Mn2TeO6: A Distorted Inverse Trirutile Structure

[en] Inverse trirutile Mn2TeO6 was investigated using in situ neutron and X-ray powder diffraction between 700 °C and room temperature. When the temperature was decreased, a structural phase transition was observed around 400 °C, from a tetragonal (P42/mnm) to a monoclinic phase (P21/c), involving a doubling of the cell parameter along b. This complex monoclinic structure has been solved by combining electron, neutron, and synchrotron powder diffraction techniques at room temperature. It can be described as a distorted superstructure of the inverse trirutile structure, in which compressed and elongated MnO6 octahedra alternate with more regular TeO6 octahedra, forming a herringbone-like pattern. Rietveld refinements, carried out with symmetry-adapted modes, show that the structural transition, arguably of Jahn-Teller origin, is driven by a single primary mode. © 2017 American Chemical Society.

Disciplines :

Physique
Chimie

Auteur, co-auteur :

Matsubara, N.; CRISMAT, 6 bvd Maréchal Juin, Caen Cedex, France, Laboratoire Léon Brillouin, CEA-CNRS UMR12, Université Paris-Saclay, Gif sur Yvette Cedex, France

Damay, F.; Laboratoire Léon Brillouin, CEA-CNRS UMR12, Université Paris-Saclay, Gif sur Yvette Cedex, France

Vertruyen, Bénédicte ; Université de Liège - ULiège > Département de chimie (sciences) > Chimie inorganique structurale

Barrier, N.; CRISMAT, 6 bvd Maréchal Juin, Caen Cedex, France

Lebedev, O. I.; CRISMAT, 6 bvd Maréchal Juin, Caen Cedex, France

Boullay, P.; CRISMAT, 6 bvd Maréchal Juin, Caen Cedex, France

Elkaïm, E.; Synchrotron Soleil, Saint-Aubin BP 48, Gif sur Yvette Cedex, France

Manuel, P.; ISIS Facility, Rutherford Appleton Laboratory-CCLRC, Chilton-Didcot, Oxfordshire, United Kingdom

Khalyavin, D. D.; ISIS Facility, Rutherford Appleton Laboratory-CCLRC, Chilton-Didcot, Oxfordshire, United Kingdom

Martin, Christine; CRISMAT, 6 bvd Maréchal Juin, Caen Cedex, France

Langue du document :

Anglais

Titre :

Mn2TeO6: A Distorted Inverse Trirutile Structure

Date de publication/diffusion :

2017

Titre du périodique :

Inorganic Chemistry

ISSN :

0020-1669

eISSN :

1520-510X

Maison d'édition :

American Chemical Society (ACS), Washington, Etats-Unis

Volume/Tome :

Fascicule/Saison :

Pagination :

9742-9753

Peer reviewed :

Peer reviewed vérifié par ORBi

Disponible sur ORBi :

depuis le 13 décembre 2017

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