[en] The photoelectron spectrum of N2O and the kinetic energy distributions of NO+, N2+, O+ and N+ have been recorded with HeI and NeI resonance lines. At 21.22 eV the distributions are similar to those observed by electroionization at comparable energy. The NeI resonance line produces O+ and NO+ ions. Their respective kinetic energy distributions are related to the change induced in the N2O+(A2Sigma+) photoelectron band excited by the NeI resonance line.
Research Center/Unit :
Laboratoire de Dynamique Moléculaire
Disciplines :
Chemistry
Author, co-author :
Locht, Robert ; Université de Liège - ULiège > Département de Chimie (Faculté des sciences) > Laboratoire de Dynamique Moléculaire (Sciences)
Caprace, G.
Momigny, J.
Language :
English
Title :
The Dissociative Ionization of Nitrous Oxide. A comparison between Electroionization and HeI and NeI Photoionization.
Alternative titles :
[fr] L'ionisation dissociative de l'hémioxyde d'azote. Une comparaison entre l'électroionisation et la photoionisation par HeI et NeI.
Publication date :
1984
Journal title :
Chemical Physics Letters
ISSN :
0009-2614
Publisher :
Elsevier Science, Amsterdam, Netherlands
Volume :
111
Pages :
560-565
Peer reviewed :
Peer Reviewed verified by ORBi
Funders :
ARC, FRFC
Commentary :
- Printed version of reprint available on request
- Version imprimée du tiré-à-part disponible sur demande
Nenner, Guyon, Baer, Govers (1980) A threshold photoelectron–photoion coincidence study of the N2O+ dissociation between 15 and 20.5 eV. The Journal of Chemical Physics 72:6587.
Orth, Dunbar (1977) Photodissociation of nitrous oxide cation. The Journal of Chemical Physics 66:1616.
Dehmer, Dehmer, Chupka J. Chem. Phys. 1980, 73:126.
.
Natalis, Collin, Delwiche, Caprace, Hubin-Franskin J. Electron Spectry. 1979, 17:421.
