CHARACTERIZATION OF NEOGENE MARLS FROM THE KERT BASIN (N.E. MOROCCO): SUITABILITY FOR THE CERAMIC INDUSTRY

Nasri, Hicham; Azdimousa, Ali; EL Hamouti, Kamal; El Haddar, Abdelilah; El Ouahabi, Meriam

doi:10.1180/clm.2019.50

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CHARACTERIZATION OF NEOGENE MARLS FROM THE KERT BASIN (N.E. MOROCCO): SUITABILITY FOR THE CERAMIC INDUSTRY

Nasri, Hicham; Azdimousa, Ali; EL Hamouti, Kamal et al.

2019 • In Clay Minerals

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https://hdl.handle.net/2268/240881

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10.1180/clm.2019.50

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Keywords :

western mediterranean basin; Neogene; Marls; Clay; Kert; Morocco; Geochemistry; Mineralogy; Ceramic

Abstract :

[en] The North-Eastern region of Morocco is filled with marine marls of Neogene age. The Neogene marls from the lower-Kert area were characterized to evaluate their suitability in the ceramic industry. To meet this objective, two cross-sections involving all the Neogene facies were performed on the both banks of the Kert River. Grey and green marls occurring between sandstone and tuffs were characterized by mineralogical (XRD) and physico-chemical analyses (grain-size, Atterberg limits, XRF, and specific surface area). The studied Neogene clays are mainly calcareous silty marls with CaCO3 content ranging from 13 to 20 wt.%. The mineralogical composition showed the occurrence of quartz, calcite, feldspars, dolomite, illite, kaolinite, chlorite, and mixed-layers (10-14 Å). Cristobalite occurred only in the uppermost level of the green marls supplied from volcanic ash during the Messinian. Siderite and rhodochrosite occurred as traces pointing out to reducing or locally oxidizing conditions during sedimentation or shortly thereafter. There, marls have medium to high plasticity that is optimum for extrusion. Raw Neogene marls are suitable for structural clay products manufacturing. More specific uses were supported by geochemical results and grain-size distribution as hollow products, roofing tiles, and masonry bricks.

Disciplines :

Physical, chemical, mathematical & earth Sciences: Multidisciplinary, general & others
Earth sciences & physical geography

Author, co-author :

Nasri, Hicham

Azdimousa, Ali

EL Hamouti, Kamal

El Haddar, Abdelilah

El Ouahabi, Meriam ; Université de Liège - ULiège > Département de géologie > Argiles, géochimie et environnements sédimentaires

Language :

English

Title :

CHARACTERIZATION OF NEOGENE MARLS FROM THE KERT BASIN (N.E. MOROCCO): SUITABILITY FOR THE CERAMIC INDUSTRY

Publication date :

2019

Journal title :

Clay Minerals

ISSN :

0009-8558

Publisher :

Mineralogical Society, United Kingdom

Peer reviewed :

