[en] As an illustration of the frantic development of (meth)acrylic esters anionic polymerization during the last decade, three significant breakthroughs will be presented and analyzed: - extension of the LAP (ligated anionic polymerization) concept to the practical synthesis of both high iso- or syndio high MW PMMA; - the production of "perfect" hydrocarbon gels from tailored PMMA-polybutadiene-PMMA triblock copolymers; - the use of reactivity "boosters" allowing to climb back up the nucleophilic reactivity scale, i.e. initiating styrene, dienes and (meth)acrylates polymerization with alcoholates and silanolates.
Research Center/Unit :
Center for Education and Research on Macromolecules (CERM)
Disciplines :
Chemistry Materials science & engineering
Author, co-author :
Teyssié, Philippe ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Baran, Janusz; Institute of Fundamental Chemistry, Technical University of Szczecin, Poland
Dubois, Philippe ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Jérôme, Robert ; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Wang, J. S.; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Yu, J. M.; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Yu, Y.; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Zundel, Thomas; Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Language :
English
Title :
Living anionic polymerization of (meth)acrylic esters : new mechanistic concepts and resulting materials
Publication date :
July 1998
Journal title :
Macromolecular Symposia
ISSN :
1022-1360
eISSN :
1521-3900
Publisher :
Wiley-V C H Verlag Gmbh, Weinheim, Germany
Volume :
132
Pages :
303-307
Peer reviewed :
Peer Reviewed verified by ORBi
Funders :
Elf Atochem Raychem Shell BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique
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