In-pipette solid-phase extraction prior to flow-modulation comprehensive two-dimensional gas chromatography with dual detection for the determination of minor components in vegetable oils

Barp, L.; Franchina, Flavio; Purcaro, Giorgia; Tranchida, P. Q.; Mondello, L.

doi:10.1016/j.talanta.2017.01.009

Article (Scientific journals)

In-pipette solid-phase extraction prior to flow-modulation comprehensive two-dimensional gas chromatography with dual detection for the determination of minor components in vegetable oils

Barp, L.; Franchina, Flavio; Purcaro, Giorgia et al.

2017 • In Talanta, 165, p. 598-603

Peer Reviewed verified by ORBi

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https://hdl.handle.net/2268/228845

DOI
10.1016/j.talanta.2017.01.009

PubMed
28153304

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Keywords :

Comprehensive two-dimensional gas chromatography; Flow modulation; Food authenticity; Food quality; In-pipette solid phase extraction; Vegetable oil; Chromatography; Gas chromatography; Gas oils; Ionization of gases; Ionization potential; Modulation; Oils and fats; Olive oil; Phase separation; Smoke detectors; Vegetable oils; Flow modulations; Solid-phase extraction; Extraction; Chromatography, Gas; Flame Ionization; Food Contamination; Mass Spectrometry; Plant Oils; Solid Phase Extraction

Abstract :

[en] The present research is based on the development of an effective, environmentally-friendly and low-cost method for investigation of minor components in vegetable oils, exploiting the advantages of a miniaturized solid-phase extraction (SPE) and the potential of flow modulation (FM) comprehensive two-dimensional gas chromatography (GC×GC), coupled to a mass spectrometer (MS) and a flame ionization detector (FID). The initial sample preparation step was carried out using a miniaturized approach characterized by a SPE process in a Pasteur pipette. Then, the isolated fraction was injected into an FM GC×GC system. Tentative identification was carried out by means of MS spectral information, while quantification was carried out by using the FID data. Four different vegetable oil samples were analyzed using the proposed method, namely an extra virgin olive oil (EVO), a hazelnut oil (HO), a borage oil, and an EVO/HO mixture. © 2017 Elsevier B.V.

Disciplines :

Physical, chemical, mathematical & earth Sciences: Multidisciplinary, general & others

Author, co-author :

Barp, L. ^✱; “Dipartimento di Scienze Chimiche, Biologiche, Farmaceutiche ed Ambientali”, University of Messina, Polo Annunziata - viale Annunziata, Messina, 98168, Italy

Franchina, Flavio ^✱; Université de Liège - ULiège > Département de chimie (sciences) > Chimie analytique, organique et biologique

Purcaro, Giorgia ; Université de Liège - ULiège > Agronomie, Bio-ingénierie et Chimie (AgroBioChem) > Chimie des agro-biosystèmes

Tranchida, P. Q.; “Dipartimento di Scienze Chimiche, Biologiche, Farmaceutiche ed Ambientali”, University of Messina, Polo Annunziata - viale Annunziata, Messina, 98168, Italy

Mondello, L.; “Dipartimento di Scienze Chimiche, Biologiche, Farmaceutiche ed Ambientali”, University of Messina, Polo Annunziata - viale Annunziata, Messina, 98168, Italy, Chromaleont s.r.l., University of Messina, Polo Annunziata - viale Annunziata, Messina, 98168, Italy

^✱ These authors have contributed equally to this work.

Language :

English

Title :

In-pipette solid-phase extraction prior to flow-modulation comprehensive two-dimensional gas chromatography with dual detection for the determination of minor components in vegetable oils

Publication date :

2017

Journal title :

Talanta

ISSN :

0039-9140

eISSN :

1873-3573

Publisher :

Elsevier B.V.

