N-heterocyclic carbene ruthenium complexes: Synthesis and catalytic properties

Dragutan, Ileana; Dragutan, Valerian; Delaude, Lionel; Demonceau, Albert; Noels, Alfred

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N-heterocyclic carbene ruthenium complexes: Synthesis and catalytic properties

Dragutan, Ileana; Dragutan, Valerian; Delaude, Lionel et al.

2007 • In Revue Roumaine de Chimie, 52 (11), p. 1013-1025

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Keywords :

ruthenium complexes; N-heterocyclic carbenes; homogeneous precatalysts; olefin metathesis; cyclopropanation

Abstract :

[en] Synthesis of imidazol(in)-2-ylidene ruthenium complexes relevant for metathesis and related catalytic processes is described. As an attractive alternative of importance for practical applications, the in situ generation of new NHC ruthenium precatalysts, starting from the easily accessible imidazolium and imidazolinium salts, ruthenium dimer [RuCl2(p-cymene)](2) and a base, is reported in detail. The new NHC family of ruthenium complexes offers great promise as metathesis precatalysts enjoying a wide application profile in organic and polymer synthesis.

Disciplines :

Chemistry

Author, co-author :

Dragutan, Ileana

Dragutan, Valerian

Delaude, Lionel ; Université de Liège - ULiège > Département de chimie (sciences) > Chimie macromoléculaire et catalyse organique

Demonceau, Albert ; Université de Liège - ULiège > Département de chimie (sciences) > Chimie macromoléculaire et catalyse organique

Noels, Alfred ; Université de Liège - ULiège > Services généraux (Faculté des sciences) > Relations académiques et scientifiques (Sciences)

Language :

English

Title :

N-heterocyclic carbene ruthenium complexes: Synthesis and catalytic properties

Publication date :

2007

Journal title :

Revue Roumaine de Chimie

ISSN :

0035-3930

Publisher :

Editura Acad Romane, Bucuresti, Romania

Volume :

Issue :

Pages :

1013-1025

Peer reviewed :

Peer reviewed

Available on ORBi :

since 26 June 2009

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