Coordination of alkali metal ions to model branched hexasaccharides dictates fragment yield in MALDI in-source decay with hydrogen abstraction using 5-nitrosalicylic acid as the matrix
Asakawa, Daiki; Smargiasso, Nicolas; De Pauw, Edwin
2014 • In Journal of Mass Spectrometry, 49, p. 1059-1062
[en] The differences among MALDI-ISD spectra of hexasaccharides cationized with various alkali metals are reflected in the different stabilities of the ‘hydrogen-deficient’ glycan radical. The stability order of alkali metal-glycan radical complexes is proportional to the size of the alkali metal cation, K+ > Na+ > Li+. The Coordination of alkali metal ions to model branched hexasaccharides is the major parameter that dictates the fragment yield in MALDI in-source decay with hydrogen abstraction using 5-nitrosalicylic acid as the matrix
Research center :
Giga-Systems Biology and Chemical Biology - ULiège
Disciplines :
Chemistry
Author, co-author :
Asakawa, Daiki; Université de Liège - ULiège > Département de Chimie > Laboratoire de spectrométrie de masse (LSM)
Smargiasso, Nicolas ; Université de Liège - ULiège > Département de chimie (sciences) > Laboratoire de spectrométrie de masse (L.S.M.)
De Pauw, Edwin ; Université de Liège - ULiège > Département de chimie (sciences) > Laboratoire de spectrométrie de masse (L.S.M.)
Language :
English
Title :
Coordination of alkali metal ions to model branched hexasaccharides dictates fragment yield in MALDI in-source decay with hydrogen abstraction using 5-nitrosalicylic acid as the matrix
Publication date :
29 September 2014
Journal title :
Journal of Mass Spectrometry
ISSN :
1076-5174
eISSN :
1096-9888
Publisher :
John Wiley & Sons, Inc, Chichester, United Kingdom
F.R.S.-FNRS - Fonds de la Recherche Scientifique [BE] Japan Society for the Promotion of Science for Young Scientists FEDER - Fonds Européen de Développement Régional [BE]
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