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Dependence of phase morphology and mechanical properties of PS/SBR/PE ternary blends on composition: transition from core-shell to triple-phase continuity structures
Luzinov, Igor; Pagnoulle, Christophe; Jérôme, Robert
2000In Polymer, 41 (9), p. 3381-3389
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Keywords :
self-assembly in bulk; nanostructured material; polymer blend
Abstract :
[en] The weight ratio of PE and PS in ternary PS/SBR/PE blends has been changed at constant SBR content (25 wt%). When the matrix is either PE or PS, the dispersed phase has a core-shell structure with SBR forming the shell. The size of the core expectedly increases with the content of the core-forming polymer. In some composition range, the three phases are simultaneously continuous, SBR being localized in between the co-continuous PE and PS phases. The ultimate mechanical properties of the ternary blends containing SBR/PE and SBR/PS core-shell dispersed phases are close to the properties of the PS/SBR and PE/SBR binary blends, respectively. Some synergism in the elongation at break of the ternary blends is observed when core-shell SBR/PS phases are dispersed in PE matrix.
Research Center/Unit :
Center for Education and Research on Macromolecules (CERM)
Disciplines :
Chemistry
Materials science & engineering
Author, co-author :
Luzinov, Igor;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Pagnoulle, Christophe;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Jérôme, Robert ;  Université de Liège - ULiège > Department of Chemistry > Center for Education and Research on Macromolecules (CERM)
Language :
English
Title :
Dependence of phase morphology and mechanical properties of PS/SBR/PE ternary blends on composition: transition from core-shell to triple-phase continuity structures
Publication date :
April 2000
Journal title :
Polymer
ISSN :
0032-3861
eISSN :
1873-2291
Publisher :
Elsevier Sci Ltd, Oxford, United Kingdom
Volume :
41
Issue :
9
Pages :
3381-3389
Peer reviewed :
Peer Reviewed verified by ORBi
Funders :
BELSPO - SPP Politique scientifique - Service Public Fédéral de Programmation Politique scientifique
Commentary :
The authors acknowledge Polymer (Elsevier) for allowing them to archive this paper.
Available on ORBi :
since 23 April 2009

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