New polysiloxane bearing imidazolium iodide side chain as electrolyte for photoelectrochemical cell

Bharwal, Anil Kumar; Nguyen, Ngoc A.; Iojoiu, Cristina; Henrist, Catherine; Alloin, Fannie

doi:10.1016/j.ssi.2017.05.004

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New polysiloxane bearing imidazolium iodide side chain as electrolyte for photoelectrochemical cell

Bharwal, Anil Kumar; Nguyen, Ngoc A.; Iojoiu, Cristina et al.

2017 • In Solid State Ionics, 307, p. 6-13

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https://hdl.handle.net/2268/220044

DOI
10.1016/j.ssi.2017.05.004

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Keywords :

Polysiloxane; Ionic liquid; Poly(ionic liquid); Dye sensitised solar cell

Abstract :

[en] A series of new polymer electrolytes based on polydimethylsiloxane bearing 1-N-methylimidazolium-pentyl iodide side chains, (PILs) with different ionic functionality have been synthesized and characterized. In order to decrease the PILs viscosity and improve the ionic transport, ILs and organic solvent were added. The physiochemical and electrochemical properties of these PILs and their blends with ILs i.e. 1-methyl-3-propylimidazolium iodide (MPII) or 1-methyl-3-propylimidazolium bis(trifluoromethylsulfonyl)imide (MPI TFSI), including density, glass transition temperature, viscosity, ionic conductivity, ionicity and diffusion coefficient were determined. Furthermore, the effect of ethylene carbonate (EC) on the physicochemical and electrochemical properties of PILs was also evaluated in terms of ionic conductivity and diffusion coefficient.

Disciplines :

Physical, chemical, mathematical & earth Sciences: Multidisciplinary, general & others

Author, co-author :

Bharwal, Anil Kumar ; Université de Liège - ULiège > Form. doct. sc. (chimie - paysage)

Nguyen, Ngoc A.

Iojoiu, Cristina

Henrist, Catherine ; Université de Liège - ULiège > Département de chimie (sciences) > LCIS - GreenMAT

Alloin, Fannie

Language :

English

Title :

New polysiloxane bearing imidazolium iodide side chain as electrolyte for photoelectrochemical cell

Publication date :

2017

Journal title :

Solid State Ionics

ISSN :

0167-2738

Publisher :

Elsevier, Netherlands

Volume :

307

Pages :

6-13

Peer reviewed :

Peer Reviewed verified by ORBi

Name of the research project :

IDS Funmat

Available on ORBi :

since 08 February 2018

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