An easy route to synthesize high-quality black phosphorus from amorphous red phosphorus

[en] The development of an easy and efficient process for producing black phosphorus (BP) remains a bottleneck for the use of BP in large-scale applications. In this work, we present a simple, potentially scalable, and economically viable method for the preparation of high-quality BP from amorphous red phosphorus. BP was synthesized under low pressure and temperature conditions from red phosphorus via the addition of small quantities of copper, tin, and tin(IV) iodide. Characterization by powder X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive spectrometry (EDX), high-resolution transmission electron microscopy (HR-TEM), and Raman spectroscopy were performed to confirm the high quality and purity of the formed BP.

Disciplines :

Chemistry

Author, co-author :

Tiouitchi, G.

Ali, M. Ait

Benyoussef, A.

Hamedoun, M.

Lachgar, A.

Benaissa, M.

Kara, A.

Ennaoui, A.

Mahmoud, Abdelfattah ; Université de Liège - ULiège > Département de chimie (sciences) > LCIS - GreenMAT

Boschini, Frédéric ; Université de Liège - ULiège > Plateforme APTIS

More authors (3 more)

Language :

English

Title :

An easy route to synthesize high-quality black phosphorus from amorphous red phosphorus

Publication date :

2019

Journal title :

Materials Letters

ISSN :

0167-577X

eISSN :

1873-4979

Publisher :

Elsevier, Amsterdam, Netherlands

Volume :

236

Pages :

56 - 59

Peer reviewed :

Peer Reviewed verified by ORBi

Available on ORBi :