Peer Reviewed verified by ORBi

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since 04 November 2019

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Bibliography

Abajo M. (2000) Manual sobre fabricación de baldosas, tejas y ladrillos. Beralmar S.A., Barcelona, Spain.
Abdellah R. (1997) Les bassins néogènes du sillon sud-rifain et du Rif nord oriental (Maroc): sédimentologie, paléontologie et évolution dynamique. Doctoral thesis. Sidi Mohammed Ben Abdellah University, Fez, Morocco.
Achalhi M. (2016) Chronostratigraphie et sédimentologie des bassins néogènes de Boudinar et d'Arbaa Taourirt (Rif oriental, Maroc). Doctoral thesis. Mohamed Premier University, Oujda, Morocco.
Achalhi M., Münch P., Cornée J.-J., Azdimousa A., Melinte-Dobrinescu M., Quillévéré F., Drinia H., Fauquette S., Jiménez-Moreno G., Merzeraud G., Moussa A.B., El Kharim Y. & Feddi N. (2016) The late Miocene Mediterranean-Atlantic connections through the north Rifian corridor: new insights from the Boudinar and Arbaa Taourirt basins (northeastern Rif, Morocco). Palaeogeography, Palaeoclimatology, Palaeoecology, 459, 131-152.
AFNOR (1992) Norme française. Sol: reconnaissance et essai. Analyse granulométrique des sols. Méthode par sédimentation. NF P 94-057. Association Française de Normalisation, Paris, France, 17 pp.
AFNOR (1993) Norme française. Sols: reconnaissance et essais. Détermination des limites d'Atterberg: Limite de liquidité à la coupelle-limite de plasticité au rouleau. NF P 94-051. Association Française de Normalisation, Paris, France, 15 pp.
AFNOR (1996) Norme française. Sols: reconnaissance et essais. Détermination de la teneur en carbonate. Méthode du calcimètre. NF P 94-048. Association Française de Normalisation, Paris, France, 11 pp.
AFNOR (1998) Norme française. Sol: reconnaissance et essais. Mesure de la capacité d'adsorption de bleu de méthylène d'un sol ou d'un matériau rocheux. NF P 94-068. Association Française de Normalisation, Paris, France, 8 pp.
Alvares J.I., Navarro I. & Garcia Casado P.J.G. (2000) Thermal, mineralogical and chemical studies of the mortars used in the cathedral of Pamplona, Spain. Thermochim Acta, 365(1-2): 177-187.
Andres A., Díaz M.C., Coz A., Abellán M.J. & Viguri J.R. (2009) Physico-chemical characterisation of bricks all through the manufacture process in relation to efflorescence salts. Journal of the European Ceramic Society, 29(10), 1869-1877.
Asebriy L., Bourgois J., Cherkaoui T.E. & Azdimousa A. (1993) Evolution tec-tonique récente de la zone de faille du Nékor: importance paléogéographique et structurale dans le Rif externe, Maroc. Journal of African Earth Sciences, 17, 65-74.
Azdimousa A. & Bourgois J. (1993) Les communications entre l'Atlantique et la Méditerranée par le couloir sud-rifain du Tortonien à l'Actuel: stratigra-phie séquentielle des bassins Néogènes de la région du Cap des Trois Fourches (Rif oriental, Maroc). Journal of African Earth Sciences (and the Middle East), 17, 233-240.
Azdimousa A., Jabaloy A., Asebriy L., Booth-Rea G., Gonzalez-Lodeiro F. & Bourgois J. (2007) Lithostratigraphy and structure of the Temsamane unit (eastern external Rif, Morocco). Revista de la Sociedad Geológica de España, 20, 187-200.
Azdimousa A., Poupeau G., Rezqi H., Asebriy L., Bourgois J. & Aït Brahim L. (2006) Géodynamique des bordures méridionales de la mer d'Alboran; application de la stratigraphie séquentielle dans le bassin néogène de Boudinar (Rif oriental, Maroc). Bulletin de l'Institut Scientifique. Rabat, 28, 9-18.
