[en] The Institute of Astrophysics of the University of Liege has been present at the High Altitude Research Station Jungfraujoch, Switzerland, since the late 1940s, to perform spectrometric solar observations under dry and weakly polluted high-mountain conditions. Several solar atlases of photometric quality, extending altogether from the near-ultra-violet to the middle-infrared, were produced between 1956 and 1994, first with grating spectrometers then with Fourier transform instruments. During the early 1970s, scientific concerns emerged about atmospheric composition changes likely to set in as a consequence of the growing usage of nitrogen-containing agricultural fertilisers and the industrial production of chlorine-bearing compounds such as the chlorofluorocarbons and hydro-chlorofluorocarbons. Resulting releases to the atmosphere with ensuing photolysis in the stratosphere and catalytic depletion of the protective ozone layer prompted a worldwide consortium of chemical manufacturing companies to solicit the Liege group to help in clarifying these concerns by undertaking specific observations with its existing Jungfraujoch instrumentation. The following pages evoke the main steps that led from quasi full sun-oriented studies to priority investigations of the Earth's atmosphere, in support of both the Montreal and the Kyoto Protocols.
Disciplines :
Earth sciences & physical geography
Author, co-author :
Zander, Rodolphe ; Université de Liège - ULiège > Services généraux (Faculté des sciences) > Relations académiques et scientifiques (Sciences)
Mahieu, Emmanuel ; Université de Liège - ULiège > Département d'astrophys., géophysique et océanographie (AGO) > Groupe infra-rouge de phys. atmosph. et solaire (GIRPAS)
Demoulin, Philippe ; Université de Liège - ULiège > Département d'astrophys., géophysique et océanographie (AGO) > Groupe infra-rouge de phys. atmosph. et solaire (GIRPAS)
Duchatelet, Pierre ; Université de Liège - ULiège > Département d'astrophys., géophysique et océanographie (AGO) > Groupe infra-rouge de phys. atmosph. et solaire (GIRPAS)
Roland, Ginette
Servais, Christian ; Université de Liège - ULiège > Département d'astrophys., géophysique et océanographie (AGO) > Groupe infra-rouge de phys. atmosph. et solaire (GIRPAS)
De Mazière, Martine
Reimann, Stefan
Rinsland, Curtis P.
Language :
English
Title :
Our Changing Atmosphere: Evidence Based on Long-Term Infrared Solar Observations at the Jungfraujoch since 1950
Connes P. High resolution and high information Fourier spectroscopy. In: Vanasse G., Stair Jr. A., and Backer D. (Eds). Proc of the 1970-Aspen Int. Conf. Fourier Spectroscopy. AFCRL-71-0019 Special Report 114 (1971) 121
Crutzen P.J. The influence of nitrogen oxides on atmospheric ozone content. Q J R Meteorol Soc 96 (1970) 320-325
Delbouille L., and Roland G. Photometric atlas of the solar spectrum from λ 7498 to λ 12016. Mém Soc Roy Sci Liège (1963) Special vol 4
Delbouille L., Roland G., Neven L. Photometric Atlas of the Solar Spectrum from λ3000 to λ10000. Institute of Astrophysics - Univ. of Liège, Special Vol., 1973-1988.
Delbouille L., and Roland G. High-resolution solar and atmospheric spectroscopy from the Jungfraujoch high-altitude station. Opt Eng 34/9 (1995) 2736-2730
De Mazière M., Van Roozendael M., Herman C., Simon P.C., Demoulin P., Roland G., et al. Quantitative evaluation of post-Pinatubo NO2 reduction and recovery, based on 10 years of FTIR and UV-visible spectroscopic measurements at the Jungfraujoch. J Geophys Res 103 (1998) 10849-10858
Demoulin P.h., Zander R., Roland G., and Delbouille L. Long-term remote monitoring of NO, NO2 and HNO3 above the Jungfraujoch. Proc of the Third European Symposium on Polar Stratospheric Ozone Research, 18-22 September 1995, Schliersee, Germany. EC Air Pollution Research Report 56 (1996) 170-174
Dils B., De Mazière M., Müller J.F., Blumenstock T., Buchwitz M., de Beek R., et al. Comparisons between SCIAMACHY and ground-based FTIR data for total columns of CO, CH4, CO2 and N2O. Atmos Chem Phys 6 (2006) 1953-1976
Farmer C.B., Delbouille L., Roland G., and Servais C. The solar spectrum between 16 and 40 microns. San Juan Capistrano Research Institute, SJI Technical Report (1994) 83 pp
Gunson M.R., Abrams M.C., Lowes L.L., Mahieu E., Zander R., Rinsland C.P., et al. Increase in levels of stratospheric chlorine and fluorine loading between 1985 and 1992. Geophys Res Lett 21 (1994) 2223-2226
Höpfner M., von Clarmann T., Fischer H., Funke B., Glatthor N., Grabowski U., et al. Validation of MIPAS ClONO2 measurements. Atmos Chem Phys 7 (2007) 257-281
Kaye J.A., Douglas A.R., Jackman C.H., Stolarski R.S., Zander R., and Roland G. Two-dimensional model calculations of fluorine-containing reservoir species in the stratosphere. J Geophys Res 96 (1991) 12,865-12,881
Krieg J., Notholt J., Mahieu E., Rinsland C.P., and Zander R. Sulphur hexafluoride (SF6): comparison of FTIR-measurements at three sites and determination of its trend in the northern hemisphere. J Quant Spectrosc Radiat Transfer 92 (2005) 383-392
Mahieu E., Zander R., Demoulin P., De Mazière M., Mélen F., Servais C., et al. Fifteen years-trend characteristics of key stratospheric constituents monitored by FTIR above the Jungfraujoch. In: Harris N., Guirlet M., and Amanatidis G. (Eds). Proc of the Fifth European Symposium on Stratospheric Ozone, 27 September-1 October 1999, St. Jean de Luz, France. Air Pollut Res Rep No. 73 73 (2000) 99-102
Mahieu E. L'évolution du chlore inorganique au-dessus du Jungfraujoch et le Protocole de Montréal. PhD Thesis, University of Liège - Faculty of Sciences, 2001;-172 pp.