since 07 May 2019

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Bridgman, P.W., Two new modifications of phosphorus. J. Am. Chem. Soc. 36 (1914), 1344–1363, 10.1021/ja02184a002.
Karttunen, A.J., Linnolahti, M., Pakkanen, T.A., Structural principles of polyhedral allotropes of phosphorus. ChemPhysChem 9 (2008), 2550–2558, 10.1002/cphc.200800646.
Keyes, R.W., The electrical properties of black phosphorus. Phys. Rev. 92 (1953), 580–584, 10.1103/PhysRev. 92.580.
Zhu, Z., Tománek, D., Semiconducting layered blue phosphorus: a computational study. Phys. Rev. Lett., 112, 2014, 176802, 10.1103/PhysRevLett.112.176802.
Brown, A., Rundqvist, S., Refinement of the crystal structure of black phosphorus. Acta Crystallogr. 19 (1965), 684–685, 10.1107/S0365110X65004140.
Liu, H., Du, Y., Deng, Y., Ye, P.D., Semiconducting black phosphorus: synthesis, transport properties and electronic applications. Chem. Soc. Rev. 44 (2015), 2732–2743, 10.1039/c4cs00257a.
Ling, X., Liang, L., Huang, S., Puretzky, A.A., Geohegan, D.B., Sumpter, B.G., Kong, J., Meunier, V., Dresselhaus, M.S., Low-Frequency interlayer breathing modes in few-layer black phosphorus. Nano Lett. 15 (2015), 4080–4088, 10.1021/acs.nanolett.5b01117.
Ribeiro-Soares, J., Almeida, R.M., Cançado, L.G., Dresselhaus, M.S., Jorio, A., Group theory for structural analysis and lattice vibrations in phosphorene systems. Phys. Rev. B, 91, 2015, 205421, 10.1103/PhysRevB.91.205421.
Xia, F., Wang, H., Jia, Y., Rediscovering black phosphorus as an anisotropic layered material for optoelectronics and electronics. Nat. Commun. 5 (2014), 1–6, 10.1038/ncomms5458.
Jain, R., Narayan, R., Sasikala, S.P., Lee, K.E., Jung, H.J., Kim, S.O., Phosphorene for energy and catalytic application—filling the gap between graphene and 2D metal chalcogenides. 2D Mater., 4, 2017, 42006, 10.1088/2053-1583/aa89b3.
Tran, V., Soklaski, R., Liang, Y., Yang, L., Layer-controlled band gap and anisotropic excitons in few-layer black phosphorus. Phys. Rev. B, 89, 2014, 235319, 10.1103/PhysRevB.89.235319.
Shirotani, I., Growth of large single crystals of black phosphorus at high pressures and temperatures, and its electrical properties. Mol. Cryst. Liq. Cryst. 86 (1982), 203–211, 10.1080/00268948208073686.
Scelta, D., Baldassarre, A., Serrano-Ruiz, M., Dziubek, K., Cairns, A.B., Peruzzini, M., Bini, R., Ceppatelli, M., Interlayer bond formation in black phosphorus at high pressure. Angew. Chem. Int. Ed. Engl. 56 (2017), 14135–14140, 10.1002/anie.201708368.
Maruyama, Y., Suzuki, S., Kobayashi, K., Tanuma, S., Synthesis and some properties of black phosphorus single crystals. Phys. B+C 105 (1981), 99–102, 10.1016/0378-4363(81)90223-0.
Baba, M., Izumida, F., Morita, A., Koike, Y., Fukase, T., Electrical properties of black phosphorus single crystals prepared by the bismuth-flux method. Jpn. J. Appl. Phys. 30 (1991), 1753–1758, 10.1143/JJAP.30.1753.
Krebs, H., Weitz, H., Worms, K.H., Über die Struktur und Eigenschaften der Halbmetalle. VIII. Die katalytische Darstellung des schwarzen Phosphors. ZAAC J. Inorg. Gen. Chem. 280 (1955), 119–133, 10.1002/zaac.19552800110.
Tian, B., Tian, B., Smith, B., Scott, M.C., Lei, Q., Hua, R., Tian, Y., Liu, Y., Facile bottom-up synthesis of partially oxidized black phosphorus nanosheets as metal-free photocatalyst for hydrogen evolution. Proc. Natl. Acad. Sci. U.S.A. 115 (2018), 4345–4350, 10.1073/pnas.1800069115.
Lange, S., Schmidt, P., Nilges, T., Au3SnP7@black phosphorus: an easy access to black phosphorus. Inorg. Chem. 46 (2007), 4028–4035, 10.1021/ic062192q.
Koenig, S.P., Doganov, R.A., Schmidt, H., Castro Neto, A.H., Özyilmaz, B., Electric field effect in ultrathin black phosphorus. Appl. Phys. Lett., 104, 2014, 103106, 10.1063/1.4868132.
Ziletti, A., Carvalho, A., Campbell, D.K., Coker, D.F., Castro Neto, A.H., Oxygen defects in phosphorene. Phys. Rev. Lett., 114, 2015, 46801, 10.1103/PhysRevLett.114.046801.
Rahman, M.Z., Kwong, W., Environmental Science photocatalyst : fundamentals to applications. Energy Environ. Sci. 9 (2016), 709–728, 10.1039/C5EE03732H.
Han, X., Stewart, H.M., Shevlin, S.A., Catlow, C.R.A., Guo, Z.X., Strain and orientation modulated bandgaps and effective masses of phosphorene nanoribbons. Nano Lett. 14 (2014), 4607–4614, 10.1021/nl501658d.
Niu, L., Coleman, J.N., Zhang, H., Shin, H., Chhowalla, M., Zheng, Z., Production of two-dimensional nanomaterials via liquid-based direct exfoliation. Small 12 (2016), 272–293, 10.1002/smll.201502207.
Kim, J.S., Liu, Y., Zhu, W., Kim, S., Wu, D., Tao, L., Dodabalapur, A., Lai, K., Akinwande, D., Toward air-stable multilayer phosphorene thin-films and transistors. Sci. Rep. 5 (2015), 1–22, 10.1038/srep08989.
Zhang, Z., Xin, X., Yan, Q., Li, Q., Yang, Y., Ren, T.-L., Two-step heating synthesis of sub-3 millimeter-sized orthorhombic black phosphorus single crystal by chemical vapor transport reaction method. Sci. China Mater. 59 (2016), 122–134, 10.1007/s40843-016-0122-1.
A. Favron, E. Gaufrès, F. Fossard, P.L. Lévesque, A.-L. Phaneuf-L'Heureux, N.Y.-W. Tang, A. Loiseau, R. Leonelli, S. Francoeur, R. Martel, Exfoliating pristine black phosphorus down to the monolayer: photo-oxidation and electronic confinement effects, (2014). <> (accessed 26.09.18).
Sugai, S., Ueda, T., Murase, K., Pressure dependence of the lattice vibration in the orthorhombic and rhombohedral structures of black phosphorus. J. Phys. Soc. Jpn. 50 (1981), 3356–3361, 10.1143/JPSJ.50.3356.
Vanderborgh, C.A., Schiferl, D., Raman studies of black phosphorus from 0.25 to 7.7 GPa at 15 K. Phys. Rev. B. 40 (1989), 9595–9599.
Sugai, S., Shirotani, I., Raman and infrared reflection spectroscopy in black phosphorus. Solid State Commun. 53 (1985), 753–755, 10.1016/0038-1098(85)90213-3.
Gupta, S.N., Singh, A., Pal, K., Chakraborti, B., Muthu, D.V.S., Waghmare, U.V., Sood, A.K., Raman anomalies as signatures of pressure induced electronic topological and structural transitions in black phosphorus: experiments and theory. Phys. Rev. B, 96, 2017, 94104, 10.1103/PhysRevB.96.094104.
Hultgren, R., Gingrich, N.S., Warren, B.E., The atomic distribution in red and black phosphorus and the crystal structure of black phosphorus. J. Chem. Phys. 3 (1935), 351–355.
Crichton, W.A., Mezouar, M., Monaco, G., Falconi, S., Phosphorus: New in situ powder data from large-volume apparatus. Powder Diffr. 18 (2003), 155–158, 10.1154/1.1545115.
Lange, S., Schmidt, P., Nilges, T., Au 3 SnP 7 @black phosphorus: an easy access to black phosphorus. Inorg. Chem. 46 (2007), 4028–4035, 10.1021/ic062192q.