Fluorinated alcohols as activators for the solvent-free chemical fixation of carbon dioxide onto epoxides

Gennen, Sandro; Alves, Margot; Méreau, Raphaël; Tassaing, Thierry; Gilbert, Bernard; Detrembleur, Christophe; Jérôme, Christine; Grignard, Bruno

doi:10.1002/cssc.201500103

Request a copy

Article (Scientific journals)

Fluorinated alcohols as activators for the solvent-free chemical fixation of carbon dioxide onto epoxides

Gennen, Sandro; Alves, Margot; Méreau, Raphaël et al.

2015 • In ChemSusChem, 8 (11), p. 1845-1849

Peer Reviewed verified by ORBi

Permalink
https://hdl.handle.net/2268/180754

DOI
10.1002/cssc.201500103

PubMed
25951520

Files (2)Send to Details Statistics Bibliography Similar publications

Files

Full Text

Gennen_S 2015 ChemSusChem 8, 1845.pdf

Publisher postprint (877.83 kB)

Request a copy

Annexes

Gennen_S 2015 ChemSusChem 8, 1845 SI.pdf

Publisher postprint (816.23 kB)

Supplementary Information

Request a copy

All documents in ORBi are protected by a user license.

Send to

RIS BibTex APA Chicago Permalink X Linkedin

Details

Keywords :

supercritical carbon dioxide; cyclic carbonate

Abstract :

[en] The addition of fluorinated alcohols to onium salts provides highly efficient organocatalysts for the chemical fixation of CO2 onto epoxides under mild experimental conditions. The combination of online kinetic studies, NMR titrations and DFT calculations allows understanding this synergistic effect that provides an active organocatalyst for CO2/epoxides coupling.

Research Center/Unit :

Center for Education and Research on Macromolecules (CERM)

Disciplines :

Chemistry
Materials science & engineering

Author, co-author :

Gennen, Sandro ; University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Alves, Margot ; University of Bordeaux, Institute of Molecular Sciences, France

Méreau, Raphaël; University of Bordeaux, Institute of Molecular Sciences, France

Tassaing, Thierry; University of Bordeaux, Institute of Molecular Sciences, France

Gilbert, Bernard ; University of Liège (ULg), Department of Chemistry, Analytic Chemistry and Electrochemistry

Detrembleur, Christophe ; University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Jérôme, Christine ; University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Grignard, Bruno ; University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Language :

English

Title :

Fluorinated alcohols as activators for the solvent-free chemical fixation of carbon dioxide onto epoxides

Publication date :

08 June 2015

Journal title :

ChemSusChem

ISSN :

1864-5631

eISSN :

1864-564X

Publisher :

Wiley-VCH, Weinheim, Germany

Volume :

Issue :

Pages :

1845-1849

Peer reviewed :

Peer Reviewed verified by ORBi

Funders :

the “Region Wallonne” in the frame of the CO2Green, Sinopliss and Flycoat projects
BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique
F.R.S.-FNRS - Fonds de la Recherche Scientifique
The International Doctoral School IDS-FUNMAT

Available on ORBi :

since 21 April 2015

Statistics

Number of views

137 (31 by ULiège)

Number of downloads

19 (13 by ULiège)

