[en] Dispersions of inorganic fillers within polymers are commonly designated as polymer-based composites. The properties of these materials are isotropic or anisotropic, depending on the geometry of the filler particles and the effect of the processing conditions on their orientation. Fillers are used to improve some physicomechanical properties of the polymer, the material processability, or decrease the final cost. As a typical example, highly filled composites in which the filler concentration approaches the maximum packing fraction are known for their use in the shaping of ceramic articles.
Research center :
Center for Education and Research on Macromolecules (CERM)
Disciplines :
Chemistry Materials science & engineering
Author, co-author :
Dubois, Philippe ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Alexandre, Michaël ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Hindryckx, François; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Jérôme, Robert ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Language :
English
Title :
Polyolefin-based composites by polymerization-filling technique
Publication date :
1998
Journal title :
Journal of Macromolecular Science. Reviews in Macromolecular Chemistry and Physics
BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique F.R.S.-FNRS - Fonds de la Recherche Scientifique [BE] Dow Europe, Terneuzen, The Netherlands
A. A. Berlin, S. A. Volfson, N. S. Enikolopian, and S. S. Negmatov, Principles of Polymer Composites (G. Henrici-Olivé and S. Olivé, eds.), Springer-Verlag, Berlin, 1986, p. 1.
D. M. Kalyon, Chemtech, 25, 22 (1995) and the references cited therein.
F. R. Eirich, J. Appl. Polym. Sci. Appl. Polym. Symp., 39, 93 (1984).
D. G. Thomas, J. Colloid Sci, 20, 267 (1965).
E. G. Howard, R. D. Lipscomb, R. N. MacDonald, B. L. Glazar, C. W. Tullock, and J. W. Collette, Ind. Eng. Chem. Prod. Res. Dev., 20, 421 (1981).
F. M. Fowkes, J. Colloid Interface Sci., 28, 493 (1968).
V. Svehlova and E. Poloucek, Angew. Makromol. Chem., 153, 197 (1987).
V. Svehlova and E. Poloucek, Angew. Makromol. Chem., 174, 205 (1990).
C. B. Bucknall, Adv. Polym. Sci., 27, 121 (1978).
F. Fowkes, D. C. McCarthy, and J. A. Wolfe, ACS Polym. Prepr., 24, 228 (1983).
M. Y. Boluk and H. P. Schreiber, J. Appl. Polym. Sci., 40, 1783 (1990).
H. P. Shreiber and F. S. Germain, J. Adhesion Sci. Technol., 4, 319 (1990).
J. H. Plummer and C. F. Neumeyer, SPI Reinforced Plast. Div. Prepr., 28, 1 (1964).
S. Sterman and J. G. Marsden, Mod. Plast., 125 (July 1963).
D. G. Hawthorne and D. H. Solomon, J. Macromol. Sci. - Chem., A8, 659 (1974).
L. E. Nielsen, J. Appl. Polym. Sci, 10, 97 (1966).
S. J. Monte and P. F. Briuns, Mod. Plast., 68 (1974).
C. D. Han, T. Van den Weghe, P. Shete, and J. R. Haw, Polym. Eng. Sci., 21, 196 (1981).
M. Arroyo, M. Sanchez, and J. P. Vigo, Polym. Eng. Sci., 31, 245 (1991).
M. Arroyo, F. Perez, and J. P. Vigo, Polym. Compos., 7, 448 (1986).
M. Arroyo, F. Perez, and J. P. Vigo, J. Appl. Polym. Sci., 32, 5105 (1986).
R. Rothon, Particulate-Filled Polymer Composites (R. Rothon, ed.), Polym. Sci. Tech. Series, Longman Scientific and Technical, Harlow, 1995, Chap. 4.
