Fluorinated alcohols as activators for the solvent-free chemical fixation of carbon dioxide onto epoxides

Gennen, Sandro; Alves, Margot; Méreau, Raphaël; Tassaing, Thierry; Gilbert, Bernard; Detrembleur, Christophe; Jérôme, Christine; Grignard, Bruno

doi:10.1002/cssc.201500103

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Article (Scientific journals)

Fluorinated alcohols as activators for the solvent-free chemical fixation of carbon dioxide onto epoxides

Gennen, Sandro; Alves, Margot; Méreau, Raphaël et al.

2015 • In ChemSusChem, 8 (11), p. 1845-1849

Peer Reviewed verified by ORBi

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https://hdl.handle.net/2268/180754

DOI
10.1002/cssc.201500103

PubMed
25951520

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Keywords :

supercritical carbon dioxide; cyclic carbonate

Abstract :

[en] The addition of fluorinated alcohols to onium salts provides highly efficient organocatalysts for the chemical fixation of CO2 onto epoxides under mild experimental conditions. The combination of online kinetic studies, NMR titrations and DFT calculations allows understanding this synergistic effect that provides an active organocatalyst for CO2/epoxides coupling.

Research center :

Center for Education and Research on Macromolecules (CERM)

Disciplines :

Chemistry
Materials science & engineering

Author, co-author :

Gennen, Sandro ; University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Alves, Margot ; University of Bordeaux, Institute of Molecular Sciences, France

Méreau, Raphaël; University of Bordeaux, Institute of Molecular Sciences, France

Tassaing, Thierry; University of Bordeaux, Institute of Molecular Sciences, France

Gilbert, Bernard ; University of Liège (ULg), Department of Chemistry, Analytic Chemistry and Electrochemistry

Detrembleur, Christophe ; University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Jérôme, Christine ; University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Grignard, Bruno ; University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Language :

English

Title :

Fluorinated alcohols as activators for the solvent-free chemical fixation of carbon dioxide onto epoxides

Publication date :

08 June 2015

Journal title :

ChemSusChem

ISSN :

1864-5631

eISSN :

1864-564X

Publisher :

Wiley-VCH, Weinheim, Germany

Volume :

Issue :

Pages :

1845-1849

Peer reviewed :

Peer Reviewed verified by ORBi

Funders :

the “Region Wallonne” in the frame of the CO2Green, Sinopliss and Flycoat projects
BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique
F.R.S.-FNRS - Fonds de la Recherche Scientifique [BE]
The International Doctoral School IDS-FUNMAT

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since 21 April 2015

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