Stimuli-responsive behavior of micelles prepared from a poly(vinyl alcohol)-block-poly(acrylic acid)-block-poly(4-vinylpyridine) triblock terpolymer

Poggi, Elio; Guerlain, Claire; Debuigne, Antoine; Detrembleur, Christophe; Gigmes, Didier; Hoeppener, Stephanie; Schubert, Ulrich S.; Fustin, Charles-André; Gohy, Jean-François

doi:10.1016/j.eurpolymj.2014.06.026

Article (Scientific journals)

Stimuli-responsive behavior of micelles prepared from a poly(vinyl alcohol)-block-poly(acrylic acid)-block-poly(4-vinylpyridine) triblock terpolymer

Poggi, Elio; Guerlain, Claire; Debuigne, Antoine et al.

2015 • In European Polymer Journal, 62, p. 418-425

Peer Reviewed verified by ORBi

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https://hdl.handle.net/2268/176656

DOI
10.1016/j.eurpolymj.2014.06.026

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Keywords :

radical polymerization; cobalt-mediated radical polymerization (CMRP); stimuli responsive micelle

Abstract :

[en] A poly(vinyl alcohol)-block-poly(acrylic acid)-block-poly(4-vinylpyridine) triblock terpolymer (PVOH-b-PAA-b-P4VP) is prepared by hydrolyzing a poly(vinyl acetate)-block-poly(acrylonitrile)-block-poly(4-vinylpyridine) precursor (PVAc-b-PAN-b-P4VP) synthesized by a combination of cobalt-mediated radical polymerization (CMRP) and nitroxide mediated polymerization (NMP). The PVOH-b-PAA-b-P4VP terpolymer is further micellized in water and the accordingly obtained micellar structures are characterized by a combination of dynamic light scattering (DLS) and cryo-transmission electron microscopy (cryo-TEM) as a function of pH. Well-defined micelles are observed in the whole pH range except for pH values below 4.5 where non-aggregated chains (unimers) are present. The formation of micelles can be rationalized by the formation of insoluble PAA/P4VP inter-polyelectrolyte complexes in the 4.5–6 pH range while hydrophobic P4VP cores are observed at pH values above 6. Finally, the effect of the addition of different salts on the micellar characteristic features is investigated.

Research Center/Unit :

Center for Education and Research on Macromolecules (CERM)

Disciplines :

Chemistry
Materials science & engineering

Author, co-author :

Poggi, Elio; Université catholique de Louvain (UCL), Institute of Condensed Matter and Nanosciences, Bio and Soft Matter

Guerlain, Claire; Université catholique de Louvain (UCL), Institute of Condensed Matter and Nanosciences, Bio and Soft Matter

Debuigne, Antoine ; University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Detrembleur, Christophe ; University of Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Gigmes, Didier; University of Aix-Marseille, France, CNRS, Institut de Chimie Radicalaire, UMR 7273

Hoeppener, Stephanie; Friedrich Schiller University Jena and Jena Center for Soft Matter, Germany, Laboratory of Organic and Macromolecular Chemistry

Schubert, Ulrich S.; Friedrich Schiller University Jena and Jena Center for Soft Matter, Germany, Laboratory of Organic and Macromolecular Chemistry

Fustin, Charles-André; Université catholique de Louvain (UCL), Institute of Condensed Matter and Nanosciences, Bio and Soft Matter

Gohy, Jean-François; Université catholique de Louvain (UCL), Institute of Condensed Matter and Nanosciences, Bio and Soft Matter

Language :

English

Title :

Stimuli-responsive behavior of micelles prepared from a poly(vinyl alcohol)-block-poly(acrylic acid)-block-poly(4-vinylpyridine) triblock terpolymer

Publication date :

January 2015

Journal title :

European Polymer Journal

ISSN :

0014-3057

eISSN :

1873-1945

Publisher :

Elsevier Science

Volume :

Pages :

418-425

Peer reviewed :

Peer Reviewed verified by ORBi

Funders :

F.R.S.-FNRS - Fonds de la Recherche Scientifique
BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique
The ESF for the P2M program

