Article (Scientific journals)
Anionic block copolymerization of 4-vinylpyridine and tert-butyl methacrylate at "elevated" temperature : influence of various additives on the molecular parameters
Creutz, Serge; Teyssié, Philippe; Jérôme, Robert
1997In Macromolecules, 30 (19), p. 5596-5601
Peer Reviewed verified by ORBi
 

Files


Full Text
Creutz S 1997 Macromolecules 5596.pdf
Publisher postprint (250.56 kB)
Request a copy

All documents in ORBi are protected by a user license.

Send to



Details



Keywords :
anionic polymerization; block copolymer
Abstract :
[en] The living anionic polymerization of 4-vinylpyridine (4VP) in 9/1 pyridine/THF at 0 °C has been reported lately (Creutz, S.; Teyssié, Ph.; Jérôme, R. Macromolecules 1997, 30, 1). The success of its block copolymerization with tert-butyl methacrylate (tBMA) has been shown to be dependent on the addition mode, highlighting the difference in reactivity between the two monomers. Moreover, the (co)solvent also strongly influences the fate of that copolymerization. Thus, the impact of various (co)solvents and additives has been investigated more thoroughly, revealing the interesting possibility of modifying the apparent relative reactivities of these two monomers.
Research center :
Center for Education and Research on Macromolecules (CERM)
Disciplines :
Materials science & engineering
Chemistry
Author, co-author :
Creutz, Serge;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Teyssié, Philippe ;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Jérôme, Robert ;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Language :
English
Title :
Anionic block copolymerization of 4-vinylpyridine and tert-butyl methacrylate at "elevated" temperature : influence of various additives on the molecular parameters
Publication date :
22 September 1997
Journal title :
Macromolecules
ISSN :
0024-9297
eISSN :
1520-5835
Publisher :
Amer Chemical Soc, Washington, United States - Washington
Volume :
30
Issue :
19
Pages :
5596-5601
Peer reviewed :
Peer Reviewed verified by ORBi
Funders :
BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique
Akzo Nobel [NL]
Available on ORBi :
since 25 June 2009

Statistics


Number of views
56 (1 by ULiège)
Number of downloads
0 (0 by ULiège)

Scopus citations®
 
16
Scopus citations®
without self-citations
14
OpenCitations
 
15

Bibliography


Similar publications



Contact ORBi