[en] An ordered mesoporous carbon (OMC) was functionalized with ammonium or chelating phosphine ligands. In both cases, the functionalization procedure started by oxidation by nitric acid treatment, followed by activation of surface carboxylic acid groups with thionyl chloride, then formation of amide bonds with diamines. The pendant amine groups were then either quaternized or further reacted with phosphine. The introduced functions were used as anchors for molecular mixed-metal clusters. These organometallic grafted species could then be thermally transformed into hetero-metallic nanoparticles (NP) embedded within the mesoporous framework. The NP/OMC nanocomposites could find application in hydrogenation, heterogeneous catalysis or as electrodes in fuel cells.
Disciplines :
Chemistry
Author, co-author :
Vidick, Deborah; Université Catholique de Louvain - UCL > Institute of Condensed Matter and Nanosciences
Léonard, Alexandre ; Université de Liège - ULiège > Département de chimie appliquée > Ingéniérie électrochimique
Poleunis, Claude; Université Catholique de Louvain - UCL > Institute of Condensed Matter and Nanosciences
Delcorte, Arnaud; Université Catholique de Louvain - UCL > Institute of Condensed Matter and Nanosciences
Devillers, Michel; Université Catholique de Louvain - UCL > Institute of Condensed Matter and Nanosciences
Hermans, Sophie; Université Catholique de Louvain - UCL > Institute of Condensed Matter and Nanosciences
Language :
English
Title :
Phosphine- and ammonium-functionalized ordered mesoporous carbons as supports for cluster-derived metal nanoparticles
G. Liu, J. Ma, X. Li, and Q. Qin J. Hazard. Mater. 164 2009 1275 1280
P. Serp, and J.L. Figueiredo Carbon Materials for Catalysis 2009 John Wiley & Sons Hoboken, NJ
F. Rodriguez-Reinoso J.W. Patrick, Porosity in Carbons 1995 Wiley UK 253
A. Stein, Z. Wang, and M.A. Fierke Adv. Mater. 21 2009 265 293
J.L. Figueiredo J. Mater. Chem. A 1 2013 9351 9364
N. Job, R. Pirard, J. Marien, and J.P. Pirard Carbon 42 2004 619 628
T.Y. Ma, L. Liu, and Z.Y. Yuan Chem. Soc. Rev. 42 2013 3977 4003
R. Ryoo, S.H. Joo, and S. Jun J. Phys. Chem. B 103 1999 7743 7746
S. Jun, S.H. Joo, R. Ryoo, M. Kruk, M. Jaroniec, Z. Liu, T. Ohsuna, and O. Terasaki J. Am. Chem. Soc. 122 2000 10712 10713
D.Y. Zhao, Q.S. Huo, J.L. Feng, B.F. Chmelka, and G.D. Stucky J. Am. Chem. Soc. 120 1998 6024
C.D. Liang, Z.J. Li, and S. Dai Angew. Chem. Int. Ed. 47 2008 3696 3717
A.H. Lu, and F. Schüth Adv. Mater. 18 2006 1793 1805
I. Muylaert, A. Verberckmoes, J. De Decker, and P. Van Der Voort Adv. Colloid. Interface Sci. 175 2012 39 51
F.Q. Zhang, Y. Meng, D. Gu, Y. Yan, Z.X. Chen, B. Tu, and D.Y. Zhao Chem. Mater. 18 2006 5279 5288
S. Tanaka, N. Nishiyama, Y. Egashira, and K. Ueyama Chem. Commun. 2005 2125 2127
