Article (Scientific journals)
Radical addition to 2‐isopropenyl‐5‐butoxyoxazole
Drapier, J.; Parla, D.; Moniotte, Ph et al.
1986In Journal of Polymer Science. Part A, Polymer Chemistry, 24 (9), p. 2185-2190
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Keywords :
POLYMERIZATION - Copolymerization; SPECTROSCOPIC ANALYSIS; DIMERIC ADDUCT; HOMOPOLYMERIZATION; INITIATORS; RADICAL ADDITION; STYRENE
Abstract :
[en] The preparation and the spectroscopic analysis of a dimeric adduct (V) obtained from 2‐isopropenyl‐5‐butoxyoxazole (III) and α,α‐azobis‐isobutyronitrile (AIBN) (IV) are reported. It is noteworthy that (III) inhibits completely the homopolymerization of styrene. This is in strong opposition to the facile homopolymerization and copolymerization of 2‐isopropenyl‐4,5‐dimethyloxazole with styrene. The smooth formation of (V) is also in sharp contrast to the lack of reactivity of (III) towards cationic initiators. Copyright © 1986 John Wiley & Sons, Inc.
Disciplines :
Chemistry
Author, co-author :
Drapier, J.;  Université de Liège - ULiège > Institut de Chimie > Laboratoire de Chimie Macromoléculaire Et de Catalyse Organique
Parla, D.;  Université de Liège - ULiège > Institut de Chimie > Laboratoire de Chimie Macromoléculaire Et de Catalyse Organique
Moniotte, Ph;  Université de Liège - ULiège > Institut de Chimie > Laboratoire de Chimie Macromoléculaire Et de Catalyse Organique
Warin, Roger;  Université de Liège - ULiège
Hubert, André J.
Teyssié, Philippe ;  Université de Liège - ULiège > Relations académiques et scientifiques (Sciences)
Language :
English
Title :
Radical addition to 2‐isopropenyl‐5‐butoxyoxazole
Publication date :
1986
Journal title :
Journal of Polymer Science. Part A, Polymer Chemistry
ISSN :
0887-624X
eISSN :
1099-0518
Publisher :
John Wiley & Sons, Hoboken, United States - New Jersey
Volume :
24
Issue :
9
Pages :
2185-2190
Peer reviewed :
Peer Reviewed verified by ORBi
Available on ORBi :
since 29 May 2019

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