Baccour H., Medhioub M., Jamoussi F., Mhiri T. & Daoud A. (2008) Mineralogical evaluation and industrial applications of the Triassic clay deposits, southern Tunisia. Materials Characterization, 59, 1613-1622.
Baghdad A., Bouazi R., Bouftouha Y., Bouabsa L. & Fagel N. (2017) Mineralogical characterization of Neogene clay areas from the Jijel Basin for ceramic purposes (N.E. Algeria-Africa). Applied Clay Science, 136, 176-183.
Bain A.J. (1986) Composition and properties of clays used in various fields of ceramics: part I. Ceramic Forum International, 62, 536-538.
Beaulieu J. (1979) Identification géotechnique des matériaux argileux naturels par la mesure de leur surface spécifique au moyen de bleu de méthylène. Postgraduate thesis. University of Paris-Sud, Orsay, France.
Biscaye P.E. (1965) Mineralogy and sedimentation of recent deep-sea clay in the Atlantic Ocean and adjacent seas and oceans. Geological Society of America Bulletin, 76, 803-832.
Boski T., Pessoa J., Pedro P., Thorez J., Dias J.M.A. & Hall I.R. (1998) Factors governing abundance of hydrolyzable amino acids in the sediments from the N.W. European Continental Margin (47-50°N). Progress in Oceanography, 42, 145-164.
Brindley G.W. & Nakahira M. (1959) The kaolinite-mullite reaction series: II. Metakolin. Journal of the American Ceramic Society, 42(7), 314-318.
Casagrande A. (1947) Plasticity chart for the classification of cohesive soils. Transactions of the American Society of Civil Engineers, 73, 783-811.
Chalouan A., Michard A., Kadiri K.E., Negro F., Lamotte D.F.d., Soto J.I. & Saddiqi O. (2008) The Rif Belt. Pp. 203-302 in Continental evolution: The Geology of Morocco: Structure, Stratigraphy, and Tectonics of the Africa-Atlantic-Mediterranean Triple Junction (A. Michard, O. Saddiqi, A. Chalouan, & D. Frizon de Lamotte, editors). Springer, Berlin, Germany.
Cook H.E., Johnson P.D., Matti J.C. & Zemmels I. (1975) Methods of sample preparation and X-ray diffraction data analysis, X-ray mineralogy laboratory, deep sea drilling project, University of California, Riverside. Initial Reports of the Deep Sea Drilling Project, 28, 999-1007.
Cornée J.-J., Münch P., Achalhi M., Merzeraud G., Azdimousa A., Quillévéré F., Melinte-Dobrinescu M., Chaix C., Moussa A.B., Lofi J., Séranne M. & Moissette P. (2016) The Messinian erosional surface and early Pliocene reflooding in the Alboran Sea: new insights from the Boudinar Basin, Morocco. Sedimentary Geology, 333, 115-129.
Cunningham K.J. & Collins L.S. (2002) Controls on facies and sequence stratigraphy of an upper Miocene carbonate ramp and platform, Melilla Basin, N.E. Morocco. Sedimentary Geology, 146, 285-304.
Cunningham K.J., Benson R.H., Rakic-El Bied K. & McKenna L.W. (1997) Eustatic implications of late Miocene depositional sequences in the Melilla Basin, northeastern Morocco. Sedimentary Geology, 107, 147-165.
De Jong E. (1999) Comparison of three methods of measuring surface area of soils. Canadian Journal of Soil Science, 79, 345-351.
De Kimpe C.R., Laverdiere M.R. & Martel Y.A. (1979) Surface area and exchange capacity of clay in relation to the mineralogical composition of gleysolic soils. Revue Canadienne de la Science du Sol, 59, 341-347.
Dondi M. (1999) Clay materials for ceramic tiles from the Sassuolo district (northern Apennines, Italy). Geology, composition and technological properties. Applied Clay Science, 15, 337-366.
Dondi M., Raimondo M. & Zanelli C. (2014) Clays and bodies for ceramic tiles: reappraisal and technological classification. Applied Clay Science, 96, 91-109.
