Article (Scientific journals)
Chemical properties of 2‐isopropylimino‐3‐isopropyl‐5‐methoxy‐Δ4‐oxazoline: Formation of charge‐transfer complexes from an oxazoline
Drapier, J.; Badot, J.; Jonius, L. et al.
1985In Journal of Heterocyclic Chemistry, 22 (2), p. 417-421
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Abstract :
[en] 2‐Isopropylimino‐3‐isopropyl‐5‐methoxy‐Δ4‐oxazoline 1 copolymerizes readily by a radicalar mechanism with maleic anhydride, an air and heat sensitive isolable charge‐transfer monomer 2 being formed as intermediate. Similarly, a (more stable) adduct 4 has been prepared from 1 and TCNE. In opposition, acrylic acid adds onto the Δ4‐oxazoline endocyclic double bond giving the acrylate 5. The hydrolysis and hydrogenation of 1 are also reported. Copyright © 1985 Journal of Heterocyclic Chemistry
Disciplines :
Chemistry
Author, co-author :
Drapier, J.;  Université de Liège - ULiège > Institut de Chimie
Badot, J.;  Université de Liège - ULiège > Institut de Chimie
Jonius, L.;  Université de Liège - ULiège > Institut de Chimie
Warin, Roger ;  Université de Liège - ULiège > Département de géologie > Minéralogie et cristallochimie
Hubert, André J.
Teyssié, Philippe ;  Université de Liège - ULiège > Relations académiques et scientifiques (Sciences)
Language :
English
Title :
Chemical properties of 2‐isopropylimino‐3‐isopropyl‐5‐methoxy‐Δ4‐oxazoline: Formation of charge‐transfer complexes from an oxazoline
Publication date :
1985
Journal title :
Journal of Heterocyclic Chemistry
ISSN :
0022-152X
Publisher :
Wiley-Blackwell, United States - Utah
Volume :
22
Issue :
2
Pages :
417-421
Peer reviewed :
Peer Reviewed verified by ORBi
Available on ORBi :
since 29 May 2019

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