[en] A simple, low-cost, and environmentally friendly water-based colloidal spraypainting process is developed to obtain mechanically stable microelectrodes of pure LiCoO2 on stainless steel disks, which display reversible high-rate discharge capacity and good cyclability. By using a simple nanostructuring process with commercially available LiCoO2, the use of dispersant, conductive, and binder additives during the electrode preparation is completely avoided. The nanostructuring approach is based on: i) planetary ball milling and annealing of LiCoO2 microparticles and ii) LiCoO2 surface modification through dissociative H2O adsorption during contact with air- and water-based colloid preparation. The coating technique involves: i) water-based colloid
preparation, ii) spray-coating, and iii) post-treatment (drying and calcination) processes. The effects of particle size distribution, shape, crystallinity, specific surface area, and LiCoO2 surface modification on the electrode architecture (roughness, thickness, packing density, and porosity) are studied, together with their impact on the final electrochemical performances of batteries
assembled with such a LiCoO2 electrode.
Disciplines :
Chemistry
Author, co-author :
Pàez Martinez, Carlos ; Université de Liège - ULiège > Department of Chemical Engineering > Génie chimique - Nanomatériaux et interfaces
Exantus, Chellda ; Université de Liège - ULiège > Department of Chemical Engineering > Génie chimique - Nanomatériaux et interfaces
Dallel, Dorra
Alié, Christelle ; Université de Liège - ULiège > Department of Chemical Engineering > Génie chimique - Nanomatériaux et interfaces
Calberg, Cédric ; Université de Liège - ULiège > Department of Chemical Engineering > Génie chimique - Nanomatériaux et interfaces
Liquet, Dimitri ; Université de Liège - ULiège > Department of Chemical Engineering > Génie chimique - Nanomatériaux et interfaces
Eskenazi, David
Deschamps, Fabien ; Université de Liège - ULiège > Department of Chemical Engineering > Ingéniérie électrochimique
Job, Nathalie ; Université de Liège - ULiège > Department of Chemical Engineering > Ingéniérie électrochimique
Heinrichs, Benoît ; Université de Liège - ULiège > Department of Chemical Engineering > Génie chimique - Nanomatériaux et interfaces
Language :
English
Title :
Water-Based Paintable LiCoO2 Microelectrodes: A HighRate Li-Ion Battery Free of Conductive and Binder Additives
Publication date :
26 September 2019
Journal title :
Advanced Materials Technologies
eISSN :
2365-709X
Publisher :
Wiley-Blackwell, Hoboken, United States - New Jersey
S. S. Zhang, K. Xu, T. R. Jow, J. Power Sources 2004, 138, 226.
A. F. Léonard, N. Job, Mater. Today Energy 2019, 12, 168.
K. Wu, Y. Wang, I. Zhitomirsky, J. Colloid Interface Sci. 2010, 352, 371.
C. C. Li, J. T. Lee, Y. L. Tung, C. R. Yang, J. Mater. Sci. 2007, 42, 5773.
A. Kohut, A. Voronov, W. Peukert, Langmuir 2007, 23, 504.
A. Kraytsberg, Y. Ein-Eli, Adv. Energy Mater. 2016, 6, 1600655.
V. Wenzel, H. Nirschl, D. Nötzel, Energy Technol. 2015, 3, 692.
G. Liu, H. Zheng, X. Song, V. S. Battaglia, J. Electrochem. Soc. 2012, 159, A214.
H. Zheng, R. Yang, G. Liu, X. Song, V. S. Battaglia, J. Phys. Chem. C 2012, 116, 4875.
J. T. Lee, Y. J. Chu, F. M. Wang, C. R. Yang, C. C. Li, J. Mater. Sci. 2007, 42, 10118.
H. Zhang, P. J. Baker, P. S. Grant, J. Am. Ceram. Soc. 2010, 1859, 1856.
S. Shiraki, H. Oki, Y. Takagi, T. Suzuki, A. Kumatani, R. Shimizu, M. Haruta, T. Ohsawa, Y. Sato, Y. Ikuhara, T. Hitosugi, J. Power Sources 2014, 267, 881.
