Halato-telechelic polymers - 2. Glass transition and viscoelastic behavior

Broze, Guy; Jérôme, Robert; Teyssié, Philippe; Marco, Claude

doi:10.1007/BF00256312

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Halato-telechelic polymers - 2. Glass transition and viscoelastic behavior

Broze, Guy; Jérôme, Robert; Teyssié, Philippe et al.

1981 • In Polymer Bulletin, 4 (4), p. 241-246

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https://hdl.handle.net/2268/242693

DOI
10.1007/BF00256312

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Keywords :

CHEMICAL REACTIONS; POLYBUTADIENES - Molecular Structure; THERMODYNAMICS; VISCOELASTICITY; HALATO-TELECHELIC POLYMERS; POLYMERS

Abstract :

[en] Halato-telechelic polymers (HTP) resulting from the neutralization of carboxy telechelic polymers behave as useful ion-containing model compounds. Carboxy telechelic polybutadiene ( {Mathematical expression}) neutralized by magnesium methoxide exhibits a secondary relaxation mechanism characteristic of the ionic component. The activation process of this secondary relaxation obeys to an Arrhenius-type dependence and an activation energy of 30.5 Kcal/mole is calculated. © 1981 Springer-Verlag.

Disciplines :

Chemistry

Author, co-author :

Broze, Guy ; Université de Liège - ULiège > Département de chimie (sciences) > Chimie des macromolécules et des matériaux organiques (CERM)

Jérôme, Robert ; Université de Liège - ULiège > Département de chimie (sciences) > Département de chimie (sciences)

Teyssié, Philippe ; Université de Liège - ULiège > Relations académiques et scientifiques (Sciences)

Marco, Claude; Laboratory of Macromolecular Chemistry and Organic Catalysis, University of Liège, Sart Tilman, Liège, 4000, Belgium, Laboratory of Materials Science, University of Mons, Avenue Maistriau, 19, Mons, 2000, Belgium

Language :

English

Title :

Halato-telechelic polymers - 2. Glass transition and viscoelastic behavior

Publication date :

1981

Journal title :

Polymer Bulletin

ISSN :

0170-0839

eISSN :

1436-2449

Publisher :

Springer-Verlag

Volume :

Issue :

Pages :

241-246

Peer reviewed :

Peer Reviewed verified by ORBi

Available on ORBi :

since 04 January 2020

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Bibliography

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Eisenberg A., Matsuura H., Tsutsui T. J. Polym. Sci., Polym. Phys. Ed. 1980, 18:479.
Ionic Polymers, L., Holiday, Wiley, New York; 1975.
Otocka E.P., Hellman M.Y., Blyler L.L. J. Appl. Phys. 1969, 40:4221.
Pineri M., Meyer C., Levelut A.M., Lambert M. (1974) Evidence for ionic clusters in butadiene–methacrylic acid copolymers neutralized with various salts. Journal of Polymer Science: Polymer Physics Edition 12:115.