enhanced relative cooling power of Ni1−xZnxFe2O4 (0.0≤x≤0.7) ferrites. Acta Mater. 71 (2014), 100–107.
Fkhar, L., Mahmoud, A., Boschini, F., Hamedoun, M., Benyoussef, A., Hlil, E.K., Ait Ali, M., Mounkachi, O., Structural, magnetic, and magnetocaloric properties in rare earth orthochromite (Sm, Nd, and La)CrO3 for cooling product. J. Supercond. Nov. Magn. 33 (2020), 1023–1030.
Saw, A.K., Channagoudra, G., Hunagund, S., Hadimani, R.L., Dayal, V., Study of transport, magnetic and magnetocaloric properties in Sr2+ substituted praseodymium manganite. Mater. Res. Express, 7, 2019, 16105.
Wang, G.F., Li, L.R., Zhao, Z.R., Yu, X.Q., Zhang, X.F., Structural and magnetocaloric effect of Ln0.67Sr0.33MnO3 (Ln=La, Pr and Nd) nanoparticles. Ceram. Int. 40:PB (2014), 16449–16454.
Luo, Q., Zhao, D.Q., Pan, M.X., Wang, W.H., Magnetocaloric effect of Ho-, Dy-, and Er-based bulk metallic glasses in helium and hydrogen liquefaction temperature range. Appl. Phys. Lett., 211903, 2007, 2014.