Homobimetallic Ethylene− and Vinylidene−Ruthenium Complexes for ATRP

Borguet, Yannick; Delaude, Lionel; Demonceau, Albert

doi:10.1021/bk-2012-1100.ch008

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Homobimetallic Ethylene− and Vinylidene−Ruthenium Complexes for ATRP

Borguet, Yannick; Delaude, Lionel; Demonceau, Albert

2012 • In Matyjaszewski, Krysztof; Sumerlin, Brent S.; Tsarevsky, Nicolay V. (Eds.) Progress in Controlled Radical Polymerization: Mechanisms and Techniques

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https://hdl.handle.net/2268/115190

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10.1021/bk-2012-1100.ch008

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Abstract :

[en] The catalytic activity of a series of homobimetallic ruthenium complexes of the type [(p-cymene)Ru(μ-Cl)3RuCl(L)(L′)] [L = C2H4 or a vinylidene ligand (=C=CHR); L′ = PPh3, PCy3, or an N-heterocyclic carbene ligand] was determined by investigating the atom transfer radical polymerisation of methyl methacrylate. The results clearly demonstrate that the ligands strongly affect the ability of the ruthenium complexes to favour the occurrence of a well-behaved ATRP.

Disciplines :

Chemistry

Author, co-author :

Borguet, Yannick ; Université de Liège - ULiège > Département de chimie (sciences) > Chimie macromoléculaire et catalyse organique

Delaude, Lionel ; Université de Liège - ULiège > Département de chimie (sciences) > Chimie organométallique et catalyse homogène

Demonceau, Albert ; Université de Liège - ULiège > Département de chimie (sciences) > Chimie macromoléculaire et catalyse organique

Language :

English

Title :

Homobimetallic Ethylene− and Vinylidene−Ruthenium Complexes for ATRP

Publication date :

2012

Main work title :

Progress in Controlled Radical Polymerization: Mechanisms and Techniques

Editor :

Matyjaszewski, Krysztof

Sumerlin, Brent S.

Tsarevsky, Nicolay V.

Publisher :

American Chemical Society, Washington, United States

ISBN/EAN :

9780841226999

Collection name :

ACS Symposium Series 1100

Pages :

115-132

Available on ORBi :

since 22 March 2012

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