[en] The oxidation of cyclic alkanes and alkenes by cobalt(III) acetate leads to the formation of cycloalkyl and cycloalkenyl acetates. The formation of chlorinated hydrocarbons is observed for cycloalkanes in the presence of carbon tetrachloride but no incorporation of chlorine takes place in the olefins. The results are best interpreted by assuming a determining role by both steric and conformational effects on the reaction, involving the conversion of a co-ordinated radical to a carbocation.
Disciplines :
Chemistry
Author, co-author :
Verstraelen, L.; University of Liège, Laboratory of Macromolecular Chemistry and Organic Catalysis, Sart Tilman, 4000 Liège, Belgium
Lalmand, Maurice
Hubert, André J.
Teyssié, Philippe ; Université de Liège - ULiège > Relations académiques et scientifiques (Sciences)
Language :
English
Title :
Oxidation of cyclic hydrocarbons by cobalt(III) acetate
Publication date :
1976
Journal title :
Journal of the Chemical Society, Perkin Transactions 2
scite shows how a scientific paper has been cited by providing the context of the citation, a classification describing whether it supports, mentions, or contrasts the cited claim, and a label indicating in which section the citation was made.
Bibliography
R. A. Sheldon and J. K. Kochi, Oxidation and Combustion Rev., 1973, 5, 135, and references therein.
E. I. Heiba, R. M. Dessau, and W. J. Koehl, jun., J. Amer. Chem. Soc., 1969, 91, 6830.
J. Hanotier, Ph. Camerman, M. Hanotier-Bridoux, and P. de Radzitzky, J.C.S. Perkin II, 1972, 2247.
J. Hanotier, M. Hanotier-Bridoux, and P. de Radzitzky, J.C.S. Perkin II, 1973, 381.
J. Hanotier and M. Hanotier-Bridoux, J.C.S. Perkin II, 1973, 1035.
I. Tabushi, Z. Yoshida, and Y. Tamaru, Tetrahedron Letters 1973, 29, 81.
C. Masters, J.C.S. Chem. Comm., 1973, 191.
A. C. Udding, J. Strating, H. Wynberg, Tetrahedron Letters, 1968, 1345.
F. N. Stepanov and Z. E. Stolyarov, Zhur. Vsesoyuz. Khitn. obshch., 1968, 13, 713.
W. Hoeek, T. Strating, and H. Wynberg, Rec. Trav. chim., 1966, 85, 1045.
Similar publications
Sorry the service is unavailable at the moment. Please try again later.
This website uses cookies to improve user experience. Read more
Save & Close
Accept all
Decline all
Show detailsHide details
Cookie declaration
About cookies
Strictly necessary
Performance
Strictly necessary cookies allow core website functionality such as user login and account management. The website cannot be used properly without strictly necessary cookies.
This cookie is used by Cookie-Script.com service to remember visitor cookie consent preferences. It is necessary for Cookie-Script.com cookie banner to work properly.
Performance cookies are used to see how visitors use the website, eg. analytics cookies. Those cookies cannot be used to directly identify a certain visitor.
Used to store the attribution information, the referrer initially used to visit the website
Cookies are small text files that are placed on your computer by websites that you visit. Websites use cookies to help users navigate efficiently and perform certain functions. Cookies that are required for the website to operate properly are allowed to be set without your permission. All other cookies need to be approved before they can be set in the browser.
You can change your consent to cookie usage at any time on our Privacy Policy page.