El Bakkali S., Bourdier J.-L. & Gourgaud A. (1998a) Caractérisation et strati-graphie de dépôts volcanoclastiques marqueurs dans le Miocène supérieur du bassin de Melilla-bas Kert (Rif Oriental, Maroc). Comptes Rendus de l'Académie des Sciences-Series IIA-Earth and Planetary Science, 327, 93-100.
El Bakkali S., Gourgaud A., Bourdier J.-L., Bellon H. & Gundogdu N. (1998b) Post-collision Neogene volcanism of the eastern Rif (Morocco): magmatic evolution through time. Lithos, 45, 523-543.
El Boudour El Idrissi H., Daoudi L., El Ouahabi M., Collin F. & Fagel N. (2018) The influence of clay composition and lithology on the industrial potential of earthenware. Construction and Building Materials, 172, 650-659.
El Ouahabi M. (2013) Valorisation industrielle et artisanale des argiles du Maroc. PhD thesis. University of Liège, Liège, Belgium.
El Ouahabi M., Daoudi L. & Fagel N. (2014b) Mineralogical and geotechnical characterization of clays from northern Morocco for their potential use in the ceramic industry. Clay Minerals, 49, 35-51.
El Ouahabi M., Daoudi L., De Vleeschouwer F., Bindler R. & Fagel N. (2014a) Potentiality of clay raw materials from northern Morocco in ceramic industry: Tetouan and Meknes areas. Journal of Minerals and Materials Characterization and Engineering, 2, 145-159.
El Ouahabi M., Daoudi L., Hatert F. & Fagel N. (2015) Modified mineral phases during clay ceramic firing. Clays and Clay Minerals, 63, 404-413.
Essafi M. (1986) Etude minéralogique et géochimique des bentonites du Rif nord oriental (bassin de Melilla-Nador). Doctoral thesis. University of Paris-Sud, Orsay, France.
Fagel N., Boski T., Likhoshway L. & Oberhaensli H. (2003) Late Quaternary clay mineral record in Central Lake Baikal (Academician Ridge, Ciberia). Palaeogeography, Palaeoclimatology, Palaeoecology, 193, 159-179.
Fagel N., Thamó-Bózsó E. & Heim B. (2007) Mineralogical signatures of Lake Baikal sediments: sources of sediment supplies through Late Quaternary. Sedimentary Geology, 194, 37-59.
Ferrari S. & Gualtieri A.F. (2006) The use of illitic clays in the production of stoneware tile ceramics. Applied Clay Science, 32, 73-81.
Fiori C., Fabbri B., Donati G. & Venturi I. (1989) Mineralogical composition of the clay bodies used in the Italian tile industry. Applied Clay Science, 4, 461-473.
Frizon de Lamotte D. & Leikine M. (1985) Métamorphisme miocène du Rif oriental (Maroc) et individualisation de la nappe gravitaire d'Aknoul. Revue de Géologie Dynamique et de Géographie Physique, 26, 29-42.
González I., Galán E., & Miras A. (2006) Fluorine, chlorine and sulphur emissions from the Andalusian ceramic industry (Spain)-proposal for their reduction and estimation of threshold emission values. Applied Clay Science, 32, 3-4.
González I., Galán E., Miras A. & Aparicio P. (1998) New uses for brick-making clay from the Bailén area (southern materials Spain). Clay Minerals, 33, 453-465.
Guillemin M. & Houzay J.-P. (1982) Le Néogène post-nappe et le Quaternaire du Rif nord-oriental. Stratigraphie et tectonique des bassins de Melilla, du Kert, de Boudinar, et du piedmont des Kebdana. Notes et Mémoires du Service Géologique du Maroc, Rabat, Morocco, 7 pp.
Harvey C.C. & Lagaly G. (2006) Conventional applications. Pp. 501-540 in: Developments in Clay Science, Volume 1 (F. Bergaya, B.K.G. Theng & G. Lagaly, editors). Elsevier, Amsterdam, The Netherlands.
Holtz R.D. & Kovacs W.D. (1981) An Introduction to Geotechnical Engineering. Prentice Hall, Upper Saddle River, NJ, USA, 733 pp.
