[en] The micellization on surfaces of two series of quasi-diblock copoly(2-oxazoline)s consisting of 2-phenyl-2-oxazoline (PhOx) segments linked to either 2-methyl-2-oxazoline (MeOx) or 2-ethyl-2-oxazoline (EtOx) segments is investigated in detail. Those micelles are not preexisting in the initial ethanol solution but are formed during the spin-coating process by the evaporation of the solvent inducing the precipitation of the less soluble PhOx segments. The morphology and size of the surface micelles vary according to the fraction of PhOx in the copolymers. Moreover, it is demonstrated that the chemical nature of the more soluble MeOx or EtOx segments also has an influence on the morphology of the resulting surface micelles.
Disciplines :
Chemistry
Author, co-author :
Fustin, Charles-André; Université Catholique de Louvain - UCL > Chimie > Unité de Chimie des Matériaux Inorganiques et Organiques (CMAT), and Research Center in Micro- and Nanoscopic Materials and Electronic Devices (CeRMiN)
Lefèvre, Nathalie ; Université Catholique de Louvain - UCL > Chimie > Unité de Chimie des Matériaux Inorganiques et Organiques (CMAT), and Research Center in Micro- and Nanoscopic Materials and Electronic Devices (CeRMiN)
Hoogenboom, Richard; Eindhoven University of Technology > Laboratory of Macromolecular Chemistry and Nanoscience
Schubert, Ulrich S.; Eindhoven University of Technology > Laboratory of Macromolecular Chemistry and Nanoscience
Gohy, Jean-François; Université Catholique de Louvain - UCL > Chimie > Unité de Chimie des Matériaux Inorganiques et Organiques (CMAT), and Research Center in Micro- and Nanoscopic Materials and Electronic Devices (CeRMiN)
Language :
English
Title :
Micellization of Poly(2-oxazoline)-Based Quasi-Diblock Copolymers on Surfaces
scite shows how a scientific paper has been cited by providing the context of the citation, a classification describing whether it supports, mentions, or contrasts the cited claim, and a label indicating in which section the citation was made.
Bibliography
I. W. Hamley, "The Physics of Block Copolymers", Oxford University Press, Oxford 1998.
J. Zhao, S. Tian, Q. Wang, X. Liu, S. Jianga, X. Ji, L. An, B. Jiang, Eur. Phys. J. E 2005, 16, 49.
J. P. Spatz, M. Möller, M. Noeske, R. J. Behm, M. Pietralla, Macromolecules 1997, 30, 3874.
I. I. Potemkin, E. Y. Kramarenko, A. R. Khokhlov, R. G. Winkler, P. Reineker, P. Eibeck, J. P. Spatz, M. Möller, Langmuir 1999, 15, 7290.
K. Albrecht, A. Mourran, M. Möller, Adv. Polym. Sci. 2006, 200, 57.
[6a] G. B. Webber, E. J. Wanless, S. P. Armes, Y. Tang, Y. Li, S. Biggs, Adv. Mater. 2004, 16, 1794;
[6b] J. Hahn, S. E. Webber, Langmuir 2004, 20, 4211.
J. P. Spatz, S. Sheiko, M. Möller, Macromolecules 1996, 29, 3220.
Z. Li, Y. Liu, M. H. Rafailovich, J. Sokolov, K. Khougaz, A. Eisenberg, R. B. Lennox, G. Krausch, J. Am. Chem. Soc. 1996, 118, 10892.
J. Zhu, R. B. Lennox, A. Eisenberg, J. Chem. Phys. 1962, 96, 4727.
C. A. Fustin, H. Huang, R. Hoogenboom, F. Wiesbrock, A. M. Jonas, U. S. Schubert, J. F. Gohy, Soft Matter 2007, 3, 79.
T. G. Bassiri, A. Levy, M. Litt, Polym. Lett. 1967, 5, 871.
R. Hoogenboom, M. W. M. Fijten, H. M. L. Thijs, B. M. Van Lankvelt, U. S. Schubert, Des. Monomers Polym. 2005, 8, 659.
R. Hoogenboom, F. Wiesbrock, H. Huang, M. A. M. Leenen, H. M. L. Thijs, S. F. G. M. van Nispen, M. van der Loop, C. A. Fustin, A. M. Jonas, J. F. Gohy, U. S. Schubert, Macromolecules 2006, 39, 4719.
R. Hoogenboom, F. Wiesbrock, M. A. M. Leenen, H. M. L. Thijs, H. Huang, C. A. Fustin, P. Guillet, J. F. Gohy, U. S. Schubert, Macromolecules 2007, 40, 2837.
F. Wiesbrock, R. Hoogenboom, M. A. M. Leenen, S. F. G. M. van Nispen, M. van der Loop, C. H. Abeln, A. M. J. van den Berg, U. S. Schubert, Macromolecules 2005, 38, 7957.
R. Hoogenboom, M. W. M. Fijten, R. M. Paulus, H. M. L. Thijs, S. Hoeppener, G. Kickelbick, U. S. Schubert, Polymer 2006, 47, 75.
M. H. Litt, J. Herz, E. Turi, "Block Copolymers", S. L. Aggarwal, Ed., Plenum Press, New York 1970, pp. 313-319.
S. Kobayashi, T. Igarashi, Y. Moriuchi, T. Saegusa, Macromolecules 1986, 19, 535.
R. H. Jin, Adv. Mater. 2002, 14, 889.
R. Hoogenboom, H. M. L. Thijs, M. W. M. Fijten, B. M. van Lankvelt, U. S. Schubert, J. Polym. Sci., Part A: Polym. Chem. 2007, 45, 416.
F. Wiesbrock, R. Hoogenboom, M. A. M. Leenen, M. A. R. Meier, U. S. Schubert, Macromolecules 2005, 38, 5025.
S. Hoeppener, F. Wiesbrock, R. Hoogenboom, H. M. L. Thijs, U. S. Schubert, Macromol. Rapid Commun. 2006, 27, 405.
Similar publications
Sorry the service is unavailable at the moment. Please try again later.
This website uses cookies to improve user experience. Read more
Save & Close
Accept all
Decline all
Show detailsHide details
Cookie declaration
About cookies
Strictly necessary
Performance
Strictly necessary cookies allow core website functionality such as user login and account management. The website cannot be used properly without strictly necessary cookies.
This cookie is used by Cookie-Script.com service to remember visitor cookie consent preferences. It is necessary for Cookie-Script.com cookie banner to work properly.
Performance cookies are used to see how visitors use the website, eg. analytics cookies. Those cookies cannot be used to directly identify a certain visitor.
Used to store the attribution information, the referrer initially used to visit the website
Cookies are small text files that are placed on your computer by websites that you visit. Websites use cookies to help users navigate efficiently and perform certain functions. Cookies that are required for the website to operate properly are allowed to be set without your permission. All other cookies need to be approved before they can be set in the browser.
You can change your consent to cookie usage at any time on our Privacy Policy page.
