Sodium vanadium (III) fluorophosphate/carbon nanotubes composite (NVPF/CNT) prepared by spray-drying: good electrochemical performance thanks to well-dispersed CNT network within NVPF particles

Eshraghi, Nicolas; Caes, Sébastien; Mahmoud, Abdelfattah; Cloots, Rudi; Vertruyen, Bénédicte; Boschini, Frédéric

doi:10.1016/j.electacta.2017.01.026

Article (Scientific journals)

Sodium vanadium (III) fluorophosphate/carbon nanotubes composite (NVPF/CNT) prepared by spray-drying: good electrochemical performance thanks to well-dispersed CNT network within NVPF particles

Eshraghi, Nicolas; Caes, Sébastien; Mahmoud, Abdelfattah et al.

2017 • In Electrochimica Acta, 228, p. 319 - 324

Peer Reviewed verified by ORBi

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https://hdl.handle.net/2268/205797

DOI
10.1016/j.electacta.2017.01.026

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Keywords :

Spray drying; NASICON-type material; Electrochemistry; Hybrid-ion Batteries; Composite Electrode

Abstract :

[en] We successfully prepared NASICON-type Na3V2(PO4)2F3 (NVPF) and a Na3V2(PO4)2F3/carbon nanotubes (CNT) composite by spray-drying followed by heat treatment in argon for 2 hours at 600 °C. The addition of CNT in the spray-drying solution creates a CNT network within the NVPF particles. After grinding, the smaller NVPF particles remain linked by CNT. Thanks to this conducting network, the composite powder displays competitive electrochemical performance when cycled against lithium in hybrid-ion batteries (2–4.6 V vs. Li+/Li) with specific capacities of 125 mAh.g−1 at C/10, 103 mAh.g−1 at 1C and 91 mAh.g−1 at 4C, together with 97.5% capacity retention at 1C over 100 cycles with coulombic efficiency of 99.4%. These results demonstrate that sodium vanadium (III) fluorophosphate electrode material can be obtained in a time-efficient way using the easily up-scalable spray-drying method.

Research Center/Unit :

GreenMat
CESAM - Complex and Entangled Systems from Atoms to Materials - ULiège

Disciplines :

Chemistry

Author, co-author :

Eshraghi, Nicolas ; Université de Liège > Département de chimie (sciences) > LCIS - GreenMAT

Caes, Sébastien

Mahmoud, Abdelfattah ; Université de Liège > Département de chimie (sciences) > LCIS - GreenMAT

Cloots, Rudi ; Université de Liège > Département de chimie (sciences) > LCIS - GreenMAT

Vertruyen, Bénédicte ; Université de Liège > Département de chimie (sciences) > Chimie inorganique structurale

Boschini, Frédéric ; Université de Liège > Plateforme APTIS

Language :

English

Title :

Sodium vanadium (III) fluorophosphate/carbon nanotubes composite (NVPF/CNT) prepared by spray-drying: good electrochemical performance thanks to well-dispersed CNT network within NVPF particles

Publication date :

06 January 2017

Journal title :

Electrochimica Acta

ISSN :

0013-4686

Publisher :

Pergamon Press - An Imprint of Elsevier Science

Volume :

228

Pages :

319 - 324

Peer reviewed :

Peer Reviewed verified by ORBi

Additional URL :

http://www.sciencedirect.com/science/article/pii/S0013468617300269

Funders :

F.R.S.-FNRS - Fonds de la Recherche Scientifique
BATWAL project [PE Plan Marshall 2.vert]
Beware Fellowship Academia [2015-1, RESIBAT no. 1510399]
FRIA - Fonds pour la Formation à la Recherche dans l'Industrie et dans l'Agriculture

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