Jabaloy-Sánchez A., Azdimousa A., Booth-Rea G., Asebriy L., Vázquez-Vílchez M., Martínez-Martínez J.M. & Gabites J. (2015) The structure of the Temsamane fold-and-thrust stack (eastern Rif, Morocco): evolution of a transpressional orogenic wedge. Tectonophysics, 663, 150-176.
Jordán M.M., Sanfeliu T. & De la Fuente C. (2001) Firing transformations of Tertiary clays used in the manufacturing of ceramic tile bodies. Applied Clay Science, 20, 87-95.
Keith K.S. & Murray H.H. (2009) Common clays and shale. Pp. 369-371 in Industrial Minerals and Rocks. Commodities, Markets, and Uses (J.E. Kogel, N.C. Trivedi, J.M. Barker & S.T. Krukowski, editors). Society for Mining, Metallurgy, and Exploration, Englewood, CO, USA.
Kharbish S. & Farhat H.I. (2017) Mineralogy and physico-chemical properties of Wadi Badaa clays (Cairo-Suez district, Egypt): a prospective resource for the ceramic industry. Arabian Journal of Geosciences, 10, 174.
Lisboa J.V., Rocha F. & de Oliveira D.P.S. (2016) Application of multivariate analysis in the assessment of ceramic raw materials. Clays and Clay Minerals, 64, 767-787.
Mahmoudi S., Bennour A., Srasra E. & Zargouni F. (2017) Characterization, firing behavior and ceramic application of clays from the Gabes region in south Tunisia. Applied Clay Science, 135, 215-225.
Mazzoli S. & Helman M. (1994) Neogene patterns of relative plate motion for Africa-Europe: some implications for recent central Mediterranean tectonics. Geologische Rundschau, 83, 464-468.
Mesrar L., Akdim M., Akhrif I., Lakrim M., El Aroussi O., Chaouni A. & Jabrane R. (2013) Technological valorization of the Miocene clay in the region of Fez (Morocco): characterisation and exploitation possibilities. Present Environment and Sustainable Development, 7, 310-317.
Mesrar L., Lakrim M., Akdim M., Benamar A., Es-Sbai N. & Jabrane R. (2017) Preparation and characterization of Miocene clay powders in the region of Taza (Morocco) after doping with metal oxides Al2O3. Pp. 1-9 in: Proceedings of the XII Maghreb Days of Material Sciences-Materials Science and Engineering. IOP Science, Fez, Morocco.
Michard A., Chalouan A., Feinberg H., Goffé B. & Montigny R. (2002) How does the Alpine Belt end between Spain and Morocco? Bulletin de la Société Géologique de France, 173, 3-15.
Milheiro F.A.C., Freire M.N., Silva A.G.P. & Holanda J.N.F. (2005) Densification behaviour of a red firing Brazilian kaolinitic clay. Ceramics International, 31, 757-763.
Miloŝevic M. & Logar M. (2017) Properties and characterization of a clay raw material from Milicinica (Serbia) for use in the ceramic industry. Clay Minerals, 52, 329-340.
Moore D.M. & Reynolds R.C. (1997) X-Ray Diffraction and the Identification and Analysis of Clay Minerals. Second Edition. Oxford University Press, Oxford, UK, 378 pp.
Mukherjee S. (2013) The Science of Clays. Applications in Industry, Engineering and Environment. First Edition. Capital Publishing Company, New Delhi, India, 335 pp.
Münch P., Cornée J.J., Féraud G., Martin J.P.S., Ferrandini M., Garcia F., Conesa G., Roger S. & Moullade M. (2006) Precise 40Ar/39Ar dating of volcanic tuffs within the upper Messinian sequences in the Melilla carbonate complex (N.E. Morocco): implications for the Messinian Salinity Crisis. International Journal of Earth Sciences, 95, 491-503.
Murray H.H. (1994) Common clays. Pp. 247-248 in: Industrial minerals and rocks (D.D. Carr, editor). Society for Mining, Metallurgy and Exploration, Englewood, CO, USA.
Murray H.H. (2007) Applied Clay Mineralogy: Occurrences, Processing and Application of Kaolins, Bentonites, Palygorskite-Sepiolite, and Common Clays. Elsevier, Amsterdam, The Netherlands, 180pp.
