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Living anionic homo- and block copolymerization of 2-(tert-butylamino) ethyl methacrylate
Creutz, Serge; Teyssié, Philippe; Jérôme, Robert
1997In Journal of Polymer Science. Part A, Polymer Chemistry, 35 (10), p. 2035-2040
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Keywords :
anionic polymerization; (meth)acrylate
Abstract :
[en] Anionic polymerization of 2-(tert-butylamino)ethyl methacrylate (tBAEMA), which bears an unprotected secondary amine moiety, has been investigated in THF at -78°C. The presence of lithium chloride has been shown to be desirable to afford narrow molecular weight distribution as well as a good agreement between theoretical and observed molecular weight. The living character of the polymerization has also been demonstrated, and the synthesis of block copolymers carried out successfully. They have been analyzed by SEC by adding a mixture of secondary and tertiary amines to the eluent (THF) so as to avoid any polymer adsorption during elution. © 1997 John Wiley
Research center :
Center for Education and Research on Macromolecules (CERM)
Disciplines :
Materials science & engineering
Chemistry
Author, co-author :
Creutz, Serge;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Teyssié, Philippe ;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Jérôme, Robert ;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Language :
English
Title :
Living anionic homo- and block copolymerization of 2-(tert-butylamino) ethyl methacrylate
Publication date :
30 July 1997
Journal title :
Journal of Polymer Science. Part A, Polymer Chemistry
ISSN :
0887-624X
eISSN :
1099-0518
Publisher :
John Wiley & Sons, Hoboken, United States - New Jersey
Volume :
35
Issue :
10
Pages :
2035-2040
Peer reviewed :
Peer Reviewed verified by ORBi
Funders :
Akzo Nobel [NL]
BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique
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