Halomethyl-cobalt(bis-acetylacetonate) for the controlled synthesis of functional polymers

Demarteau, Jérémy; Kermagoret, Anthony; German, Ian; Cordella, Daniela; Robeyns, Koen; De Winter, Julien; Gerbaux, Pascal; Jérôme, Christine; Debuigne, Antoine; Detrembleur, Christophe

doi:10.1039/C5CC04714E

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Article (Scientific journals)

Halomethyl-cobalt(bis-acetylacetonate) for the controlled synthesis of functional polymers

Demarteau, Jérémy; Kermagoret, Anthony; German, Ian et al.

2015 • In Chemical Communications, 51 (76), p. 14334-14337

Peer Reviewed verified by ORBi

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https://hdl.handle.net/2268/184993

DOI
10.1039/C5CC04714E

PubMed
26273709

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Keywords :

radical polymerization; cobalt-mediated radical polymerization (CMRP)

Abstract :

[en] Novel organocobalt complexes featuring weak C–CoL2 bonds (L = acetylacetonate) are prepared and used as sources of halomethyl radicals. They permit the precision synthesis of a-halide functionalized and telechelic polymers in organic media or in water. Substitution of halide by azide allows derivatization of polymers using the CuAAC click reaction.

Research Center/Unit :

Center for Education and Research on Macromolecules (CERM)

Disciplines :

Chemistry
Materials science & engineering

Author, co-author :

Demarteau, Jérémy ; University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Kermagoret, Anthony; University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

German, Ian; University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Cordella, Daniela ; University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Robeyns, Koen; Université Catholique de Louvain (UCL), Institute of Condensed Matter and Nanosciences (IMCN)

De Winter, Julien; University of Mons-Hainaut (UMH), Organic Synthesis and Mass Spectrometry Laboratory

Gerbaux, Pascal; University of Mons-Hainaut (UMH), Organic Synthesis and Mass Spectrometry Laboratory

Jérôme, Christine ; University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Debuigne, Antoine ; University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Detrembleur, Christophe ; University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Language :

English

Title :

Halomethyl-cobalt(bis-acetylacetonate) for the controlled synthesis of functional polymers

Publication date :

01 October 2015

Journal title :

Chemical Communications

ISSN :

1359-7345

eISSN :

1364-548X

Publisher :

Royal Society of Chemistry, Cambridge, United Kingdom

Volume :

Issue :

Pages :

14334-14337

Peer reviewed :

Peer Reviewed verified by ORBi

European Projects :

FP7 - 289347 - RENAISSANCE - TRAINING NETWORK IN INNOVATIVE POLYELECTROLYTES FOR ENERGY AND ENVIRONMENT

Funders :

F.R.S.-FNRS - Fonds de la Recherche Scientifique
FRIA - Fonds pour la Formation à la Recherche dans l'Industrie et dans l'Agriculture
BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique
CE - Commission Européenne

Available on ORBi :

since 17 August 2015

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