Article (Scientific journals)
Catalysed prototropic rearrangements. Part 3. Metal carbonyl-catalysed lsomerization of N-allylsulphonamides to N-prop-2-enyl and N-propylidene derivatives
Hubert, André J.; Feron, A.; Goebbels, G. et al.
1977In Journal of the Chemical Society, Perkin Transactions 2, (1), p. 11-14
Peer reviewed
 

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Abstract :
[en] N-Allylsulphonamides (4) are readily isomerized in the presence of pentacarbonyliron upon irradiation by u.v. light. N-Prop-2-enyl derivatives (5) are obtained, and further isomerization under suitable conditions leads to N-propylidenesulphonamides (6). The last reaction proceeds by a specific 1,3-proton migration involving an NH group as shown by isotopic labelling experiments. © 1977 by The Chemical Society.
Disciplines :
Chemistry
Author, co-author :
Hubert, André J.
Feron, A.;  Laboratory of Macromolecular Chemistry and Organic Catalysis, Université de Liège Sart Tilman, Liège, 4000, Belgium
Goebbels, G.;  Laboratory of Macromolecular Chemistry and Organic Catalysis, Université de Liège Sart Tilman, Liège, 4000, Belgium
Warin, Roger ;  Université de Liège - ULiège > Département de géologie > Minéralogie et cristallochimie
Teyssié, Philippe ;  Université de Liège - ULiège > Relations académiques et scientifiques (Sciences)
Language :
English
Title :
Catalysed prototropic rearrangements. Part 3. Metal carbonyl-catalysed lsomerization of N-allylsulphonamides to N-prop-2-enyl and N-propylidene derivatives
Publication date :
1977
Journal title :
Journal of the Chemical Society, Perkin Transactions 2
ISSN :
1470-1820
Publisher :
Chemical Society, United Kingdom
Issue :
1
Pages :
11-14
Peer reviewed :
Peer reviewed
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