K. Ghosh and S. N. Maiti, J. Appl. Polym. Sci., 60, 323 (1996).
Z. Liu and M. Gilbert, J. Appl. Polym. Sci., 59, 1087 (1996).
K. Mitsuishi, Angew. Makromol. Chem., 248, 73 (1997).
B. Pukanszky, E. Fekete, and F. Tudos, Makromol. Chem., Macromol. Symp., 28, 165 (1989).
T. Nakatsuka, Polym. Sci. Technol., 27, 51 (1985).
J. Jancar, A. Dianselmo, and A. T. Dibenedetto, Polym. Eng. Sci., 32, 1394 (1992).
J. Jancar and J. Kucera, Polym. Eng. Sci., 30, 714 (1990).
S. Datta, N. Dharmarajan, G. Versstrate, and L. Ban, Polym. Eng. Sci., 33, 721 (1993).
P. R. Hornsby and C. L. Watson, J. Mater. Sci., 30, 5347 (1995).
E. Morales, M. C. Ojeda, A. Linares, and J. L. Acosta, Polym. Eng. Sci., 32, 769 (1992).
E. P. Plueddmann, ACS Polym. Prepr., 24, 196 (1983).
H. Ishida, ACS Polym. Prepr., 24, 198 (1983).
L. A. Utracki and B. Fisa, Polym. Compos., 3, 193 (1982).
T. M. Malik, Polym. Bull., 26, 709 (1991).
G. A. McFarren, T. F. Sanderson, and F. G. Schappell, Polym. Eng. Sci., 17, 46 (1977).
J. D. Miller, H. Ishida, and F. H. J. Maurer, J. Mater. Sci., 24, 2555 (1989).
J. D. Miller, H. Ishida, and F. H. J. Maurer, Rheol. Acta, 27, 397 (1988).
Y. Wang, J. Lu, and G. Wang, J. Appl. Polym. Sci., 64, 1275 (1997).
M. Atsuta and D. T. Turner, Polym. Compos., 3, 83 (1982).
H. J. Bixler and G. J. Fallick, U.S. Pat. 3,471,439 (October 7, 1969).
R. Hausslein and G. J. Fallick, Appl. Polym. Symp., 11, 119 (1969).
G. J. Fallick, H. J. Bixler, R. A. Marsella, F. R. Gamer, and E. M. Fettes, Mod. Plast., 45, 143 (1968).
D. G. Hawthorne, J. H. Hodgkin, B. C. Loft, and D. H. Solomon, J. Macromol. Sci. - Chem., A8, 649 (1974).
J. H. Hodgkin and D. H. Solomon, J. Macromol. Sci. - Chem., A8, 621 (1974).
A. Galeski and R. Kalinski, in Polymer Blends: Processing, Morphology and Properties, Plenum, New York, 1980, p. 435.
B. M. Badran, A. Galeski, and M. Kryszewski, J. Appl. Polym. Sci., 27, 3669 (1982).
R. Kalinski, A. Galeski, and M. Kryszewski, J. Appl. Polym. Sci., 26, 4047 (1981).
A. Galeski, M. Kryszewski, and T. Kowalewski, Polym. Eng. Sci., 32, 1217 (1992).
M. L. Fridman, N. S. Enikolopyan, et al., Proc. IX Symp. Synthesis a. Props. Polym.-Filled Polyolefins, Chernogolovka (Moscow District), 113 (1982); see Chap. 1, p. 34 in Ref. 1.
Y. I. Yermakov, V. A. Zakharov, and G. A. Nesterov, Catalytic Polymerization of Olefins. In Studies in Surf, and Cat., Vol. 25 (T. Kelt and S. Kazuo, eds.), Elsevier, Amsterdam, 1986, p. 181.
R. L. Banks and C. F. Cook, Catalyst Technology: Discovery to Commercialisation, Disproportionation of Propylene in Modern Aspect of Catalysis, Nauka, Novosibirsk, 1978, p. 149.
D. C. Bailey and S. H. Langer, Chem. Rev., 81, 105 (1981).
R. D. Lipscomb, U.S. Pat. 3,950,303 (1976).
E. G. Howard, U.S. Pat. 4,104,243 (1978).
E. G. Howard, U.S. Pat. 4,097,447 (1978).
N. S. Enikolopian, USSR Pat. 763,379 (1976); U.S. Pat. 4,241,112 (1980).
L. A. Kostandov, USSR Pat. 787,394 (1976); U.S. Pat. 4,241,138 (1980).
Idemitsu Kosan, Jap. Pat. 60,106,810 (1983).
E. G. Howard, U.S. Pat. 4,151,126 (1979).
S. Casenave, A. Aït-Kadi, and B. Riedl, Can. J. Chem. Eng., 74, 308 (1996).
Imperial Chemical Industries, Br. Pat., 1,420,315 (1975).
H. Hayashi, K. Matono, S. Asahi, M. Uoi, E.P. Pat. 0 142 143 B1 (1984).
F. S. D'yachkovskii, L. A. Novokshonova, and V. I. Tsvetkova, Intl. J. Polym. Mater., 15, 277 (1991).
J. A. Orsino, Ger. Pat. 1,494,876 (1966).
Q. Wang, S. Kaliaguine, and A. Aït-Kadi, J. Appl. Polym. Sci., 44, 1107 (1992).
Kruse Uno, U.S. Pat. 3,503,785 (1970).
Q. Wang, A. Aït-Kadi, and S. Kaliaguine, J. Appl. Polym. Sci., 45, 1023 (1992).
J. M. Patterson and S. Tsai, Reinforcement. In Encycl. Polym. Sci. Eng., (J. I. Kroschwitz, ed.), 2nd ed., Vol. 14, Wiley Interscience, New York, 1988, p. 391.
