Radical addition to 2‐isopropenyl‐5‐butoxyoxazole

[en] The preparation and the spectroscopic analysis of a dimeric adduct (V) obtained from 2‐isopropenyl‐5‐butoxyoxazole (III) and α,α‐azobis‐isobutyronitrile (AIBN) (IV) are reported. It is noteworthy that (III) inhibits completely the homopolymerization of styrene. This is in strong opposition to the facile homopolymerization and copolymerization of 2‐isopropenyl‐4,5‐dimethyloxazole with styrene. The smooth formation of (V) is also in sharp contrast to the lack of reactivity of (III) towards cationic initiators. Copyright © 1986 John Wiley & Sons, Inc.

Disciplines :

Chemistry

Author, co-author :

Drapier, J.; Université de Liège - ULiège > Institut de Chimie > Laboratoire de Chimie Macromoléculaire Et de Catalyse Organique

Parla, D.; Université de Liège - ULiège > Institut de Chimie > Laboratoire de Chimie Macromoléculaire Et de Catalyse Organique

Moniotte, Ph; Université de Liège - ULiège > Institut de Chimie > Laboratoire de Chimie Macromoléculaire Et de Catalyse Organique

Warin, Roger; Université de Liège - ULiège

Hubert, André J.

Teyssié, Philippe ; Université de Liège - ULiège > Relations académiques et scientifiques (Sciences)

Language :

English

Title :

Radical addition to 2‐isopropenyl‐5‐butoxyoxazole

Publication date :

1986

Journal title :

Journal of Polymer Science. Part A, Polymer Chemistry

ISSN :

0887-624X

eISSN :

1099-0518

Publisher :

John Wiley & Sons, Hoboken, United States - New Jersey

Volume :

Issue :

Pages :

2185-2190

Peer reviewed :

Peer Reviewed verified by ORBi

Available on ORBi :

since 29 May 2019

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Bibliography

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