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Bibliography

N. Rapoport Prog Polym Sci 32 2007 962 990
D. Roy, J. Cambre, and B. Sumerlin Prog Polym Sci 35 2010 278 301
F. Liu, and M. Urban Prog Polym Sci 35 2010 3 23
M.A.C. Stuart, W.T.S. Huck, J. Genzer, M. Müller, C. Ober, and M. Stamm Nat Mater 9 2010 101 113
E. Gil, and S. Hudson Prog Polym Sci 29 2004 1173 1222
I. Hamley The Physics of Block Copolymers 1998 Oxford University Press New York
G. Riess Prog Polym Sci 28 2003 1107 1170
J.-F. Gohy Adv Polym Sci 190 2005 65 136
Z.L. Tyrrell, Y. Shen, and M. Radosz Prog Polym Sci 35 2010 1128 1143
K. Szczubiaka, U. Moczek, S. Baszkiewicz, and M. Nowakowska J Polym Sci, Part A: Polym Chem 42 2004 3879 3886
K. Sumaru, M. Kameda, T. Kanamori, and T. Shinbo Macromolecules 37 2004 4949 4955
D. Roy, J.N. Cambre, and B.S. Sumerlin Chem Commun 2009 2106
A. Klaikherd, C. Nagamani, and S. Thayumanavan J Am Chem Soc 131 2009 4830 4838
J. Weiss, and A. Laschewsky Langmuir 27 2011 4465 4473
Q. Jin, G. Liu, and J. Ji J Polym Sci, Part A: Polym Chem 48 2010 2855 2861
J. Hu, and S. Liu Macromolecules 43 2010 8315 8330
S. Guragain, B.P. Bastakoti, S.-I. Yusa, and K. Nakashima Polymer 51 2010 3181 3186
A.E. Smith, X. Xu, S.E. Kirkland-York, D.A. Savin, and C.L. Mccormick Macromolecules 43 2010 1210 1217
S. Liu, and S.P. Armes Langmuir 19 2003 4432 4438
V. Bütün, N.C. Billingham, and S.P. Armes J Am Chem Soc 120 1998 11818 11819
J.-F. Gohy, S.K. Varshney, and R. Jérôme Macromolecules 24 2001 3361 3366
W. Agut, A. Brûlet, C. Schatz, D. Taton, and S. Lecommandoux Langmuir 26 2010 10546 10554
C.-A. Fustin, V. Abetz, and J.-F. Gohy Eur Phys J E 16 2005 291 302
J.F. Gohy, N. Willet, S. Varshney, J.X. Zhang, and R. Jérôme Angew Chem Int Ed 40 2001 3214 3216
E. Giebeler, and R. Stadler Macromol Chem Phys 198 1997 3815 3825
C. Tsitsilianis, Y. Roiter, I. Katsampas, and S. Minko Macromolecules 41 2008 925 934
R. Bryaskova, D. Pencheva, M. Kyulavska, D. Bozukova, A. Debuigne, and C. Detrembleur J Colloid Interface Sci 344 2010 424 428
C.M. Hassan, and N.A. Peppas Adv Polym Sci 153 2000 37 65
C. Detrembleur, A. Debuigne, C. Jérôme, T.N.T. Phan, D. Bertin, and D. Gigmes Macromolecules 42 2009 8604 8607
A. Debuigne, R. Poli, C. Jérôme, R. Jérôme, and C. Detrembleur Prog Polym Sci 34 2009 211 239
M. Hurtgen, C. Detrembleur, C. Jérôme, and A. Debuigne Polym Rev 51 2011 188 213
S.N. Sidorov, L.M. Bronstein, Y.A. Kabachii, M. Peter, P.L. Soo, and D. Maysinger Langmuir 20 2004 3543 3550
K. Wu, L. Shi, W. Zhang, Y. An, X.X. Zhu, and X. Zhang Soft Matter 1 2005 455 459
K. Wu, L. Shi, W. Zhang, Y. An, X. Zhang, and Z. Li Langmuir 22 2006 1474 1477
T.K. Bronich, P.A. Keifer, L.S. Shlyakhtenko, and A.V. Kabanov J Am Chem Soc 127 2005 8236 8237

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