Material properties of perovskites in the quasi-ternary system LaFeO3-LaCoO3-LaNiO3

Electrical conductivity; Mössbauer spectroscopy; Oxygen permeation; Perovskites; Thermal expansion; Electric conductivity; Lanthanum alloys; Metal ions; Oxygen; Oxygen permeable membranes; Perovskite; Powders; Sintering; Ternary systems; X ray diffraction; X ray powder diffraction; Coefficients of thermal expansions; DC electrical conductivity; Powder X ray diffraction; Rhombohedral structures; Ssbauer spectroscopies; Thermal expansion coefficients

Abstract :

[en] An overview is presented on the variation of electrical conductivity, oxygen permeation, and thermal expansion coefficient as a function of the composition of perovskites in the quasi-ternary system LaFeO3-LaCoO3-LaNiO3. Powders of thirteen nominal perovskite compositions were synthesized under identical conditions by the Pechini method. The powder X-ray diffraction data of two series, namely La(Ni0.5Fe0.5)1-xCoxO3 and LaNi0.5-xFexCo0.5O3, are presented after the powders had been sintered at 1100 °C for 6 h in air. The measurements revealed a rhombohedral structure for all compositions except LaNi0.5Fe0.5O3 for which 60% rhombohedral and 40% orthorhombic phase was found. The maximum DC electrical conductivity value of the perovskites at 800 °C was 1229 S cm-1 for the composition LaCoO3 and the minimum was 91 S cm-1 for the composition LaCo0.5Fe0.5O3. The oxygen permeation of samples with promising conductivities at 800 °C was one order of magnitude lower than that of La0.6Sr0.4Co0.8Fe0.2O3 (LSCF). The highest value of 0.017 ml cm-2 min-1 at 950 °C was obtained with LaNi0.5Co0.5O3. The coefficients of thermal expansion varied in the range of 13.2×10-6 K-1 and 21.9×10-6 K-1 for LaNi0.5Fe0.5O3 and LaCoO3, respectively. 57Fe Mössbauer spectroscopy was used as probe for the oxidation states, local environment and magnetic properties of iron ions as a function of chemical composition. The substitution had a great influence on the chemical properties of the materials. © 2016 Elsevier Inc. All rights reserved.

Disciplines :

Chemistry

Author, co-author :

Tietz, F.; Forschungszentrum Jülich GmbH, Institute of Energy and Climate Research, Materials Synthesis and Processing (IEK-1), Jülich, Germany

Arul Raj, I.; Central Electrochemical Research Institute, Karaikudi, Tamil Nadu, India

Ma, Q.; Forschungszentrum Jülich GmbH, Institute of Energy and Climate Research, Materials Synthesis and Processing (IEK-1), Jülich, Germany

Baumann, S.; Forschungszentrum Jülich GmbH, Institute of Energy and Climate Research, Materials Synthesis and Processing (IEK-1), Jülich, Germany

Mahmoud, Abdelfattah ; Université de Liège - ULiège > Département de chimie (sciences) > LCIS - GreenMAT

Hermann, Raphaël ; Université de Liège - ULiège > Département de chimie (sciences) > Département de chimie (sciences)

Title :

Material properties of perovskites in the quasi-ternary system LaFeO3-LaCoO3-LaNiO3

Publication date :

2016

Journal title :

Journal of Solid State Chemistry

ISSN :

0022-4596

eISSN :

1095-726X

Publisher :

Academic Press Inc.

Volume :

237

Pages :

183-191

Peer reviewed :

Peer Reviewed verified by ORBi

Funders :

ORNL, Oak Ridge National Laboratory

Available on ORBi :

