Transition‐Metal‐Catalysed Reactions of Diazoesters: Synthesis of Chrysanthemic and Permethric Acid Esters by Cyclopropanation of Conjugated Dienes

Demonceau, Albert; Noels, Alfred; Anciaux, A. J.; Hubert, André J.; Teyssié, Philippe

doi:10.1002/bscb.19840931104

Article (Scientific journals)

Transition‐Metal‐Catalysed Reactions of Diazoesters: Synthesis of Chrysanthemic and Permethric Acid Esters by Cyclopropanation of Conjugated Dienes

Demonceau, Albert; Noels, Alfred; Anciaux, A. J. et al.

1984 • In Bulletin des Sociétés Chimiques Belges, 93 (11), p. 949-952

Peer reviewed

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https://hdl.handle.net/2268/237693

DOI
10.1002/bscb.19840931104

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Abstract :

[en] Pyrethroid precursors (permethric and chrysanthemic acid esters) are efficiently synthesized by rhodium(II)‐catalysed cyclopropanation of the properly substituted conjugated diene. Reaction selectivities depend on both the catalyst counter‐ion and the diazoester alkoxy‐group (carbene precursor) and are attributed to non‐bonded interactions. Copyright © 1984 Wiley‐VCH Verlag GmbH & Co. KGaA, Weinheim

Disciplines :

Chemistry

Author, co-author :

Demonceau, Albert ; Université de Liège - ULiège > Département de chimie (sciences) > Chimie macromoléculaire et catalyse organique

Noels, Alfred ; Université de Liège - ULiège > Relations académiques et scientifiques (Sciences)

Anciaux, A. J.; Laboratory of Macromolecular Chemistry and Organic Catalysis, Laboratory of Organic Synthesis and Catalysis, University of Liège, Sart-Tilman, B-4000, Belgium

Hubert, André J.

Teyssié, Philippe ; Université de Liège - ULiège > Relations académiques et scientifiques (Sciences)

Language :

English

Title :

Transition‐Metal‐Catalysed Reactions of Diazoesters: Synthesis of Chrysanthemic and Permethric Acid Esters by Cyclopropanation of Conjugated Dienes

Publication date :

1984

Journal title :

Bulletin des Sociétés Chimiques Belges

ISSN :

0037-9646

Publisher :

John Wiley & Sons, United Kingdom

Volume :

Issue :

Pages :

949-952

Peer reviewed :

Peer reviewed

Available on ORBi :

since 29 June 2019

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Bibliography

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