X.C. Zhao, A. Wang, J.W. Yan, G.Q. Sun, L.X. Sun, and T. Zhang Chem. Mater. 22 2010 5463 5473
D. Liu, J.H. Lei, L.P. Guo, D. Qu, Y. Li, and B.L. Su Carbon 50 2012 476 487
K.-I. Min, J.-S. Choi, Y.M. Chung, W.S. Ahn, R. Ryoo, and P.K. Lim Appl. Catal. A 337 2008 97
P. Gao, A.Q. Wang, X.D. Wang, and T. Zhang Chem. Mater. 20 2008 1881 1888
Y. Zhai, Y. Dou, X. Liu, S.S. Park, C.S. Ha, and D.Y. Zhao Carbon 49 2011 545 555
A.H. Lu, W. Schmidt, N. Matoussevitch, H. Bönnemann, B. Spliethoff, B. Tesche, E. Bill, W. Kiefer, and F. Schüth Angew. Chem. Int. Ed. 43 2004 4303 4306
A.H. Lu, W.C. Li, Z. Hou, and F. Schüth Chem. Commun. 2007 1038
K.S. Ha, G. Kwak, K.W. Jun, J. Hwang, and J. Lee Chem. Commun. 49 2013 5141 5143
X. Wang, R. Liu, M.M. Waje, Z. Chen, Y. Yan, K.N. Bozhilov, and P. Feng Chem. Mater. 19 2007 2395 2397
C. Freire, and A.R. Silva P. Serp, J.L. Figueiredo, Carbon Materials for Catalysis 2009 John Wiley & Sons Hoboken, NJ 267 307
A.R. Silva, C. Freire, B. de Castro, M.M.A. Freitas, and J.L. Figueiredo Micropor. Mesopor. Mater. 46 2001 211 221
K. Scholz, J. Scholz, A.J. McQuillan, G. Wagner, and O. Klepel Carbon 48 2010 1788
W.C. Choi, S.I. Woo, M.K. Jeon, J.M. Sohn, M.R. Kim, and H.J. Jeon Adv. Mater. 17 2005 446
S.H. Joo, S.J. Choi, I. Oh, J. Kwak, Z. Liu, O. Terasaki, and R. Ryoo Nature 412 2001 169
F.B. Su, J.H. Zeng, X.Y. Bao, Y.S. Yu, J.Y. Lee, and X.S. Zhao Chem. Mater. 17 2005 3960
F.B. Su, X.S. Zhao, Y. Wang, J.H. Zeng, Z.C. Zhou, and J.Y. Lee J. Phys. Chem. B 109 2005 20200
F.B. Su, H.J. Zeng, Y.J. Yu, L. Lv, J.Y. Lee, and X.S. Zhao Carbon 43 2005 2368
Y.L. Cao, J.M. Cao, M.B. Zheng, J.S. Liu, G.B. Ji, and H.M. Ji J. Nanosci. Nanotechnol. 7 2007 504
A.H. Lu, W.C. Li, Z.S. Hou, and F. Schuth Chem. Commun. 2007 1038
Y. Wan, H.Y. Wang, Q.F. Zhao, M. Klingstedt, O. Terasaki, and D.Y. Zhao J. Am. Chem. Soc. 131 2009 4541
S.M. Holmes, P. Foran, E.P.L. Roberts, and J.M. Newton Chem. Commun. 2005 1912
J. Lee, S.M. Jin, Y. Hwang, J.G. Park, H.M. Park, and T. Hyeon Carbon 43 2005 2536
A.H. Lu, W. Schmidt, N. Matoussevitch, H. Bonnemann, B. Spliethoff, B. Tesche, E. Bill, W. Kiefer, and F. Schuth Angew. Chem. Int. Ed. 43 2004 4303
T. Yu, Y.H. Deng, L. Wang, R.L. Liu, L.J. Zhang, B. Tu, and D.Y. Zhao Adv. Mater. 19 2007 2301
M.-L. Lin, M.-Y. Lo, and C.-Y. Mou J. Phys. Chem. C 113 2009 16158
G.S. Chai, S.B. Yoon, J.S. Yu, J.H. Choi, and Y.E. Sung J. Phys. Chem. B 108 2004 7074
L. Calvillo, M.J. Lázaro, E. García-Bordejé, R. Moliner, P.L. Cabot, I. Esparbé, E. Pastor, and J.J. Quintana J. Power Sources 169 2007 59
G. Álvarez, F. Alcaide, O. Miguel, L. Calvillo, M.J. Lázaro, J.J. Quintana, J.C. Calderón, and E. Pastor J. Solid State Electrochem. 14 2010 1027
