Article (Scientific journals)
Secular Increase of the Vertical Column Abundance of Methane Derived From IR Solar Spectra Recorded at the Jungfraujoch Station
Zander, Rodolphe; Demoulin, Philippe; Ehhalt, D.H. et al.
1989In Journal of Geophysical Research, 94 (D8), p. 11029-11039
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Keywords :
methane; atmospheric composition; trace gases; infrared spectroscopy; trend
Abstract :
[en] Using all of the pertinent infrared solar spectra recorded at the Jungfraujoch Station, Switzerland, in 1951, 1975, and in 1984-1987, the increase of the vertical column abundance of methane, CH4, above that station has been reevaluated. The results are based on equivalent widths measurements of both the R0 and the R5 transitions of the 2v3 band of CH4 at 6015.66 and 6067.09 cm-1 and on the CH4-v3 band absorption characteristics between 2905.0 and 2908.8 cm-1. The data between 1984 and 1987 provide a full seasonal cycle. They demonstrate a significant annual variation in the column abundance of CH4 of +- 10% around the mean. They also show variability on shorter time scales. The mean cumulative rate of increase of the total vertical column abundance of CH4 above the Jungfraujoch is found to be (0.7 +- 0.1) %/yr between 1951 and 1986. Using a realistic CH4 concentration profile throughout the troposphere and the stratosphere, we deduce volume mixing ratios at the altitude of the Jungfraujoch, equal to 1.28 +- 0.08 and 1.64 +- 0.09 ppm, for 1951 and for 1985-1987, respectively.
Disciplines :
Earth sciences & physical geography
Author, co-author :
Zander, Rodolphe ;  Université de Liège - ULiège > Institut d'Astrophysique
Demoulin, Philippe ;  Université de Liège - ULiège > Institut d'Astrophysique
Ehhalt, D.H.;  Kernforschungsanlage Jülich, Jülich, Federal Republic of Germany > Institut für Atmosphärische Chemie
Schmidt, U.;  Kernforschungsanlage Jülich, Jülich, Federal Republic of Germany > Institut für Atmosphärische Chemie
Language :
English
Title :
Secular Increase of the Vertical Column Abundance of Methane Derived From IR Solar Spectra Recorded at the Jungfraujoch Station
Publication date :
20 August 1989
Journal title :
Journal of Geophysical Research
ISSN :
0148-0227
eISSN :
2156-2202
Publisher :
American Geophysical Union (AGU), Washington, United States - District of Columbia
Volume :
94
Issue :
D8
Pages :
11029-11039
Peer reviewed :
Peer Reviewed verified by ORBi
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