Nasri H., Elhammouti K., Azdimousa A., Achalhi M. & Bengamra S. (2016) Calcimetric and sedimentometric characterization of clay deposits in the Neogene Boudinar basin (north eastern Rif, Morocco): implication on the eustatic and hydrodynamic evolution of the basin and economic interest. Journal of Materials and Environmental Science, 7, 859-870.
Negro F., de Sigoyer J., Goffé B., Saddiqi O. & Villa I.M. (2008) Tectonic evolution of the Betic-Rif arc: new constraints from 40Ar/39Ar dating on white micas in the Temsamane units (External Rif, northern Morocco). Lithos, 106, 93-109.
Ngun B.K., Mohamad H., Sulaiman S.K., Okada K. & Ahmad Z.A. (2011) Some ceramic properties of clays from central Cambodia. Applied Clay Science, 53, 33-41.
Nkalih Mefire A., Yongue Fouateu R., Njoya A., Mache J.R., Pilate P., Hatert F. & Fagel N. (2018) Mineralogy and geochemical features of Foumban clay deposits (west Cameroon): genesis and potential applications. Clay Minerals, 53, 431-445.
Petersen L.W., Moldrup P., Jacobsen O.H. & Rolston D.E. (1996) Relations between specific surface area and soil physical and chemical properties. Soil Science, 161, 9-21.
Petrick K., Diedel R., Peuker M., Dieterle M., Kuch P., Kaden R., Krolla-Sidenstein P., Schuhmann R. & Emmerich K. (2011) Character and amount of I-S mixed-layer minerals and physical-chemical parameters of two ceramic clays from Westerwald, Germany: implications for processing properties. Clays and Clay Minerals, 59, 58-74.
Reeves G.M., Sims I. & Cripps J. (2006) Clay Materials Used in Construction. The Geological Society, London, UK, 447 pp.
Rosenbaum G., Lister G.S. & Duboz C. (2002) Relative motions of Africa, Iberia and Europe during Alpine orogeny. Tectonophysics, 359, 117-129.
Shepard F.P. (1954) Nomenclature based on sand-silt-clay ratios. Journal of Sedimentary Petrology, 24, 151-158.
Shvarzman A., Kovler K.G., Grader G.S. & Shter E. (2003) The effect of dehy-droxylation/amorphization degree on pozzolanic activity of kaolinite. Cement and Concrete Research, 33, 405-416.
Strazzera B., Dondi M. & Marsigli M. (1997) Composition and ceramic properties of Tertiary clays from southern Sardinia (Italy). Applied Clay Science, 12, 247-266.
Tiller K.G. & Smith L.H. (1990) Limitations of EGME retention to estimate the surface area of soils. Australian Journal of Soil Research, 28, 1-26.
Trindade M.J., Dias M.I., Coroado J. & Rocha F. (2009) Mineralogical transformations of calcareous rich clays with firing: a comparative study between cal-cite and dolomite rich clays from Algarve, Portugal. Applied Clay Science, 42, 345-355.
Trindade M.J., Dias M.I., Coroado J.O. & Rocha F. (2010) Firing tests on clay-rich raw materials from the Algarve basin (southern Portugal): study of mineral transformations with temperature. Clays and Clay Minerals, 58, 188-204.
Van Assen E., Kuiper K.F., Barhoun N., Krijgsman W. & Sierro F.J. (2006) Messinian astrochronology of the Melilla basin: stepwise restriction of the Mediterranean-Atlantic connection through Morocco. Palaeogeography, Palaeoclimatology, Palaeoecology, 238, 15-31.
Wattanasiriwech D., Srijan K. & Wattanasiriwech S. (2009) Vitrification of illitic clay from Malaysia. Applied Clay Science, 43, 57-62.
Wentworth C.K. (1922) A scale of grade and class terms for clastic sediments. Journal of Geology, 30, 377-392.
Winkler H.G.F. (1954) Bedeutung der korngrössenverteilung und des miner-albestandes von tonen für die herstellung grobkeramischer erzeugnisse. Berichte der Deutschen Keramischen Gesellschaft, 31, 337-343.