A.C.W. Koh, L.W. Chen, W.K. Leong, T.P. Ang, B.F.G. Johnson, T. Khimyak, and J.Y. Lin Int. J. Hydrogen Energy 34 2009 5691
C.X. Li, W.K. Leong, and Z.Y. Zhong J. Organomet. Chem. 694 2009 2315
S. Chotisuwan, J. Wittayakan, and B.C. Gates J. Phys. Chem. B 110 2006 12459
A. Siani, B. Captain, R.D. Adams, O.S. Alexeev, and M.D. Amiridis Top. Catal. 54 2011 318
R. Raja, T. Khimyak, J.M. Thomas, S. Hermans, and B.F.G. Johnson Angew. Chem. Int. Ed. 40 2001 4638
J.M. Thomas, B.F.G. Johnson, R. Raja, G. Sankar, and P.A. Midgley Accounts Chem. Res. 36 2003 20
C. Vollmer, E. Redel, K. bu-Shandi, R. Thomann, H. Manyar, C. Hardacre, and C. Janiak Chem. Eur. J. 16 2010 3849
S.M. Yunusov, E.S. Kalyuzhnaya, H. Mahapatra, V.K. Puri, V.A. Likholobov, and V.B. Shur J. Mol. Catal. A: Chem. 139 1999 219
Y. Zhu, H.F. Qian, M.Z. Zhu, and R.C. Jin Adv. Mater. 22 2010 1915
R.S. Armstrong, T. Bell, A.F. Masters, M.A. Williams, and A.L. Chaffee Polyhedron 9 1990 2815
P. Moggi, G. Predieri, F. Di Silvestri, and A. Ferretti Appl. Catal. A 182 1999 257
D. Vidick, M. Herlitschke, C. Poleunis, A. Delcorte, R.P. Hermann, M. Devillers, and S. Hermans J. Mater. Chem. A 1 2013 2050 2063
S. Hermans, C. Diverchy, V. Dubois, and M. Devillers Appl. Catal. A: Gen. 2013 10.1016/j.apcata.2013.09.029 (in press)
P. Chini, L. Colli, and M. Peraldo Gazz. Chim. Ital. 90 1960 1005
J.N. Nicholls, M.D. Vargas, J. Hriljac, and M. Sailor Inorg. Synth. 26 1989 280
S. Hermans, T. Khimyak, and B.F.G. Johnson J. Chem. Soc. Dalton Trans. 2001 3295
M.I. Bruce, E. Horn, P.A. Humphrey, and E.R.T. Tiekink J. Organomet. Chem. 518 1996 121
B.F.G. Johnson, J. Lewis, W.J.H. Nelson, J.N. Nicholls, J. Puga, P.R. Raithby, M.J. Rosales, M. Schröder, and M.D. Vargas J. Chem. Soc. Dalton Trans. 1983 2447
A.G. Cowie, B.F.G. Johnson, J. Lewis, and P.R. Raithby J. Chem. Soc. Chem. Commun. 1984 1710
T. Khimyak, B.F.G. Johnson, S. Hermans, and A.D. Bond Dalton Trans. 2003 2651
C. Willocq, D. Vidick, B. Tinant, A. Delcorte, P. Bertrand, M. Devillers, and S. Hermans Eur. J. Inorg. Chem. 2011 4721 4729
P.A. Bazula, A.H. Lu, J.J. Nitz, and F. Schuth Micropor. Mesopor. Mater. 108 2008 266
S. Kundu, Y.M. Wang, W. Xia, and M. Muhler J. Phys. Chem. C 112 2008 16869
H. Darmstadt, C. Roy, S. Kaliaguine, S.J. Choi, and R. Ryoo Carbon 40 2002 2673
M.L. Toebes, E.M.P. van Heeswijk, J.H. Bitter, A.J. Dillen, and K.P. de Jong Carbon 42 2004 307
U. Dettlaff-Weglikowska, V. Skakalova, R. Graupner, S.H. Jhang, B.H. Kim, H.J. Lee, L. Ley, Y.W. Park, S. Berber, D. Tomanek, and S. Roth J. Am. Chem. Soc. 127 2005 5125
J.K. Wassei, K.C. Cha, V.C. Tung, Y. Yang, and R.B. Kaner J. Mater. Chem. 21 2011 3391
C. Laslau, W. Henderson, Z.D. Zujovic, and J. Travas-Sejdic Synth. Met. 160 2010 1173
S. Hermans, T. Khimyak, N. Feeder, S.J. Teat, and B.F.G. Johnson Dalton Trans. 4 2003 672 684