A. K. Dhingra and H. G. Lauterbach, Fibers, Engineering. In Encycl. Polym. Sci. Eng., (J. I. Kroschwitz, ed.), 2nd ed., Vol. 6, Wiley Interscience, New York, 1986, p. 765.
H. S. Katz and J. V. Milewski, Handbook of Fillers and Reinforcements for Plastics, Van Nostrand, New York, 1978.
J. A. Orsino, D. F. Herman, and J. Brancato, U.S. Pat. 3,121,698 (1964).
D. F. Herman, U. Kruse, and J. J. Brancato, J. Polym. Sci., 11, 75 (1965).
F. S. D'yachkovskii and L. A. Novokshonova, Ref. 94 in our Ref. 1.
J. P. Candlin and H. Thomas, Adv. Chem. Ser., 132, 212 (1974).
V. A. Zakharov, V. K. Dudchenko, E. A. Paukshtis, L. G. Karakchiev, and Y. I. Yermakov, J. Mol. Catal., 2, 421 (1977).
B. Diedrich, ACS Polym. Prepr., 16, 316 (1975).
A. Munoz-Escalona, ACS Polym. Prepr., 24, 112 (1983).
N. V. Semikolenova, G. A. Nesterov, V. A. Zakcharov, G. N. Krjukova, and V. P. Ivanov, Makromol. Chem., 189, 1739 (1988).
W. Schoppel and K. H. Reichert, Makromol. Chem. Rapid Commun., 3, 483 (1982).
D. Damyanov, M. Velikova, and L. Petkov, Eur. Polym. J., 15, 233 (1979).
S. Lin, H. Wang, Q. Zhang, Z. Lu, and Y. Lu, Catalytic Polymerization of Olefins. In Studies in Surf. and Cat., Vol. 25 (T. Keit and S. Kazuo, eds.), Elsevier, Amsterdam, 1986, p. 91.
G. R. Marchand, R. Fuentes, and W. M. Coleman, U.S. Pat. 4,910,272 (1990).
(a) F. Hindryckx, Ph. Dubois, Ph. Teyssie, R. Jerome, and M. Garcia Marti, J. Appl. Polym. Sci., 64, 423 (1997);
(b) F. Hindryckx, Ph. Dubois, Ph. Teyssie, R. Jerome, and M. Garcia Marti, J. Appl. Polym. Sci., 64, 439 (1997).
G. A. Nesterov, V. A. Zakharov, V. V. Volkov, and K. G. Myakishev, J. Mol. Catal., 36, 253 (1986).
Y. I. Yermakov, J. Mol. Catal., 21, 35 (1983).
L. Minkova, M. Velikova, and D. Damyanov, Eur. Polym. J., 26, 1161 (1990).
D. Damyanov, I. Ivanov, and M. Velikova, Eur. Polym. J., 24, 657 (1988).
M. Mihailov, L. Minkova, and E. Nedkov, Makromol. Chem., 180, 2351 (1979).
D. Damyanov, I. Ivanov, and M. Velikova, Eur. Polym. J., 24, 657 (1988).
G. A. Nesterov, V. A. Zakharov, E. A. Paukshtis, E. N. Yurchenko, and Y. I. Ermakov, Kinet. Catal. [Eng. transl.], 20, 349 (1979).
C. W. Tullock, F. N. Tebbe, R. Mulhaupt, D. W. Ovenall, R. A. Setterquist, and S. D. Ittel, J. Polym. Sci., Part A; Polym. Chem., 27, 3063 (1989).
C. W. Tullock, R. Mulhaupt, and S. D. Ittel, Makromol. Chem. Rapid Commun., 10, 19 (1989).
D. Martineau, P. Dumas, and P. Sigwalt, Makromol. Chem., 184, 1389 (1983).
J. Ulbricht and J. Giesemann, Makromol. Chem., Macromol. Symp., 12, 53 (1987).
A. Akar, N. C. Billingham, and P. D. Calvert, Polymer, 24, 889 (1983).
E. G. Howard, U.S. Pat. 4,187,210 (1980).
N. V. Semikolenova, G. A. Nesterov, G. N. Kryukova, V. P. Ivanov, and V. A. Zakharov, Polym. Sci. USSR, 27, 2248 (1985).
N. V. Semikolenova, G. A. Nesterov, and V. A. Zakharov. Polym. Sci. USSR, 28, 186 (1986).
D. Damyanov and M. Velikova, Eur. Polym. J., 15, 1075 (1979).
I. N. Meshkova, T. M. Ushkova, I. L. Dubnikova, Y. M. Kazakov, Y. E. Shashkova, N. M. Rudneva, N. K. Portnaya, G. N. Kornienko, V. I. Sergeyev, A. I. Petrosyan, A. I. Makhin'ko, and F. S. D'yachkovskii, Polym. Sci. USSR, 28, 724 (1986).
