Ethylene/vinyl acetate-based macrocycles via organometallic-mediated radical polymerization and CuAAC ‘click’ reaction

radical polymerization; cobalt-mediated radical polymerization (CMRP); macrocycle; vinyl acetate; ethylene; click chemistry; copper-mediated Huisgen's cycloaddition

Abstract :

[en] Recent advances in organometallic-mediated radical polymerization led to unique α,ω-difunctional poly(vinyl acetate) (PVAc) and ethylene/vinyl acetate copolymers (EVA). A copper- catalyzed Huisgen dipolar cycloaddition ring-closure reaction was applied to these difunctional precursors paving the way to unprecedented PVAc and/or EVA macrocycles, and to their PVOH- and EVOH-counterparts after hydrolysis.

Research Center/Unit :

CESAM Complex and Entangled Systems from Atoms to Materials (CESAM)
Center for Education and Research on Macromolecules (CERM)

Disciplines :

Chemistry
Materials science & engineering

Author, co-author :

Demarteau, Jérémy ; University of Liège (ULiège), Complex and Entangled Systems from Atoms to Materials (CESAM), Center for Education and Research on Macromolecules (CERM)

De Winter, Julien; University of Mons, Organic Synthesis and Mass Spectrometry Laboratory, Belgium

Detrembleur, Christophe ; University of Liège (ULiège), Complex and Entangled Systems from Atoms to Materials (CESAM), Center for Education and Research on Macromolecules (CERM)

Debuigne, Antoine ; University of Liège (ULiège), Complex and Entangled Systems from Atoms to Materials (CESAM), Center for Education and Research on Macromolecules (CERM)

Language :

English

Title :

Ethylene/vinyl acetate-based macrocycles via organometallic-mediated radical polymerization and CuAAC ‘click’ reaction

Publication date :

21 January 2018

Journal title :

Polymer Chemistry

ISSN :

1759-9954

eISSN :

1759-9962

Publisher :

Royal Society Chemistry, Cambridge, United Kingdom

Volume :

Issue :

Pages :

273-278

Peer reviewed :

Peer Reviewed verified by ORBi

Funders :

F.R.S.-FNRS - Fonds de la Recherche Scientifique
FRIA - Fonds pour la Formation à la Recherche dans l'Industrie et dans l'Agriculture

Available on ORBi :

since 12 December 2017

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