W. G. Choi, S. G. Yoon, J. Power Sources 2004, 125, 236.
M. Hayashi, M. Takahashi, Y. Sakurai, J. Power Sources 2007, 174, 990.
C. A. Paez, D. Liquet, C. Calberg, B. Heinrichs, C. Allié, WO Patent 2016/097396 Al, 2016.
D. Prat, A. Wells, J. Hayler, H. Sneddon, C. R. McElroy, S. Abou-Shehada, P. J. Dunn, Green Chem. 2015, 18, 288.
P. R. Rios, F. Siciliano Jr., H. R. Z. Sandim, R. L. Plaut, A. F. Padilha, Mater. Res. 2005, 8, 225.
R. Alcántara, G. F. Ortiz, P. Lavela, J. L. Tirado, W. Jaegermann, A. Thißen, J. Electroanal. Chem. 2005, 584, 147.
M. N. Obrovac, O. Mao, J. R. Dahn, Solid State Ionics 1998, 112, 9.
J. Geder, H. E. Hoster, A. Jossen, J. Garche, D. Y. W. Yu, J. Power Sources 2014, 257, 286.
K. Nakamura, H. Hirano, D. Nishioka, Y. Michihiro, T. Moriga, Solid State Ionics 2008, 179, 1806.
G. Cherkashinin, W. Jaegermann, J. Chem. Phys. 2016, 144, 184706.
M. Motzko, M. A. Carrillo Solano, W. Jaegermann, R. Hausbrand, J. Phys. Chem. C 2015, 119, 23407.
P. S. Maram, G. C. C. Costa, A. Navrotsky, Angew. Chem., Int. Ed. 2013, 52, 12139.
N. Mijung, Y. Lee, J. Cho, J. Electrochem. Soc. 2006, 153, A935.
R. Alcántara, P. Lavela, J. L. Tirado, R. Stoyanova, E. Zhecheva, J. Solid State Chem. 1997, 134, 265.
W. Huang, R. Frech, Solid State Ionics 1996, 86–88, 395.
H. Porthault, R. Baddour-Hadjean, F. Le Cras, C. Bourbon, S. Franger, Vib. Spectrosc. 2012, 62, 152.
Y. Bai, K. Jiang, S. Sun, Q. Wu, X. Lu, N. Wan, Electrochim. Acta 2014, 134, 347.
Z. Wang, X. Huang, L. Chen, J. Electrochem. Soc. 2004, 151, A1641.
J. Kim, M. Kim, S. Noh, G. Lee, D. Shin, Ceram. Int. 2016, 42, 2140.
A. Boulant, J. F. Bardeau, A. Jouanneaux, J. Emery, J. Y. Buzare, O. Bohnke, Dalton Trans. 2010, 39, 3968.
L. Fan, D. Tang, D. Wang, Z. Wang, L. Chen, Nano Res. 2016, 9, 3903.
X. Wang, L. Andrews, Mol. Phys. 2009, 107, 739.
H. Li, X. Jiao, L. Li, N. Zhao, F. Xiao, W. Wei, Y. Sun, B. Zhang, Catal. Sci. Technol. 2015, 5, 989.
H. Kudo, J. Nucl. Mater. 1979, 87, 185.
J. Kim, Y. Hong, K. S. Ryu, M. G. Kim, J. Cho, Electrochem. Solid-State Lett. 2006, 9, A19.
H. Beyer, S. Meini, N. Tsiouvaras, M. Piana, H. A. Gasteiger, Phys. Chem. Chem. Phys. 2013, 15, 11025.
K. Park, J. H. Park, S. G. Hong, B. Choi, S. Heo, S. W. Seo, K. Min, J. H. Park, Sci. Rep. 2017, 7, 1.