[en] The addition of fluorinated alcohols to onium salts provides highly efficient organocatalysts for the chemical fixation of CO2 onto epoxides under mild experimental conditions. The combination of online kinetic studies, NMR titrations and DFT calculations allows understanding this synergistic effect that provides an active organocatalyst for CO2/epoxides coupling.
Research Center/Unit :
Center for Education and Research on Macromolecules (CERM)
Disciplines :
Chemistry Materials science & engineering
Author, co-author :
Gennen, Sandro ; University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Alves, Margot ; University of Bordeaux, Institute of Molecular Sciences, France
Méreau, Raphaël; University of Bordeaux, Institute of Molecular Sciences, France
Tassaing, Thierry; University of Bordeaux, Institute of Molecular Sciences, France
Gilbert, Bernard ; University of Liège (ULg), Department of Chemistry, Analytic Chemistry and Electrochemistry
Detrembleur, Christophe ; University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Jérôme, Christine ; University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Grignard, Bruno ; University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Language :
English
Title :
Fluorinated alcohols as activators for the solvent-free chemical fixation of carbon dioxide onto epoxides
Publication date :
08 June 2015
Journal title :
ChemSusChem
ISSN :
1864-5631
eISSN :
1864-564X
Publisher :
Wiley-VCH, Weinheim, Germany
Volume :
8
Issue :
11
Pages :
1845-1849
Peer reviewed :
Peer Reviewed verified by ORBi
Funders :
the “Region Wallonne” in the frame of the CO2Green, Sinopliss and Flycoat projects BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique F.R.S.-FNRS - Fonds de la Recherche Scientifique The International Doctoral School IDS-FUNMAT
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