The published manuscript is available at EurekaSelect via http://www.eurekaselect.com/openurl/content.php?genre=article&doi=10.2174/187640290601140919123530.
All documents in ORBi are protected by a user license.
[en] We present the structural and magnetic properties of a multiferroic Ba2Mg2Fe12O22 hexaferrite composite containing a small amount of MgFe2O4. The composite material was obtained by auto-combustion synthesis and, alternatively, by co-precipitation. The Ba2Mg2Fe12O22 particles obtained by co-precipitation have an almost perfect hexagonal shape in contrast with those prepared by auto-combustion. Two magnetic phase transitions, responsible for the composite’s multiferroic properties, were observed, namely, at 183 K and 40 K for the material produced by auto-combustion, and at 196 K and 30 K for the sample prepared by co-precipitation. No magnetic phase transitions in these temperature ranges were observed for a MgFe2O4 sample, which shows that the magnesium ferrite does not affect the multiferroic properties of this type of multiferroic metarials.
Disciplines :
Chemistry
Author, co-author :
Koutzarova, T.; Institute of Electronics, Bulgarian Academy of Sciences, 72 Tsarigradsko ChausseeSofia, Bulgaria
Kolev, Svetoslav; Institute of Electronics, Bulgarian Academy of Sciences, 72 Tsarigradsko ChausseeSofia, Bulgaria
Nedkov, I.; Institute of Electronics, Bulgarian Academy of Sciences, 72 Tsarigradsko ChausseeSofia, Bulgaria
Krezhov, Kiril; Institute for Nuclear Research and Nuclear Energy, Bulgarian Academy of Sciences, 72 Tsarigradsko Chaussee. Blvd.Sofia, Bulgaria
Kovacheva, D.; Institute of General and Inorganic Chemistry, Bulgarian Academy of Sciences, Acad. Georgi Bonchev Str., bld. 11Sofia, Bulgaria
Ghelev, C.; Institute of Electronics, Bulgarian Academy of Sciences, 72 Tsarigradsko ChausseeSofia, Bulgaria
Vertruyen, Bénédicte ; Université de Liège - ULiège > Département de chimie (sciences) > Chimie inorganique structurale
Henrist, Catherine ; Université de Liège - ULiège > Département de chimie (sciences) > LCIS - GreenMAT
Cloots, Rudi ; Université de Liège - ULiège > Département de chimie (sciences) > LCIS - GreenMAT
Language :
English
Title :
Study of quasi-monophase Y-type hexaferrite Ba2Mg2Fe12O22 powder
Cheong, S.-W.; Mostovoy, M. Multiferroics: a magnetic twist for ferroelectricity. Nat. Mater., 2007, 6, 13-20.
Taniguchi, K.; Abe, N.; Ohtani, S.; Umetsu, H.; Arima, T. Fef-foelictric polarization reversal by a magnetic field in multiferroic Y-type hexaferrite Ba2Mg2Fe12O22. Appl. Phys. Express, 2008, 1, 031301.
Temuujin, J.; Aoyama, M.; Senna, M.; Masuko, T.; Ando, C.; Kishi, H. Synthesis of Y-type hexaferrite via a soft mechanochemi-cal route. J. Solid State Chem., 2004, 177, 3903-3908.
Kamishima, K.; Ito, C.; Kakizaki, K.; Hiratsuka, N.; Shirahata, T.; Imakubo, T. Improvement of initial permeability for Z-type ferrite by Ti and Zn substitution. J. Magn. Magn. Mater., 2007, 312, 228-233.
Momozava, N.; Yamaguchi, Y.; Mita, M. Magnetic structure change in Ba2Mg2Fe12O22. J. Phys. Soc. Jpn., 1986, 55, 1350-1358.
Nakamura, S.; Tsunoda, Y.; Fuwa A. Moesbauer Study on Y-type hexaferrite Ba2Mg2Fe12O22. Hyperfine Interact., 2012, 208, 49-52.
Tokura, Y.; Seki, S. Multiferroics with spiral spin orders. Adv. Mater., 2010, 22, 1554-1565.
Ishiwata, S.; Okuyama, D.; Kakurai, K.; Nishi, M.; Taguchi, Y.; Tokura, Y.; Neutron diffraction studies on the multiferroic conical magnet Ba2Mg2Fe12O22. Phys. Rev. B., 2010, 81, 174418.