Mahieu E., Duchatelet P., Zander R., Demoulin P., Servais C., Rinsland C.P., et al. The evolution of inorganic chlorine above the Jungfraujoch station: an update. Proc. of the XX Quadrennial Ozone Symposium Vol II, 1-8 June 2004, Kos, Greece (2004) 997-998
Malbrouck R. Spectroscopie à très haute résolution par transformée de Fourier: Application à l'étude du spectre solaire. PhD Thesis, University of Liège - Faculty of Sciences, 1977: 244pp.
McClatchey R.A., Benedict W.S., Clough S.A., Burch D.E., Calfee R.F., Fox K., et al. AFCRL Atmospheric Absorption Line Parameters Compilation. Project 7670, Environmental Research Papers No 434, AFCRL-TR-73-0096 (1973)
Mélen F., Mahieu E., Zander R., Rinsland C.P., Demoulin P., Roland G., et al. Vertical column abundances of COF2 above the Jungfraujoch station derived from ground-based infrared solar observations. J Atmos Chem 29 (1998) 119-134
Migeotte M.V. Spectroscopic evidence of methane in the Earth's atmosphere. Phys Rev 73 (1948) 519
Migeotte M.V. The fundamental band of carbon monoxide at 4.7 μ in the solar spectrum. Phys Rev 75 (1949) 1108
Migeotte M.V., and Neven L. Détection du monoxide de carbone dans l'atmosphère terrestre, à 3580 mètres d'altitude. Physica 16 (1950) 423-424
Migeotte M.V., Neven L., and Swensson J. The solar spectrum from 2.8 to 23.7 microns - part I: Photometric atlas. Mém Soc Roy Sci Liège (1956) Special vol 1
Migeotte M.V., Neven L., Swensson J., and Benedict W.S. The solar spectrum from 2.8 to 23.7 microns - part II: Measures and identifications. Mém Soc Roy Sci Liège (1957) Special vol 2
Molina M.J., and Rowland F.S. Stratospheric sink for chlorofluoromethanes: chlorine atom-catalysed destruction of ozone. Nature 249 (1974) 810-812
Montzka SA, Fraser PJ, Butler JH, Cunnold D, Daniel J, Derwent D, Connell PS, Lal S, McCulloch A, Oram DE, Reeves CE, Sanhueza E, Steele P, Velders GJM, Zander R. Controlled substances and other source gases, Chapter 1 of WMO Scientific Assessment of Ozone Depletion: 2002, WMO Report Nr. 47, World Meteorological Organization, P.O. Box 2300, Geneva 2, CH 1211, Switzerland, March 2003 I-1 to I-83 pp.
Murcray D.G., Kyle T.G., Murcray F.H., and Williams W.J. Nitric acid and nitric oxide in the lower stratosphere. Nature (1968) 218: 278
Nassar R., Bernath P.F., Boone C.D., Clerbaux C., Coheur P.F., Dufour G., et al. A global inventory of stratospheric chlorine in 2004. J Geophys Res 111 (2006) D22312 10.1029/2006JD007073
Nassar R., Bernath P.F., Boone C.D., McLeod S.D., Skelton R., Walker K.A., et al. A global inventory of stratospheric fluorine in 2004 based on Atmospheric Chemistry Experiment Fourier Transform Spectrometer (ACE-FTS) measurements. J Geophys Res 111 (2006) D22313 10.1029/2006JD007395
NDSC-Workshop Report 'Network for the Detection of Stratospheric Change', Boulder, CO, USA, March 5-7, 1986. Issued by Upper Atmosphere Research Program, Code EE, NASA Headquarters, Washington, D.C. 20546, USA, 1986.