More statistics

Scopus citations^®

105

Scopus citations^®
without self-citations

OpenCitations

OpenAlex citations

106

Bibliography

Hydrogen Bonding in Organic Synthesis (Ed.:, P. M. Pihko,), Wiley-VCH, Weinheim, 2009
D. A. G. Doyle, E. N. Jacobsen, Chem. Rev. 2007, 107, 5713-5743
T. Akiyama, Chem. Rev. 2007, 107, 5744-5758
M. K. Kiesewetter, E. J. Shin, J. L. Hedrick, R. M. Waymouth, Macromolecules 2010, 43, 2093-2107
D. Vuluga, J. Legros, B. Crousse, A. M. Z. Slavin, C. Laurence, P. Nicolet, D. Bonnet-Delpon, J. Org. Chem. 2011, 76, 1126-1133
A. Berkessel, J. A. Adrio, D. Hüttenhain, J. Neudörf, J. Am. Chem. Soc. 2006, 128, 8421-8426
P. I. Dalko, L. Moisan, Angew. Chem. Int. Ed. 2004, 43, 5138-5175
Angew. Chem. 2004, 116, 5248-5286.
J.-P. Begue, D. Bonnet-Delpon, B. Crousse, Synlett 2004, 18-29.
O. Coulembier, D. P. Sanders, A. Nelson, A. N. Hollenbeck, H. W. Horn, J. E. Rice, M. Fujiwara, P. Dubois, J. L. Hedrick, Angew. Chem. Int. Ed. 2009, 48, 5170-5173
Angew. Chem. 2009, 121, 5272-5275.
J. Legros, B. Crousse, D. Bonnet-Delpon, J.-P. Begue, Eur. J. Org. Chem. 2002, 3290-3293
M. C. A. van Vliet, I. W. E. C. Arends, R. A. Sheldon, Synlett 2001, 248-250
A. Berkessel, J. A. Adrio, Adv. Synth. Catal. 2004, 346, 275-280
K. Zmitek, S. Stavber, M. Zupan, D. Bonnet-Delpon, J. Iskra, Tetrahedron 2006, 62, 1479-1484
A. Berkessel, M. R. M. Andreae, H. Schmickler, J. Lex, Angew. Chem. Int. Ed. 2002, 41, 4481-4484
Angew. Chem. 2002, 114, 4661-4664.
N. Aoyagi, Y. Furusho, T. Endo, Tetrahedron Lett. 2013, 54, 7031-7034.
B. Chatelet, L. Joucla, J.-P. Dutasta, A. Martinez, K. C. Szeto, V. Dufaud, J. Am. Chem. Soc. 2013, 135, 5348-5351
T. Yoshihiro, Y. Kyohei, Y. Masahiko, E. Tadashi, S. Takashi, Org. Lett. 2010, 12, 5728-5731
K. R. Roshan, J. Tharun, D. Kim, A. C. Kathalikkattil, D.-W. Park, Catal. Sci. Technol. 2014, 4, 963-970
J. Tharun, G. Mathai, A. C. Kathalikkattil, R. Roshan, J.-Y. Kwak, D.-W. Park, Green Chem. 2013, 15, 1673-1677
K. R. Roshan, G. Mathai, J. Kim, J. Tharun, D.-W. Park, Green Chem. 2012, 14, 2933-2940.
D. Tian, B. Liu, Q. Gan, H. Li, D. J. Darensbourg, ACS Catal. 2012, 2, 2029-2035
X.-B. Lu, D. J. Darensbourg, Chem. Soc. Rev. 2012, 41, 1462-1484
M. Taherimehr, S. M. Al-Amsyar, C. J. Whiteoak, A. W. Kleij, P. P. Pescarmona, Green Chem. 2013, 15, 3083-3090
C. J. Whiteoak, N. Kielland, V. Laserna, E. C. Escudero-Adan, E. Martin, A. W. Kleij, J. Am. Chem. Soc. 2013, 135, 1228-1231
A. Decortes, M. Martinez Belmonte, J. Benet-Buchholz, A. W. Kleij, Chem. Commun. 2010, 46, 4580-4582.
N. Aoyagi, Y. Furusho, T. Endo, J. Polym. Sci. Part A 2013, 51, 1230-1242
V. Calõ, A. Nacci, A. Monopoli, A. Fanizzi, Org. Lett. 2002, 4, 2561-2563
S. Foltran, R. Mereau, T. Tassaing, Catal. Sci. Technol. 2014, 4, 1585-1597
S. Foltran, J. Alsarraf, F. Robert, Y. Landais, E. Cloutet, H. Cramail, T. Tassaing, Catal. Sci. Technol. 2013, 3, 1046-1055.
W.-L. Dai, J. Bi, S.-L. Luo, X.-B. Luo, X.-M. Tu, A. Chak-Tong, Catal. Today 2014, 233, 92-99
S. Takashi, T. Yoshihiro, E. Tadashi, Green Chem. 2008, 10, 337-341
Q.-W. Song, L.-N. He, J.-Q. Wang, H. Yasuda, T. Sakakura, Green Chem. 2013, 15, 110-115.
A.-L. Girard, N. Simon, M. Zanatta, S. Marmitt, P. Goncalves, J. Dupont, Green Chem. 2014, 16, 2815-2825
E.-H. Lee, J.-Y. Ahn, M. M. Dharman, D.-W. Park, S.-W. Park, I. Kim, Catal. Today 2008, 131, 130-134
Y. Zhao, C. Yao, G. Chen, Q. Yuan, Green Chem. 2013, 15, 446-452
H. Kawanami, A. Sasaki, K. Matsui, Y. Ikushima, Chem. Commun. 2003, 896-897.
T. Werner, H. Büttner, ChemSusChem 2014, 7, 3268-3271
T. Werner, N. Tenhumberg, H. Büttner, ChemCatChem 2014, 6, 3493-3500
M. E. Wilhelm, M. H. Anthofer, M. Cokoja, I. I. E. Markovits, W. A. Herrmann, F. E. Kühn, ChemSusChem 2014, 7, 1357-1360
T. Werner, N. Tenhumberg, J. CO2 Util. 2014, 7, 39-45
G. Fiorani, W. Guo, A. W. Kleij, Green Chem. 2015, 17, 1375-1389.
Y. Zhang, S. Yin, S. Luo, Shenglian, C. T. Au, Ind. Eng. Chem. Res. 2012, 51, 3951-3957
L. Han, H.-J. Choi, S.-J. Choi, B. Liu, D.-W. Park, Green Chem. 2011, 13, 1023-1028.
J. Sun, W. Cheng, Z. Yang, J. Wang, T. Xu, J. Xin, S. Zhang, Green Chem. 2014, 16, 3071-3078
E. Liang, H. Liu, T. Jiang, J. Song, G. Yang, B. Han, Chem. Commun. 2011, 47, 2131-2133
C. J. Whiteoak, A. Nova, F. Maseras, A. W. Kleij, ChemSusChem 2012, 5, 2032-2038.
A. M. Hardman-Baldwin, A. E. Mattson, ChemSusChem 2014, 7, 3275-3278.
B. Grignard, B. Gilbert, C. Malherbe, C. Jérôme, C. Detrembleur, ChemPhysChem 2012, 13, 2666-2670.
J.-Q. Wang, K. Dong, W.-G. Cheng, J. Sun, S.-J. Zhang, Catal. Sci. Technol. 2012, 2, 1480-1484.