Ishiwata, S.; Taguchi, Y.; Murakawa, H.; Onose, Y.; Tokura Y. Low-magnetic-field control of electric polarization vector in a helimagnet. Science, 2008, 319, 1643-1646.
Kida, N.; Okuyama, D.; Ishiwata, S.; Taguchi, Y.; Shimano, R.; Iwasa, K.; Arima, T.; Tokura, Y. Electric-dipole-active magnetic resonance in the conical-spin magnet Ba2Mg2Fe12O22. Phys. Rev. B., 2009, 80, 220406(R).
Sagayama, H.; Taniguchi, K.; Abe, N.; Arima, T.; Nishikawa, Y.; Yano, S.; Kousaka, Y.; Akimitsu, J.; Matsuura, M.; Hirota, K. Two distinct ferroelectric phases in the multiferroic Y-type hexaferrite Ba2Mg2Fe12O22. Phys. Rev. B., 2009, 80, 180419(R).
Ishiwata, S.; Taguchi, Y.; Murakawa, H.; Onose, Y.; Tokura, Y. Magnetic-field control of electric polarization in a helimagnetic hexaferrite Ba2Mg2Fe12O22. J. Phys. Condens. Matter, 2009, 150, 042073.
Pullar, R. C. Hexagonal ferrites: A review of the synthesis, properties and applications of hexaferrite ceramics. Prog. Mater. Sci., 2012, 57, 1191-1334.
Ahmed, Y. M. Z.; Ewais, E. M. M.; Zaki, Z. I. In situ synyhesis of high dencity magnetic ferrite spinel (MgFe2O4) compacts using a mixture of conventional raw materials and waste iron oxide. J. Alloys Compd., 2010, 489, 269-274.
Maensiri, S.; Sangmanee, M; Wiengmoon, A. Magnesium ferrite (MgFe2O4) nanostructures fabricated by electrospinning. Nanoscale Res. Lett., 2009, 4, 221-228.
Antic, B.; Jovic, N.; Pavlovic, M. B.; Kremenovic, A.; Manojlovi, D. Magnetization enhancement in nanostructured random type MgFe2O4 spinel prepared by soft mechanochemical route. J. Appl. Phys., 2010, 107, 043525.
Navrotsky, A.; Kleppa, J. O. The thermodynamics of cation distributions in simple spinels. J. Inorg. Nucl. Chem., 1967, 29, 2701-2714.
Gateshki, M.; Petkov, V.; Pradhan, S.; Vogt T. Structure of nanocrystalline MgFe2O4 from X-ray diffraction, Rietveld and atomic pair distribution function analysis. J. Appl. Crystallogr., 2005, 38, 772-779.
Harrison, R. J.; Putnis, A. Determination of tehmechanism of cation ordering in magnesioferrite (MgFe2O4) from the time-and tempera-ture-dependence of magnetic susceptibility. Phys. Chem. Miner., 1999, 26, 322-332.
Rane, K. S.; Verenkar, V. M. S.; Sawant P. Y. Dielectric behaviour of MgFe2O4 prepared from chemically beneficiated iron ore rejects. Bull. Mater. Sci., 2001, 24, 323-330.
Manickam, S.; Rana, R. K. In: Ultrasound Technologies for Food and Bioprocessing; Feng, H.; Barbosa-Canovas, G.; Weiss, J., Eds.; Food Engineering Series, Springer Science+Business Media, LLC, 2011, pp. 405-444.
Koutzarova, T.; Kolev, S.; Nedkov, I.; Krezhov, K.; Kovacheva, D.; Blagoev, B.; Ghelev, Ch.; Henrist, C.; Cloots, R.; Zaleski, A. Magnetic properties of nanosized Ba2Mg2Fe12O22 powders obtained by auto-combustion. J. Supercond. Novel Magn., 2011, 25(8), 2631-2635.
Kida, N.; Kumakura, S.; Ishiwata, S.; Taguchi, Y.; Tokura Y. Gigantic terahertz magnetochromism via electromagnons in the hex-aferrite magnet Ba2Mg2Fe12O22. Phys. Rev. B., 2011, 83, 064422.