Living Anionic Homopolymerization and Block Copolymerization of 4-Vinylpyridine at "Elevated" Temperature and Its Characterization by Size Exclusion Chromatography

Creutz, Serge; Teyssié, Philippe; Jérôme, Robert

doi:10.1021/ma9610931

Article (Scientific journals)

Living Anionic Homopolymerization and Block Copolymerization of 4-Vinylpyridine at "Elevated" Temperature and Its Characterization by Size Exclusion Chromatography

Creutz, Serge; Teyssié, Philippe; Jérôme, Robert

1997 • In Macromolecules, 30 (1), p. 1-5

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https://hdl.handle.net/2268/15180

DOI
10.1021/ma9610931

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Keywords :

anionic polymerization; vinylpyridine

Abstract :

[en] The anionic polymerization of 4-vinylpyridine (4VP) has been investigated in 9/1 pyridine/THF at 0 °C. After characterization of the living character of 4VP polymerization, its copolymerization with tert-butyl methacrylate (tBMA) has been carried out also successfully. Their relative reactivity ratios have been determined. Solvent composition as well as temperature have been varied in order to evaluate their influence on the final molecular characteristics of the polymers. Finally, a new SEC methodology in 8/1/1 N,N-dimethylformamide/triethylamine/pyridine has been developed.

Research Center/Unit :

Center for Education and Research on Macromolecules (CERM)

Disciplines :

Materials science & engineering
Chemistry

Author, co-author :

Creutz, Serge; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Teyssié, Philippe ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Jérôme, Robert ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)

Language :

English

Title :

Living Anionic Homopolymerization and Block Copolymerization of 4-Vinylpyridine at "Elevated" Temperature and Its Characterization by Size Exclusion Chromatography

Publication date :

13 January 1997

Journal title :

Macromolecules

ISSN :

0024-9297

eISSN :

1520-5835

Publisher :

Amer Chemical Soc, Washington, United States - Washington

Volume :

Issue :

Pages :

1-5

Peer reviewed :

Peer Reviewed verified by ORBi

Additional URL :

http://pubs.acs.org/doi/pdf/10.1021/ma9610931

Funders :

BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique
Akzo Nobel

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since 24 June 2009

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