Nielsen A.H., and Migeotte M.V. Abundance and vertical distribution of telluric methane from measurements at 3580 meters elevation. Ann Astrophys 15 (1952) 134-141
Reimann S., Vollmer M.K., Folini D., Steinbacher M., Hill M., Buchmann B., Zander R., and Mahieu E. Observations of long-lived anthropogenic halocarbons at the high-Alpine site of Jungfraujoch (Switzerland) for assessment of trends and European sources. Sci Total Environ 391 (2008) 224-231 10.1016/j.scitotenv.2007.10.022 (this issue)
Rinsland C.P., Smith M.A.H., Rinsland C.P., Goldman A., Brault J.W., and Stockes G.M. Ground-based infrared spectroscopic measurements of atmospheric hydrogen cyanide. J Geophys Res 87 (1982) 11,119-11,125
Rinsland C.P., Zander R., and Demoulin P. Ground-based infrared measurements of HNO3 total column abundances: long-term trend and variability. J Geophys Res 96 (1991) 9379-9389
Rinsland C.P., Jones N.B., Connor B.J., Logan J.A., Pougatchev N.S., Goldman A., et al. Northern and southern hemisphere ground-based infrared spectroscopic measurements of tropospheric carbon monoxide and ethane. J Geophys Res 103 (1998) 28197-28217
Rinsland C.P., Mahieu E., Zander R., Jones N.B., Chipperfield M.P., Goldman A., et al. Long-term trends of inorganic chlorine from ground-based infrared solar spectra: past increases and evidence for stabilization. J Geophys Res 108 D8 (2003) 4252 10.1029/2002JD003001 ACH10
Rodgers C.D. Retrieval of atmospheric temperature and composition from remote measurements of thermal radiation. Rev Geophys 14 (1976) 609-624
Roland G. . Spectroscopie par Transformée de Fourier. PhD Thesis, University of Liège - Faculty of Sciences, 1965: 154 pp.
Swensson J.W., Benedict W.S., Delbouille L., and Roland G. The solar spectrum from λ 7498 to λ 12016. Mém Soc Roy Sci Liège (1970) Special vol 5
Vigouroux C., De Mazière M., Errera Q., Mahieu E., Duchatelet P., Wood S., et al. Comparisons between ground-based FTIR and MIPAS N2O and HNO3 profiles before and after assimilation in BASCOE. Atmos Chem Phys 7 (2007) 377-396
Wigley T.M.L. The Kyoto Protocol: CO2, CH4 and climate implications. Geophys Res Lett 25 13 (1998) 2285-2288
WMO Report No. 16. Atmospheric Ozone 1985: Assessment of our understanding of the processes controlling its present distribution and change (1986), World Meteorological Organization, P.O. Box 2300, Geneva 2, CH 1211, Switzerland
Zander R. Présence de HF dans la stratosphère supérieure. C R Acad Sc Paris t. 281b (1975) 213-214
Zander R., Roland G., and Delbouille L. Confirming the presence of hydrofluoric acid in the upper stratosphere. Geophys Res Lett 4 (1977) 117-120
Zander R., Roland G., Delbouille L., Sauval A.J., Farmer C.B., and Norton R.H. Monitoring of the integrated column of hydrogen fluoride above the Jungfraujoch station since 1977 - the HF/HCl column ratio. J Atmos Chem 5 (1987) 385-394
Zander R., Roland G., Delbouille L., Sauval A.J., Farmer C.B., and Norton R.H. Column abundance and long-term trend of hydrogen chloride (HCl) above the Jungfraujoch station. J Atmos Chem 5 (1987) 395-404
Zander R., and Demoulin P.h. Spectroscopic evidence for the presence of the ν4-Q branch of chlorine nitrate (ClONO2) in ground-based infrared solar spectra. J Atmos Chem 6 (1988) 191-200
Zander R., Gunson M.R., Farmer C.B., Rinsland C.P., Irion F.W., and Mahieu E. The 1985 chlorine and fluorine inventories in the stratosphere based on ATMOS observations at 30° north latitudes. J Atmos Chem 15 (1992) 171-186
Zander R., Ehhalt D.H., Rinsland C.P., Schmidt U., Mahieu E., Rudolph J., et al. Secular trend and seasonal variability of the column abundance of N2O above the Jungfraujoch station determined from IR solar spectra. J Geophys Res 99 (1994) 16,745-16,756
Zander R., Mahieu E., Gunson M.R., Abrams M.C., Chang A.Y., Abbas M., et al. The 1994 northern midlatitude budget of stratospheric chlorine derived from ATMOS/ATLAS-3 observations. Geophys Res Lett 23 (1996) 2357-2360
Zander R., Mahieu E., Demoulin P., Duchatelet P., Servais C., Roland G., et al. Evolution of a dozen non-CO2 greenhouse gases above Central Europe since the mid-1980s. Environmental Sciences, June-September 2 2-3 (2005) 295-303