Volume :

165

Pages :

598-603

Peer reviewed :

Peer Reviewed verified by ORBi

Available on ORBi :

since 24 October 2018

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Bibliography

[1] Mariani, C., Bellan, G., Detection of interesterified oils and fats with different methodologies. Riv. Ital. Sostanze Gr. 88 (2011), 3–10.
[2] International Olive Council, Determination of the content of waxes, fatty acid methyl esters and fatty acid ethyl esters by capillary gas chromatography using three grams of silica. COI/T.20/Doc. N. 31, 2012, pp. 1–14.
[3] Mariani, C., Fedeli, E., Minor components of vegetable oils: non-glyceridic esters. Riv. Ital. Sostanze Gr. 66 (1989), 397–401.
[4] Reg. (EU) n. 61/2011 Off. J. Eur. Comm. 2011, L23, 1-14.
[5] Pérez-Camino, M.D.C., Cert, A., Romero-Segura, A., Cert-Trujillo, R., Moreda, W., Alkyl esters of fatty acids a useful tool to detect soft deodorized olive oils. J. Agric. Food Chem. 56 (2008), 6740–6744.
[6] Reg. (EU) n. 1348/2013 Off. J. Eur. Comm. 2013, L338, 31-67.
[7] Reg. (EC) n. 702/2007 Off. J. Eur. Comm. 2007, L161, 11-27.
[8] Mariani, C., Fedeli, E., Grob, K., Evaluation of free and esterified minor components in fatty materials. Riv. Ital. Sostanze Gr. 68 (1991), 233–242.
[9] Grob, K., Lanfranchi, M., Mariani, C., J. Chromatogr. 471 (1989), 397–405.
[10] Purcaro, G., Barp, L., Beccaria, M., Conte, L.S., Fingerprinting of vegetable oil minor components by multidimensional comprehensive gas chromatography with dual detection. Anal. Bioanal. Chem. 407 (2015), 309–319.
[11] Purcaro, G., Barp, L., Beccaria, M., Conte, L., Characterization of minor components in vegetable oil by multidimensional comprehensive gas chromatography. Food Chem. 212 (2016), 730–738.
[12] Biedermann, M., Haase-Aschoff, P., Grob, K., Wax ester fraction of edible oils: analysis by on-line LC-GC-MS and GC×GC-FID. Eur. Lip. Res. Technol. 110 (2008), 1084–1094.
[13] Tranchida, P.Q., Salivo, S., Franchina, F.A., Bonaccorsi, I., Dugo, P., Mondello, L., Qualitative and quantitative analysis of the unsaponifiable fraction of vegetable oils by using comprehensive 2D GC with dual MS/FID detection. Anal. Bioanal. Chem. 405:13 (2013), 4655–4663.
[14] Seeley, J.V., Seeley, S.K., Multidimensional gas chromatography: fundamental advances and new applications. Anal. Chem. 85 (2013), 557–578.
[15] Seeley, J.V., Micyus, N.J., McCurry, J.D., Seeley, S.K., Comprehensive two-dimensional gas chromatography with a simple fluidic modulator. Am. Lab. 38 (2006), 24–26.
[16] Gu, Q., David, F., Lynen, F., Rumpel, K., Xu, G., De Vos, P., Sandra, P., Analysis of bacterial fatty acids by flow modulated comprehensive two-dimensional gas chromatography with parallel flame ionization detector/mass spectrometry. J. Chromatogr. A 1217 (2010), 4448–4453.
[17] Tranchida, P.Q., Franchina, F.A., Dugo, P., Mondello, L., A flow-modulated comprehensive gas chromatography-mass spectrometry method for the analysis of fatty acid profiles in marine and biological samples. J. Chromatogr. A 1255 (2012), 171–176.
[18] Tranchida, P.Q., Franchina, F.A., Dugo, P., Mondello, L., Use of greatly-reduced gas flows in flow-modulated comprehensive two-dimensional gas chromatography-mass spectrometry. J. Chromatogr. A 1359 (2014), 271–276.
[19] Wretensjö, I., Karlberg, B., Characterization of sterols in refined borage oil by GC-MS. JAOCS 79 (2002), 1069–1074.