[en] Novel organocobalt complexes featuring weak C–CoL2 bonds (L = acetylacetonate) are prepared and used as sources of halomethyl radicals. They permit the precision synthesis of a-halide functionalized and telechelic polymers in organic media or in water. Substitution of halide by azide allows derivatization of polymers using the CuAAC click reaction.
Research Center/Unit :
Center for Education and Research on Macromolecules (CERM)
Disciplines :
Chemistry Materials science & engineering
Author, co-author :
Demarteau, Jérémy ; University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Kermagoret, Anthony; University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
German, Ian; University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Cordella, Daniela ; University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Robeyns, Koen; Université Catholique de Louvain (UCL), Institute of Condensed Matter and Nanosciences (IMCN)
De Winter, Julien; University of Mons-Hainaut (UMH), Organic Synthesis and Mass Spectrometry Laboratory
Gerbaux, Pascal; University of Mons-Hainaut (UMH), Organic Synthesis and Mass Spectrometry Laboratory
Jérôme, Christine ; University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Debuigne, Antoine ; University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Detrembleur, Christophe ; University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Language :
English
Title :
Halomethyl-cobalt(bis-acetylacetonate) for the controlled synthesis of functional polymers
Publication date :
01 October 2015
Journal title :
Chemical Communications
ISSN :
1359-7345
eISSN :
1364-548X
Publisher :
Royal Society of Chemistry, Cambridge, United Kingdom
Volume :
51
Issue :
76
Pages :
14334-14337
Peer reviewed :
Peer Reviewed verified by ORBi
European Projects :
FP7 - 289347 - RENAISSANCE - TRAINING NETWORK IN INNOVATIVE POLYELECTROLYTES FOR ENERGY AND ENVIRONMENT
Funders :
F.R.S.-FNRS - Fonds de la Recherche Scientifique FRIA - Fonds pour la Formation à la Recherche dans l'Industrie et dans l'Agriculture BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique CE - Commission Européenne