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[en] A new family of ligands (dual sigma - pi ligand), i.e. chelating lithium alkoxides, Li-O-(CH2-CH2O)nCH3, is shown to be very effective in promoting the living anionic Polymerization of methacrylic and acrylic esters, including a number of primary alkyl acrylates such as n-butyl acrylate and 2-ethylhexylacrylate.
Research Center/Unit :
Center for Education and Research on Macromolecules (CERM)
Disciplines :
Materials science & engineering Chemistry
Author, co-author :
Bayard, Philippe; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Jérôme, Robert ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Teyssié, Philippe ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Varshney, Sunil; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Wang, Jin-Shan; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Language :
English
Title :
A new family of "ligated" anionic initiators for the "living" polymerization of (meth)acrylic esters
Publication date :
April 1994
Journal title :
Polymer Bulletin
ISSN :
0170-0839
eISSN :
1436-2449
Publisher :
Springer Science & Business Media B.V., New York, United States - New York
