One-pot, Pd/Cu-catalysed synthesis of alkynyl-substituted 3-ylidene-dihydrobenzo[d]isothiazole 1,1-dioxides

[en] Enyne-substituted benzoisothiazole derivatives have been synthesised under one-pot, operationally simple conditions using 2-iodo-N-(trimethylsilylethynyl)benzenesulfonamides and terminal alkynes as starting materials and a palladium–copper-based catalytic system. The structure of these heterocycles has been demonstrated by NMR spectroscopy and confirmed by X-ray crystallographic analysis. A plausible reaction mechanism has been proposed.

Research center :

Chimie macromoléculaire et catalyse organique

Disciplines :

Chemistry

Author, co-author :

Etse, Koffi Senam ; Université de Liège > Département de chimie (sciences) > Département de chimie (sciences)

Dassoneville, Benjamin; Université de Liège - ULiège > Département de chimie (sciences) > Département de chimie (sciences)

Zaragoza, Guillermo; Universidade de Santiago de Compostela, Spain > Edificio CACTUS, Campus Vida > Unidade de Difracción de Raios X

Demonceau, Albert ; Université de Liège - ULiège > Département de chimie (sciences) > Département de chimie (sciences)

Language :

English

Title :

One-pot, Pd/Cu-catalysed synthesis of alkynyl-substituted 3-ylidene-dihydrobenzo[d]isothiazole 1,1-dioxides

Publication date :

22 February 2017

Journal title :

Tetrahedron Letters

ISSN :

0040-4039

Publisher :

Elsevier, Oxford, United Kingdom

Volume :

Issue :

Pages :

789–793

Peer reviewed :

Peer Reviewed verified by ORBi

Available on ORBi :

since 28 July 2017

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Bibliography

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