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Electrochemical synthesis of polypyrrole nanowires
Jérôme, Christine; Jérôme, Robert
1998In Angewandte Chemie International Edition, 37 (18), p. 2488-2490
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Keywords :
electropolymerization; conjugated polymer; nanostructured material
Abstract :
[en] Through a hole in a poly(ethyl acrylate) (PEA) layer that is electrochemically grafted to the surface of a vitreous carbon electrode-that is the route that must be taken by a growing polypyrrole nanowire in the electropolymerization of pyrrole. Chain growth is controlled by diffusion of the monomer through the DMF-swollen PEA layer, which acts as a template for the formation of nanowires (shown in the picture) with diameters of 400-1000 nm and lengths of up to 300 m.
Research center :
Center for Education and Research on Macromolecules (CERM)
Disciplines :
Materials science & engineering
Chemistry
Author, co-author :
Jérôme, Christine  ;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Jérôme, Robert ;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Language :
English
Title :
Electrochemical synthesis of polypyrrole nanowires
Publication date :
02 October 1998
Journal title :
Angewandte Chemie International Edition
ISSN :
1433-7851
eISSN :
1521-3773
Publisher :
Wiley-V C H Verlag Gmbh, Weinheim, Germany
Volume :
37
Issue :
18
Pages :
2488-2490
Peer reviewed :
Peer Reviewed verified by ORBi
Funders :
The "Fonds der Chemischen Industrie"
The "Bayerische Forschungsstiftung" (Bayerischer Forschungsverbund Katalyse, FORKAT)
DFG - Deutsche Forschungsgemeinschaft [DE]
Degussa AG
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