Transition‐Metal‐Catalysed Reactions of Diazoesters. Insertion into C‐H Bonds of Paraffins Catalysed by Bulky Rhodium(II) Carboxylates: Enhanced Attack on Primary C‐H Bonds

Demonceau, Albert; Noels, Alfred; Hubert, André J.; Teyssié, Philippe

doi:10.1002/bscb.19840931103

Article (Scientific journals)

Transition‐Metal‐Catalysed Reactions of Diazoesters. Insertion into C‐H Bonds of Paraffins Catalysed by Bulky Rhodium(II) Carboxylates: Enhanced Attack on Primary C‐H Bonds

Demonceau, Albert; Noels, Alfred; Hubert, André J. et al.

1984 • In Bulletin des Sociétés Chimiques Belges, 93 (11), p. 945-948

Peer reviewed

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https://hdl.handle.net/2268/243004

DOI
10.1002/bscb.19840931103

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Abstract :

[en] Rhodium(II) carboxylates associated with bulky ligands catalyse the insertion of carbalkoxycarbenes (generated from diszoesters) into C‐H bonds of normal and branched alkanes with selectivities differing substantially from those associated with non‐bulky carboxylates. Copyright © 1984 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim

Disciplines :

Chemistry

Author, co-author :

Demonceau, Albert ; Université de Liège - ULiège > Département de chimie (sciences) > Département de chimie (sciences)

Noels, Alfred ; Université de Liège - ULiège > Relations académiques et scientifiques (Sciences)

Hubert, André J.

Teyssié, Philippe ; Université de Liège - ULg

Language :

English

Title :

Transition‐Metal‐Catalysed Reactions of Diazoesters. Insertion into C‐H Bonds of Paraffins Catalysed by Bulky Rhodium(II) Carboxylates: Enhanced Attack on Primary C‐H Bonds

Publication date :

1984

Journal title :

Bulletin des Sociétés Chimiques Belges

ISSN :

0037-9646

Publisher :

John Wiley & Sons, United Kingdom

Volume :

Issue :

Pages :

945-948

Peer reviewed :

Peer reviewed

Available on ORBi :

since 11 January 2020

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