since 28 November 2017

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Bibliography

B.C.H. Steele, and A. Heinzel Nature 414 2001 345 352
M. Mogensen, and S. Skaarup Solid State Ion. 88 1996 1151 1160
H. Yokokawa, H. Tu, B. Iwanschitz, and A. Mai J. Power Sources 182 2008 400 412
A. Mai, V.A.C. Haanappel, S. Uhlenbruck, F. Tietz, and D. Stöver Solid State Ion. 176 2005 1341 1350
S.P. Simner, J.F. Bonnett, N.L. Canfield, K.D. Meinhardt, V.L. Sprenkle, and J.W. Stevenson Electrochem. Solid-State Lett. 5 2002 A173 A175
A. Petric, P. Huang, and F. Tietz Solid State Ion. 135 2000 719 725
F. Tietz, I. Arul Raj, M. Zahid, and D. Stöver Solid State Ion. 177 2006 1753 1756
F. Tietz, I. Arul Raj, M. Zahid, A. Mai, and D. Stöver Progr. Solid State Chem. 35 2007 539 543
M. Zahid, I. Arul Raj, F. Tietz, and D. Stöver Solid State Sci. 9 2007 706 712
D.H. Peck, M. Miller, H. Nickel, D. Das, and K. Hilpert M. Dokiya, O. Yamamoto, H. Tagawa, S.C. Singhal, Proceedings of the 4th Int. Symp. Solid Oxide Fuel Cells (SOFC-IV) 1995 The Electrochemical Society Pennington, NJ 858 868
S.P.S. Badwal, R. Deller, K. Föger, Y. Ramprakash, and J.P. Zhang Solid State Ion. 99 1997 297 310
S.P. Jiang, J.P. Zhang, L. Apateanu, and K. Föger J. Electrochem. Soc. 147 2000 4013 4022
N.H. Menzler, P. Batfalsky, S.M. Groß, V. Shemet, and F. Tietz ECS Transact. 35 1 2011 195 206
E. Konysheva, H. Penkalla, E. Wessel, J. Mertens, U. Seeling, L. Singheiser, and K. Hilpert J. Electrochem. Soc. 153 2006 A765 A773
S.P. Jiang, S. Zhang, and Y.D. Zhen J. Electrochem. Soc. 153 2006 A127 A134
L. Niewolak, J.W. Quadakkers, and F. Tietz K. Kendall, M. Kendall, High-temperature Solid Oxide Fuel Cells for the 21st Century 2016 Elsevier 195 254, ISBN 978-0-12-410453-2
J. Sunarso, S. Baumann, J.M. Serra, W.A. Meulenberg, S. Liu, Y.S. Lin, and J.C. Diniz da Costa J. Membr. Sci. 320 2008 13 41
M. Arnold, H. Wang, and A. Feldhoff J. Membr. Sci. 293 2007 44 52
S. Engels, T. Markus, M. Modigell, and L. Singheiser J. Membr. Sci. 370 2011 58 69
R. Chiba, F. Yoshimura, and Y. Sakurai Solid State Ion. 124 1999 281 288
H. Orui, K. Watanabe, R. Chiba, and M. Arakawa J. Electrochem. Soc. 151 9 2004 A1412 A1417
H. Orui, K. Nozawa, R. Chiba, T. Komatsu, K. Watanabe, S. Sugita, H. Arai, and M. Arakawa ECS Transact. 7 2007 255 261
T. Komatsu, H. Arai, R. Chiba, K. Nozawa, M. Arakawa, and K. Sato Electrochem. Solid-State Lett. 9 2006 A9 A12
M. P. Pechini, US Patent No. 3,330,697, July 1967
S. Baumann, F. Schulze-Küppers, S. Roitsch, M. Betz, M. Zwick, E.M. Pfaff, W.A. Meulenberg, J. Mayer, and D. Stöver J. Membrane Sci. 359 2010 102 109
H. Taguchi, T. Komatsu, R. Chiba, K. Nozawa, H. Orui, and H. Arai Solid State Ion. 182 2011 127 132
R.D. Shannon Acta Crystallogr. A32 1976 751 767
J.E. Millburn, and M.J. Rosseinsky Chem. Mater. 9 1997 511 522
M.A. Señarís-Rodríguez, and J.B. Goodenough J. Solid State Chem. 118 1995 323
F. Tietz Proceedings of the 9th CIMTEC-World Ceramic Congress and Forum on New Materials P. Vincenzini, Innovative Materials in Advanced Energy Technologies Vol. 24 1999 Techna Publishers S.r.l., Faenza, Italy 61 70
K.S. Roh, K.H. Ryu, and C.H. Yo J. Solid State Chem. 142 1999 288 293
V.V. Kharton, A.P. Viskup, E.N. Naumovich, and V.N. Tikhonovich Mater. Res. Bull. 34 1999 1311 1317
X. Montero, W. Fischer, F. Tietz, M. Cassir, D. Stöver, and I. Villareal Solid State Ion. 180 2009 731 737
A. Mineshige, J. Izutsu, M. Nakamura, K. Nigaki, J. Abe, M. Kobune, S. Fujii, and T. Yazawa Solid State Ion. 176 2005 1145 1149
F. Schulze-Küppers, S. Baumann, F. Tietz, H.J.M. Bouwmeester, and W. A.Meulenberg J. Eur. Ceram. Soc. 34 2014 3741 3748
L.-P. Li, X.-Y. Song, W.-H. Su, Q. Wei, and Z.-J. Kang Hyperfine Interact. 116 1998 167-112
Y.-L. Chen, and D. Yang Mössbauer Effect in Lattice Dynamics: Experimental Techniques and Applications 2007 Wiley-VCH Weinheim
M. Romero, R.W. Gómez, V. Marquina, J.L. Pérez-Mazariego, and R. Escamilla Phys. B: Condens. Matter 443 2014 90 94
H. El Shinawi, J.F. Marco, F.J. Berry, and C. Greaves J. Solid State Chem. 182 2009 2261 2268
L. Samain, P. Amshoff, J.J. Biendicho, F. Tietz, A. Mahmoud, R.P. Hermann, S. Ya Istomin, J. Grins, and G. Svensson J. Solid State Chem. 227 2015 45 54
K. ͆wierczek, J. Marzec, D. Pałubiak, W. Zajac, and J. Molenda Solid State Ion. 177 2006 1811 1817
V.A.C. Haanappel, J. Mertens, D. Rutenbeck, C. Tropartz, W. Herzhof, D. Sebold, and F. Tietz J. Power Sources 141 2005 216 226