Electrochemistry as a correlation tool with the catalytic activities in [RuCl2(p-cymene)(PAr3)]-catalysed Kharasch additions

Richel, Aurore; Demonceau, Albert; Noels, Alfred

doi:10.1016/j.tetlet.2006.01.138

Article (Scientific journals)

Electrochemistry as a correlation tool with the catalytic activities in [RuCl2(p-cymene)(PAr3)]-catalysed Kharasch additions

Richel, Aurore; Demonceau, Albert; Noels, Alfred

2006 • In Tetrahedron Letters, 47, p. 2077-2081

Peer Reviewed verified by ORBi

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https://hdl.handle.net/2268/23303

DOI
10.1016/j.tetlet.2006.01.138

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Keywords :

Catalysis; Electrochemistry; Olefins; Radicals and radical reactions; Ruthenium and compounds

Abstract :

[en] [RuCl2(p-cymene)] complexes containing triarylphosphine ligands with various substituents at the para position were used to catalyse the atom transfer radical addition of carbon tetrachloride to various olefins, and their catalytic activities were nicely correlated with their electrochemical parameters.

Disciplines :

Chemistry

Author, co-author :

Richel, Aurore ; Université de Liège - ULiège > Gembloux Agro-Bio Tech > Gembloux Agro-Bio Tech

Demonceau, Albert ; Université de Liège - ULiège > Département de chimie (sciences) > Chimie macromoléculaire et catalyse organique

Noels, Alfred ; Université de Liège - ULiège > Services généraux (Faculté des sciences) > Relations académiques et scientifiques (Sciences)

Language :

English

Title :

Electrochemistry as a correlation tool with the catalytic activities in [RuCl2(p-cymene)(PAr3)]-catalysed Kharasch additions

Publication date :

2006

Journal title :

Tetrahedron Letters

ISSN :

0040-4039

Publisher :

Elsevier, Oxford, United Kingdom

Volume :

Pages :

2077-2081

Peer reviewed :

Peer Reviewed verified by ORBi

Available on ORBi :

since 22 September 2009

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