Evaluation of ruthenium-based complexes for the controlled radical polymerization of vinyl monomers

Simal, François; Jan, Dominique; Delaude, Lionel; Demonceau, Albert; Spirlet, Marie-Rose; Noels, Alfred

doi:10.1139/v00-206

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Evaluation of ruthenium-based complexes for the controlled radical polymerization of vinyl monomers

Simal, François; Jan, Dominique; Delaude, Lionel et al.

2001 • In Canadian Journal of Chemistry, 79 (5-6), p. 529-535

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https://hdl.handle.net/2268/15460

DOI
10.1139/v00-206

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Keywords :

ruthenium; carbene; chelate complex; homogeneous catalysis; atom transfer radical polymerization

Abstract :

[en] New complexes of the type RuCl2(p-cymene)L where the ligand L is either a phosphine or a stable triazolinylidene carbene have been tested and compared to the Grubbs' benzylidene complex RuCl2(=CHPh)(PCy3)(2) as catalyst precursors for the controlled atom transfer radical polymerization (ATRP) of methyl methacrylate and of various para-substituted styrenes. Kinetic data and Hammett rho constants are reported, as well as the X-ray structure of the ortho-metallated triazolinylidene-ruthenium(II) complex RuCl(p-cymene)[1,2-phenylene[3,4-diphenyl-1H-1,2,4-triazol-1-yl-5(4H)-yl idene]].

Disciplines :

Chemistry

Author, co-author :

Simal, François

Jan, Dominique

Delaude, Lionel ; Université de Liège - ULiège > Département de chimie (sciences) > Chimie macromoléculaire et catalyse organique

Demonceau, Albert ; Université de Liège - ULiège > Département de chimie (sciences) > Chimie macromoléculaire et catalyse organique

Spirlet, Marie-Rose ; Université de Liège - ULiège > Département de physique > Département de physique

Noels, Alfred ; Université de Liège - ULiège > Services généraux (Faculté des sciences) > Relations académiques et scientifiques (Sciences)

Language :

English

Title :

Evaluation of ruthenium-based complexes for the controlled radical polymerization of vinyl monomers

Publication date :

2001

Journal title :

Canadian Journal of Chemistry

ISSN :

0008-4042

eISSN :

1480-3291

Publisher :

NRC Research Press, Ottawa, Canada

Volume :

Issue :

5-6

Pages :

529-535

Peer reviewed :

Peer Reviewed verified by ORBi

Available on ORBi :

since 26 June 2009

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