Article (Scientific journals)
N-heterocyclic carbene ruthenium complexes: Synthesis and catalytic properties
Dragutan, Ileana; Dragutan, Valerian; Delaude, Lionel et al.
2007In Revue Roumaine de Chimie, 52 (11), p. 1013-1025
Peer reviewed
 

Files


Full Text
A040.pdf
Publisher postprint (281.88 kB)
Download

All documents in ORBi are protected by a user license.

Send to



Details



Keywords :
ruthenium complexes; N-heterocyclic carbenes; homogeneous precatalysts; olefin metathesis; cyclopropanation
Abstract :
[en] Synthesis of imidazol(in)-2-ylidene ruthenium complexes relevant for metathesis and related catalytic processes is described. As an attractive alternative of importance for practical applications, the in situ generation of new NHC ruthenium precatalysts, starting from the easily accessible imidazolium and imidazolinium salts, ruthenium dimer [RuCl2(p-cymene)](2) and a base, is reported in detail. The new NHC family of ruthenium complexes offers great promise as metathesis precatalysts enjoying a wide application profile in organic and polymer synthesis.
Disciplines :
Chemistry
Author, co-author :
Dragutan, Ileana
Dragutan, Valerian
Delaude, Lionel  ;  Université de Liège - ULiège > Département de chimie (sciences) > Chimie macromoléculaire et catalyse organique
Demonceau, Albert ;  Université de Liège - ULiège > Département de chimie (sciences) > Chimie macromoléculaire et catalyse organique
Noels, Alfred ;  Université de Liège - ULiège > Services généraux (Faculté des sciences) > Relations académiques et scientifiques (Sciences)
Language :
English
Title :
N-heterocyclic carbene ruthenium complexes: Synthesis and catalytic properties
Publication date :
2007
Journal title :
Revue Roumaine de Chimie
ISSN :
0035-3930
Publisher :
Editura Acad Romane, Bucuresti, Romania
Volume :
52
Issue :
11
Pages :
1013-1025
Peer reviewed :
Peer reviewed
Available on ORBi :
since 26 June 2009

Statistics


Number of views
142 (13 by ULiège)
Number of downloads
3 (1 by ULiège)

Scopus citations®
 
21
Scopus citations®
without self-citations
7

Bibliography


Similar publications



Contact ORBi