D. G. H. Ballard, J. Polym. Sci. Polym. Chem. Ed., 13, 2191 (1975).
E. G. Howard, U.S. Pat. 4,187,210 (1980).
N. N. Vlasova, V. I. Sergeyev, P. Y. Matkovskii, N. S. Yenikolopyan, A. T. Papoyan, B. Y. Vostorgov, L. N. Grigorov, S. A. Bukanova, L. O. Bunina, N. S. Kogarko, L. A. Tkachenko, and V. V. Smirnov, Polym. Sci. USSR, 27, 2552 (1985).
H. Kothandaraman and M. S. Devi, J. Polym. Sci., Part A; Polym. Chem., 32, 1283 (1994).
N. S. Enikolopyan, N. N. Vlasova, A. T. Papoyan, P. E. Matkovskii, V. A. Shtarkin, M. P. Gerasina, V. I. Sergeev, and L. O. Bunina, Doklady Chem. [Eng. transl. of Doklady Akad. Nauk SSSR], 280, 13 (1985).
A. Munoz-Escalona, J. G. Hernandez, and J. A. Gallardo, J. Appl. Polym. Sci., 29, 1187 (1984).
T. Garoff, Techniques and Measurement in Heterogeneous and Homogeneous Catalysis, lecture given at the University of Liverpool, 6-10 September (1993).
D. Damyanov, M. Velikova, I. Ivanov, and L. Vlaev, J. Non-Cryst. Sol., 105, 107 (1988).
E. G. Howard, B. L. Glazar, and J. W. Collette, Ind. Eng. Chem. Prod. Res. Dev., 20, 429 (1981).
D. G. H. Ballard, E. Jones, R. J. Wyatt, R. T. Murray, and P. A. Robinson, Polymer, 15, 169 (1974).
H. E. Evans and W. H. Weinberg, J. Am. Chem. Soc., 102, 2548 (1980).
N. S. Enikolopyan, Filled Polymer I, Science and Technology, Adv. Polym. Sci., 96, 1990.
B. L. Glazar, E. G. Howard, and J. W. Collette, J. Fire Flammability, 9, 430 (1978).
R. C. Ferguson, H. J. Stoklosa, W. W. Yau, and H. H. Hoehn, J. Appl. Polym. Sci., Appl. Polym. Symp., 34, 119 (1978).
H. L. Chang and A. T. Hu, Makromol. Chem., 192 2059 (1991).
V. Doláková and F. Hudecek, J. Macromol. Sci. - Phys., B15, 337 (1978).
C. G. Ek, Rheol. Acta., 27, 279 (1988).
J. Gähde, V. Müller, Y. V. Lebedev, and Y. S. Lipatov, Polym. Sci. USSR, 19, 1446 (1977).
V. P. Chacko, F. E. Karasz, R. J. Farris, and E. L. Thomas, J. Polym. Sci. Polym. Phys. Ed., 20, 2177 (1982).
L. Minkova and P. L. Magagnini, Polym. Deg. and Stab., 42, 107 (1993).
L. Minkova, M. Velikova, and D. Damyanov, Acta Polymerica, 42, 8 (1991).
E. G. Howard, U.S. Pat. 5,352,732 (December 1992).
E. G. Howard, B. L. Glazaer, and J. W. Collette, High Perf. Plast. Nat. Tech. Conf. - Soc. Plast. Eng. (Prepr.) - Cleveland, Fasc. Oct. 5/7, 36 (1976).
H. S. Göktürk, T. S. Fiske, and D. M. Kalyon, J. Appl. Polym. Sci., 50, 1891 (1993).
I. H. Tavman, J. Appl. Polym. Sci., 62, 2161 (1996).
L. A. Novokshonova and I. N. Meshkova, Polym. Sci. USSR, 36, 517 (1994).
N. V. Galashina, Polym. Sci. USSR, 36, 526 (1994).
W. Kaminsky, J. Dutschke, H. Meadler, M. Miri, and M. Schlobohm, DE Pat. 3,240,382 (May 1984).
W. Kaminsky and H. Zielonka, Polym. Adv. Technol., 4, 415 (1993).
W. Kaminsky, Macromol. Chem. Phys., 197, 3907 (1996).
M. Alexandre, F. Hindryckx, Ph. Dubois, R. Jérôme, and M. Garcia Marti, PCT pat. (pending).
Ph. Dubois, M. Alexandre, R. Jérôme, and M. Garcia Marti, communication presented at EuroFillers'97, Manchester, United Kingdom, September 8-11, 1997.
M. Alexandre, E. Martin, Ph. Dubois, R. Jérôme, and M. Garcia Marti, communication presented at IPCM'97, Eger, Hungary, September 1-3, 1997.
